Alkoxymagnesium, method for producing alkoxymagnesium, solid catalyst component for olefin polymerization, olefin polymerization catalyst, and method for producing olefin polymer

Patent metadata

Field	Value
Publication number	US-11008408-B2
Application number	US-201716088158-A
Country	US
Kind code	B2
Filing date	Mar 23, 2017
Priority date	Mar 28, 2016
Publication date	May 18, 2021
Grant date	May 18, 2021

Abstract

There is provided a novel alkoxymagnesium which, when used as a constituent of a solid catalyst component for olefin polymerization to polymerize an olefin, may reduce the formation rate of a fine powder and may form a polymer having an excellent particle size distribution under high polymerization activity. The alkoxymagnesium is characterized by comprising secondary particles each of which is an aggregate of primary particles having an average particle diameter of less than 1 μm and by having a ratio represented by the average particle diameter of the primary particles/the average particle diameter of the secondary particles of 0.1 or less, a total pore volume of 0.5 to 1 cm3/g, a specific surface area of less than 50 m2/g, and a particle size distribution index (SPAN) 1 or less.

First claim

The invention claimed is:

1. An alkoxymagnesium comprising secondary particles each of which is an aggregate of primary particles having an average particle diameter of less than 1 μm, wherein
a ratio of an average particle diameter of the primary particles/an average particle diameter of the secondary particles is 0.1 or less, a total pore volume is 0.5 to 1 cm 3 /g, a specific surface area is less than 50 m 2 /g, and a particle size distribution index (SPAN) is 1 or less.

2. The alkoxymagnesium according to claim 1 , wherein a content of a fine powder having a particle diameter of 5 μm or less is 3% by mass or less based on a total particle mass, the total pore volume is 0.5 to 1 cm 3 /g, and 50% or more of pores having a pore diameter of 1 μm or less has a pore diameter of 0.5 μm or less.

3. The alkoxymagnesium according to claim 2 , wherein the average particle diameter of the secondary particles is less than 60 μm.

4. The alkoxymagnesium according to claim 1 , wherein the average particle diameter of the secondary particles is less than 60 μm.

5. A solid catalyst component for olefin polymerization obtained by contacting (a) the alkoxymagnesium according to claim 1 , (b) a titanium halogen compound, and (c) an electron-donating compound with one another.

6. An olefin polymerization catalyst comprising (A) the solid catalyst component for olefin polymerization according to claim 5 , (B) an organoaluminum compound represented by the following general formula (IV);
R 15 p AlQ 3−p   (IV)

wherein R 15 represents an alkyl group having 1 to 4 carbon atoms, Q represents a hydrogen atom or halogen atom, and p is a real number satisfying 0<p≤3, and when a plurality of R 15 are present, each R 15 may be identical or different from one another and when a plurality of Q are present, each Q may be identical or different from one another, and (C) an external electron-donating compound.

7. The olefin polymerization catalyst according to claim 6 , wherein
(C) the external electron-donating compound is one or more selected from organosilicon compounds represented by the following general formula (V);
R 16 q Si(OR 17 ) 4−q   (V)

wherein R 16 represents an alkyl group having 1 to 12 carbon atoms, a vinyl group, an alkenyl group having 3 to 12 carbon atoms, a cycloalkyl group having 3 to 12 carbon atoms, a cycloalkenyl group having 3 to 12 carbon atoms, an aromatic hydrocarbon group having 6 to 15 carbon atoms, or an aromatic hydrocarbon group having 6 to 15 carbon atoms and having a substituent, and when a plurality of R 16 are present, the plurality of R 16 may be identical or different from one another, R 17 represents an alkyl group having 1 to 4 carbon atoms, a vinyl group, an alkenyl group having 3 to 12 carbon atoms, a cycloalkyl group having 3 to 6 carbon atoms, an aromatic hydrocarbon group having 6 to 12 carbon atoms, or an aromatic hydrocarbon group having 7 to 12 carbon atoms and having a substituent, and when a plurality of R 17 are present, the plurality of R 17 may be identical or different from one another, and q is an integer of 0≤q≤3, or

aminosilane compounds represented by the general formula (VI);
(R 18 R 19 N) s SiR 20 4−s   (VI)

wherein R 18 and R 19 each represent a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, a vinyl group, an alkenyl group having 3 to 20 carbon atoms, cycloalkyl group having 3 to 20 carbon atoms, a cycloalkenyl group having 3 to 20 carbon atoms, or an aryl group having 6 to 20 carbon atoms, R 18 and R 19 may be identical or different from each other or may bond with each other to form a ring, and when a plurality of R 18 R 19 N groups are present, the plurality of R 18 R 19 N groups may be identical or different from one another, R 20 represents an alkyl group having 1 to 20 carbon atoms, a vinyl group, an alkenyl group having 3 to 12 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a vinyloxy group having 3 to 20 carbon atoms, an alkenyloxy group having 3 to 20 carbon atoms, a cycloalkyl group having 3 to 20 carbon atoms, a cycloalkyloxy group having 3 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, or an aryloxy group having 6 to 20 carbon atoms, and when a plurality of R 20 are present, the plurality of R 20 may be identical or different from one another, and s is an integer of 1 to 3.

8. A method for producing an olefin polymer comprising polymerizing an olefin in the presence of the olefin polymerization catalyst according to claim 6 .

9. A method for producing an olefin polymer comprising polymerizing an olefin in the presence of the olefin polymerization catalyst according to claim 7 .

10. A method for producing an alkoxymagnesium, comprising sequentially carrying out
a solid formation step of reacting metal magnesium with an alcohol in the presence of a catalyst to form a solid, and
a contact step of contacting the solid with one or more carboxylic acid esters in an organic solvent to form a suspension,
wherein the one or more carboxylic acid ester is selected from diethyl succinate, dibutyl succinate, bis(2-ethylhexyl) succinate, diethyl maleate, dibutyl maleate, bis(2-ethylhexyl) maleate, diethyl malonate, dibutyl malonate, or bis(2-ethylhexyl) malonate.

11. The method for producing an alkoxymagnesium according to claim 10 , wherein the alcohol is one or more selected from methanol, ethanol, n-propanol, isopropanol, n-butanol, isobutanol, or 2-ethylhexyl alcohol.

12. The method for producing an alkoxymagnesium according to claim 11 , wherein the organic solvent is one or more selected from aliphatic hydrocarbon compounds or aromatic hydrocarbon compounds.

13. The method for producing an alkoxymagnesium according to claim 10 , wherein the organic solvent is one or more selected from aliphatic hydrocarbon compounds or aromatic hydrocarbon compounds.

14. The method for producing an alkoxymagnesium according to claim 10 , wherein the alkoxymagnesium is diethoxymagnesium.

15. The method for producing an alkoxymagnesium according to claim 10 , wherein, by carrying out the contact step,
a portion of the solid is reacted with the carboxylic acid ester to form a reactant,
a portion of the solid is dissolved in a mixture of the carboxylic acid ester and the organic solvent, or
a portion of the solid is liberated in a mixture of the carboxylic acid ester and the organic solvent.

Assignees

• Toho Titanium Co Ltd

Inventors

• Kono Hiroyuki
• Yamada Shingo
• Uozumi Toshiya

Classifications

• C08F4/654

  with magnesium or compounds thereof · CPC title

• C08F4/6425

  containing magnesium · CPC title

• C07F3/02

  Magnesium compounds · CPC title

• C07C29/70 Primary

  by converting hydroxy groups to O-metal groups {(C07C29/09 takes precedence)} · CPC title

• C08F10/00

  Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title