Quantum dots and devices including the same

Patent metadata

Field	Value
Publication number	US-11011672-B2
Application number	US-202016786004-A
Country	US
Kind code	B2
Filing date	Feb 10, 2020
Priority date	Dec 22, 2015
Publication date	May 18, 2021
Grant date	May 18, 2021

Abstract

A quantum dot includes a core-shell structure including a core including a first semiconductor nanocrystal and a shell disposed on the core, and including a material at least two different halogens, and the quantum dot does not include cadmium.

First claim

What is claimed is:

1. A core-shell quantum dot including at least two different halogens, the core-shell quantum dot comprising:
a core comprising a first semiconductor nanocrystal; and
a shell disposed on the core, the shell comprising a crystalline or amorphous material,
wherein the core-shell quantum dot does not include cadmium,
wherein the at least two different halogens comprise fluorine and chlorine, and
wherein the core-shell quantum dot has a quantum yield of greater than or equal to about 85%.

2. The core-shell quantum dot of claim 1 , wherein the core-shell quantum dot has a FWHM of less than or equal to about 50 nm.

3. The core-shell quantum dot of claim 1 , wherein at least one of the first semiconductor nanocrystal and the crystalline or amorphous material of the shell comprises Indium and phosphorous.

4. The core-shell quantum dot of claim 1 , wherein at least one of the first semiconductor nanocrystal and the crystalline or amorphous material of the shell comprises zinc and at least one of sulfur and selenium.

5. The core-shell quantum dot of claim 1 , wherein a solid state photoluminescence quantum efficiency of the core-shell quantum dot when measured at 90° C. is greater than or equal to about 95% of the solid state photoluminescence quantum efficiency of the core-shell quantum dot when measured at 25° C.

6. The core-shell quantum dot of claim 1 , wherein a solid state photoluminescence quantum efficiency of the core-shell quantum dot when measured at 150° C. is greater than or equal to about 80% of the solid state photoluminescence quantum efficiency of the core-shell quantum dot when measured at 25° C.

7. The core-shell quantum dot of claim 1 , wherein the quantum dot has a particle size of greater than or equal to about 5 nm.

8. The core-shell quantum dot of claim 1 , wherein each halogen is present in or on the shell in a doped form or in a form of a metal halide.

9. The core-shell quantum dot of claim 1 , wherein the shell has a thickness of at least one monolayer of the material of the shell, and at least one of the halogens is present at or outside the thickness of the one monolayer.

10. The core-shell quantum dot of claim 1 , wherein a total amount of the fluorine and the chlorine is greater than or equal to about 30 atomic percent, with respect to a total amount of a metal atom included in the core.

11. The core-shell quantum dot of claim 1 , wherein the first semiconductor nanocrystal comprises at least one first metal selected from a group consisting of a Group II metal excluding cadmium, a Group III metal, a Group IV metal, and a combination thereof, and
wherein the crystalline or amorphous material of the shell comprises at least one second metal that is different form the first metal and is selected from the group consisting of a Group I metal, a Group II metal excluding cadmium, a Group III metal, a Group IV metal, and a combination thereof.

12. The core-shell quantum dot of claim 1 , wherein the first semiconductor nanocrystal comprises a Group II-VI compound excluding a cadmium-containing compound, a Group III-V compound, a Group IV-VI compound, a Group IV element or compound, a Group II-III-VI compound, a Group I-III-VI compound, a Group I-II-IV-VI compound, or a combination thereof, and
wherein the crystalline or amorphous material of the shell comprises a Group II-VI compound excluding a cadmium-containing compound, a Group III-V compound, a Group IV-VI compound, a Group IV element or compound, a Group II-III-VI compound, a Group I-III-VI compound, a Group I-II-IV-VI compound, a metal-containing halogen compound, a metal oxide, or a combination thereof.

