Electrochemical energy storage device

Patent metadata

Field	Value
Publication number	US-11011321-B2
Application number	US-201816185093-A
Country	US
Kind code	B2
Filing date	Nov 9, 2018
Priority date	Jan 29, 2015
Publication date	May 18, 2021
Grant date	May 18, 2021

Abstract

An electrochemical energy storage device includes an anode having a first mixture which includes a first plurality of electrically conductive carbon-comprising particles having a first average porosity, and lithium metal materials. The weight ratio of the first plurality of carbon-comprising and lithium metal materials is from 30:1 to 3:1. A cathode includes a second mixture having a second plurality of electrically conductive carbon-comprising particles having a second average porosity greater than the first average porosity, and lithium-intercalating metal oxide particles. The weight ratio of the second plurality of carbon-comprising and lithium-intercalating metal oxide particles is from 1:20 to 5:1. The weight ratio between the lithium metal materials loaded in the anode and the second plurality of carbon-comprising particles in the cathode is from 0.1-10%. An electrolyte physically and ionically contacts the anode and the cathode, and fills the pore volume in the anode, cathode and a porous separator.

First claim

We claim:

1. An electrochemical energy storage device, comprising:
an anode comprising a first mixture, the first mixture comprising a first plurality of electrically conductive carbon-comprising particles having a first average porosity, and lithium metal materials, the weight ratio of the first plurality of carbon-comprising and lithium metal materials being from 30:1 to 3:1;
an electrically conductive current collector connecting to the anode;
a cathode comprising a second mixture, the second mixture comprising a second plurality of electrically conductive carbon-comprising particles having a second average porosity greater than the first average porosity and lithium-intercalating metal oxide particles, the weight ratio of the second plurality of carbon-comprising and lithium-intercalating metal oxide particles being from 1:20 to 5:1;
wherein the weight ratio between the lithium metal materials loaded in the anode and the second plurality of carbon-comprising particles in the cathode is from 0.6-1.7%;
an electrically conductive current collector connecting to the cathode;
a porous separator between the anode and the cathode; and
an electrolyte physically and ionically contacting the anode and the cathode, and filling the pore volume in the anode, cathode and separator.

2. The electrochemical energy storage device of claim 1 , wherein the second plurality of carbon-comprising particles in the cathode has an electrical conductivity greater than 1 S/cm.

3. The electrochemical energy storage device of claim 1 , wherein the second plurality of carbon-comprising particles in the cathode has a specific surface area greater than 500 m 2 /g.

4. The electrochemical energy storage device of claim 1 , wherein the second plurality of carbon-comprising particles in the cathode has a specific capacitance greater than 50 F/g.

5. The electrochemical energy storage device of claim 1 , wherein the second plurality of carbon-comprising particles in the cathode has a porosity greater than 50%.

6. The electrochemical energy device of claim 1 , wherein the weight ratio of the first plurality of carbon-comprising and lithium metal particles in the anode is from 20:1 to 8:1.

7. The electrochemical energy device of claim 1 , wherein the weight ratio of the first plurality of carbon-comprising and lithium metal materials in the anode is from 17:1 to 11:1.

8. The electrochemical energy storage device of claim 1 , wherein the weight ratio of the second plurality of carbon-comprising and lithium-intercalating metal oxide particles in the cathode is from 1:5 to 3:1.

9. The electrochemical energy storage device of claim 1 , wherein the weight ratio of the second plurality of carbon-comprising and lithium-intercalating metal oxide particles in the cathode is from 1:2 to 2:1.

10. The electrochemical energy storage device of claim 1 , wherein the first plurality of carbon-comprising particles comprises at least one selected from the group consisting of hard carbon, soft carbon, graphitic carbon, carbon black, carbon microbeads, carbon nanotubes, and carbon nanofibers.

11. The electrochemical energy storage device of claim 1 , wherein the second plurality of carbon-comprising particles comprises at least one selected from the group consisting of activated carbon, carbon microbeads, carbon black, carbon nanotubes, activated carbon nanotubes, and activated carbon nanofibers.