13. The core-shell quantum dot of claim 12 , wherein, the Group II-VI compound comprises ZnS, ZnSe, ZnTe, ZnO, HgS, HgSe, HgTe, MgSe, MgS, ZnSeS, ZnTeSe, ZnSTe, HgSeS, HgSeTe, HgSTe, HgZnS, HgZnSe, HgZnTe, MgZnSe, MgZnS, HgZnTeS, HgZnSeS, HgZnSeTe, or a combination thereof,
the Group III-V compound comprises GaN, GaP, GaAs, GaSb, AlN, AlP, AlAs, AlSb, InN, InP, InAs, InSb, GaNP, GaNAs, GaNSb, GaPAs, GaPSb, AlNP, AlNAs, AlNSb, AlPAs, AlPSb, InNP, InNAs, InNSb, InPAs, InPSb, GaAlNP, GaAlNAs, GaAlNSb, GaAlPAs, GaAlPSb, GaInNP, GaInNAs, GaInNSb, GaInPAs, GaInPSb, InAlNP, InAlNAs, InAlNSb, InAlPAs, InAlPSb, or a combination thereof,
the Group IV-VI compound comprises SnS, SnSe, SnTe, PbS, PbSe, PbTe, SnSeS, SnSeTe, SnSTe, PbSeS, PbSeTe, PbSTe, SnPbS, SnPbSe, SnPbTe, SnPbSSe, SnPbSeTe, SnPbSTe, or a combination thereof,
the Group I-III-VI compound comprises CuInSe 2 , CuInS 2 , CuInGaSe, CuInGaS, or a combination thereof,
the Group II-III-VI compound comprises ZnGaS, ZnAlS, ZnInS, ZnGaSe, ZnAlSe, ZnInSe, ZnGaTe, ZnAlTe, ZnInTe, ZnGaO, ZnAlO, ZnInO, HgGaS, HgAlS, HgInS, HgGaSe, HgAlSe, HgInSe, HgGaTe, HgAlTe, HgInTe, MgGaS, MgAlS, MgInS, MgGaSe, MgAlSe, MgInSe, or a combination thereof,
the Group I-II-IV-VI compound comprises CuZnSnSe, CuZnSnS, or a combination thereof,
the Group IV element compound comprises Si, Ge, SiC, SiGe, or a combination thereof,
the metal-containing halogen compound comprises LiF, NaF, KF, BeF 2 , MgF 2 , CaF 2 , SrF 2 , CuF, AgF, AuF, ZnF 2 , HgF 2 , AlF 3 , GaF 3 , InF 3 , SnF 2 , PbF 2 , LiCl, NaCl, KCl, BeCl 2 , MgCl 2 , CaCl 2 , SrCl 2 , CuCl, AgCl, AuCl, ZnCl 2 , HgCl 2 , AlCl 3 , GaCl 3 , InCl 3 , SnCl 2 , PbCl 2 , LiBr, NaBr, KBr, BeBr 2 , MgBr 2 , CaBr 2 , SrBr 2 , CuBr, AgBr, AuBr, ZnBr 2 , HgBr 2 , AlBr 3 , GaBr 3 , InBr 3 , SnBr 2 , PbBr 2 , LiI, NaI, KI, BeI 2 , MgI 2 , CaI 2 , SrI 2 , CuI, AgI, AuI, ZnI 2 , HgI 2 , AlI 3 , GaI 3 , InI 3 , SnI 2 , PbI 2 , or a combination thereof, and
the metal oxide comprises In 2 O 3 , PbO, HgO, MgO, Ga 2 O 3 , Al 2 O 3 , ZnO, SiO 2 , zinc oxysulfide, zinc oxyselenide, zinc oxysulfide selenide, indiumphosphide oxide, indiumphosphide oxysulfide, or a combination thereof.

14. The core-shell quantum dot of claim 1 , wherein the first semiconductor nanocrystal comprises a Group III-V compound or a Group II-VI compound, and the shell comprises a Group II-VI compound.

15. The core-shell quantum dot of claim 1 , wherein a total amount of the fluorine and the chlorine is greater than or equal to about 40 atomic percent, with respect to a total amount of a metal atom included in the core.

16. A quantum dot polymer composite comprising
a polymer matrix; and
the core-shell quantum dot of claim 1 dispersed in the polymer matrix.

17. The quantum dot polymer composite of claim 16 , wherein the polymer matrix comprises a thiolene polymer, a (meth)acrylate polymer, a urethane polymer, an epoxy polymer, a vinyl polymer, a silicone polymer, or a combination thereof.

18. The quantum dot polymer composite of claim 16 , wherein a content of the quantum dot is greater than or equal to about 0.1 wt % and less than or equal to about 30 wt % based on the total weight of the quantum dot polymer composite.

19. An electronic device comprising the core-shell quantum dot of claim 1 .

20. The electronic device of claim 19 , wherein the electronic device comprises a light source emitting a light comprising blue light and a quantum dot polymer composite, wherein the quantum dot polymer composite comprises a polymer matrix and a plurarity of the core-shell quantum dots.

21. The electronic device of claim 19 , wherein the light source comprises an organic light emitting diode.

Assignees

• Samsung Electronics Co Ltd

Inventors

• Park Garam
• Kim Tae Hyung
• Jang Eun Joo
• Jang Hyo Sook
• Jun Shin Ae
• Kim Yongwook
• Kim Taekhoon
• MIN Jihyun
• Won Yuho

Classifications

• C09K11/025 Primary

  non-luminescent particle coatings or suspension media · CPC title

• H10H20/826

  comprising only Group IV materials · CPC title

• H10H20/825

  containing nitrogen, e.g. GaN · CPC title

• H10H20/824

  comprising only Group III-V materials, e.g. GaP · CPC title

• H10H20/823

  comprising only Group II-VI materials, e.g. ZnO · CPC title