12. The electrochemical energy storage device of claim 1 , wherein the lithium metal oxide particles comprise at least one selected from the group consisting of LiCoO 2 (lithium cobalt oxide), LiNi 0.8 Co 0.15 Al 0.05 O 2 (NCA), LiMn 2 O 4 (spinel), LiV 3 O 8 , LiNi 1/3 Mn 1/3 Co 1/3 O 2 (NMC 333), LiMn x Co y Ni z O 2 (NMC non-stoichiometric), LiFePO 4 (lithium iron phosphate), xLi 2 MnO 3 ·(1−x)LiMO 2 , LiNi 1/3 Mn 1/3 Co 1/3 O 2 , LiNi 1/3 Mn 1/3 Co 1/3 O 2 , Li[Li 0.2 Mn 0.54 Ni 0.13 Co 0.13 ]O 2 , and Li[Li 0.2 Mn 0.54 Ni 0.13 Co 0.13 ]O 2 .

13. An electrochemical energy storage device comprising multiple unit cells, each unit cell comprising:
an anode comprising a first mixture, the first mixture comprising a first plurality of electrically conductive carbon-comprising particles having a first average porosity, and lithium metal materials, the weight ratio of the first plurality of carbon-comprising and lithium metal materials being from 30:1 to 3:1;
an electrically conductive current collector connecting to the anode;
a cathode comprising a second mixture, the second mixture comprising a second plurality of electrically conductive carbon-comprising particles having a second average porosity greater than the first average porosity and lithium-intercalating metal oxide particles, the weight ratio of the second plurality of carbon-comprising and lithium-intercalating metal oxide particles being from 1:20 to 5:1;
wherein the weight ratio between the lithium metal materials in the anode and the second plurality of carbon-comprising particles in the cathode is from 0.6-1.7%;
an electrically conductive current collector connecting to the cathode;
a porous separator between the anode and cathode; and
an electrolyte physically and ionically contacting the anode and the cathode, and filling the pore volume in the anode, cathode and separator.

14. The electrochemical energy storage device of claim 13 , wherein the electrochemical energy storage device is a pouch cell.

15. An electrochemical energy storage device, comprising:
an anode comprising a first mixture, the first mixture comprising a first plurality of electrically conductive particles having a first average porosity, and lithium metal materials, the weight ratio of the first plurality of particles and the lithium metal materials being from 30:1 to 3:1;
an electrically conductive current collector connecting to the anode;
a cathode comprising a second mixture, the second mixture comprising a second plurality of electrically conductive particles having a second average porosity greater than the first average porosity and lithium-intercalating metal oxide particles, the weight ratio of the second plurality of particles and the lithium-intercalating metal oxide particles being from 1:20 to 5:1;
wherein the weight ratio between the lithium metal materials in the anode and the second plurality of particles in the cathode is from 0.6-1.7%;
an electrically conductive current collector connecting to the cathode;
a porous separator between the anode and the cathode; and
an electrolyte physically and ionically contacting the anode and the cathode, and filling the pore volume in the anode, cathode and separator.

16. The electrochemical energy storage device of claim 15 , wherein the first plurality of electrically conductive particles comprises at least one selected from the group consisting of carbon, silicon, lithium titanate (Li 4 Ti 5 O 12 ), and tin.

17. The electrochemical energy storage device of claim 15 , wherein the second plurality of electrically conductive particles comprises carbon.

Assignees

• Univ Florida State Res Found

Inventors

• Zheng Jian-Ping
• Zheng Junsheng

Classifications

• H01G11/32 Primary

  Carbon-based · CPC title

• H01G11/24

  characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor · CPC title

• H01G11/50

  specially adapted for lithium-ion capacitors, e.g. for lithium-doping or for intercalation · CPC title

• H01G11/06 Primary

  with one of the electrodes allowing ions to be reversibly doped thereinto, e.g. lithium ion capacitors [LIC] · CPC title

• H01G11/86

  specially adapted for electrodes (carbonisation or activation of carbon for the manufacture of electrodes H01G11/34) · CPC title