Preparation method of a coated sheet comprising the application of an aqueous solution comprising an amino acid and its associated use for improving the compatibility with an adhesive

Patent metadata

Field	Value
Publication number	US-11007750-B2
Application number	US-201615546421-A
Country	US
Kind code	B2
Filing date	Feb 1, 2016
Priority date	Jan 30, 2015
Publication date	May 18, 2021
Grant date	May 18, 2021

Abstract

A method for preparing a metal sheet ( 1 ) is provided including at least the steps for:
providing a steel substrate ( 3 ) having two faces ( 5 ), at least one of which is coated with a metal coating ( 7 ) comprising at least 40% by weight of zinc, applying on the outer surface ( 15 ) of the metal coating ( 7 ) an aqueous solution comprising an amino acid,

and the metal sheet which may be obtained.

First claim

The invention claimed is:

1. A method for preparing a metal sheet comprising the steps of:
providing a steel substrate, at least one face of the steel substrate being coated with a metal coating comprising at least 40% by weight of zinc;
applying on an outer surface of the metal coating an aqueous solution consisting of a mixture of:
water,
an amino acid selected from the group consisting of: alanine, arginine, aspartic acid, cysteine, lysine, methionine, proline, threonine, valine, each amino acid being in neutral or salt form, and mixtures of said amino acids, each amino acid in the mixture independently in a neutral or salt form, and
optionally of an acid, or a mixture of acids;

the aqueous solution being free of compound comprising a metal from the group IIIB or from the group IVB and comprising less than 0.005 g/L of iron ions; and
a mass percentage as dry extract of the amino acid in neutral or salt form or of the mixture of amino acids in neutral or salt forms in the aqueous solution being greater than or equal to 50%.

2. The method according to claim 1 further comprising a preliminary step for preparing the steel substrate by hot galvanizating or electro-zinc-plating the steel substrate to form the coating.

3. The method according to claim 1 wherein the metal coating is selected from the group consisting of: a zinc coating GI, a zinc coating GA, a zinc and aluminum alloy, a zinc and magnesium alloy and a zinc, magnesium and aluminum alloy.

4. The method according to claim 3 wherein the metal coating comprises between 0.1 and 10% by weight of Mg and optionally between 0.1 and 20% by weight of Al, the remainder of the metal coating being Zn, the inevitable impurities and optionally at least one additional element selected from the group consisting of: Si, Sb, Pb, Ti, Ca, Mn, Sn, La, Ce, Cr, Ni and Bi.

5. The method according to claim 1 wherein the amino acid is selected from the group consisting of: alanine, aspartic acid, cysteine, methionine, proline, threonine, valine and a mixture thereof, each amino acid being in neutral or salt form.

6. The method according to claim 1 wherein the steel substrate is prepared by electro-zinc-plating to form the metal coating and the amino acid is selected from the group consisting of: aspartic acid, cysteine, methionine, proline, threonine or a mixture thereof, each amino acid being in neutral or salt form.

7. The method according to claim 1 wherein the steel substrate is prepared by hot galvanization to form the metal coating and the amino acid is selected from the group consisting of: alanine, proline, threonine and valine, and a mixture thereof, each amino acid being in neutral or salt form.

8. The method according to claim 1 wherein the amino acid is proline in a neutral or salt form, threonine in a neutral or salt form, or a mixture of proline and threonine, the proline and threonine being in neutral or salt form.

9. The method according to claim 1 wherein the aqueous solution comprises from 1 to 200 g/L of amino acid in neutral or salt form or of a mixture of amino acids in neutral or salt forms or from 10 to 1,750 mmol/L of amino acid in neutral or salt form or a mixture of amino acids in neutral or salt forms.

10. The method according to claim 1 wherein the mass percentage in dry extract of the amino acid in neutral or salt form or of the mixture of amino acids in neutral or salt forms in the aqueous solution is greater than or equal to 75%.

11. The method according to claim 1 wherein the aqueous solution has a pH comprised between a pH equal to the (isoelectric point of the amino acid−3) and a pH equal to the (isoelectric point of the amino acid+1).

12. The method according to claim 11 wherein the aqueous solution has a pH comprised between a pH equal to the (isoelectric point of the amino acid−3) and a pH equal to the (isoelectric point of the amino acid−1).

13. The method according to claim 1 wherein the aqueous solution is applied at a temperature comprised between 20 and 70° C. or for a period comprised between 0.5 s and 40 s on the outer surface of the metal coating.

14. The method according to claim 1 wherein the aqueous solution is applied by roll coating.

15. The method according to claim 1 further comprising, after the application step on the outer surface of the metal coating of the aqueous solution, a drying step.

16. The method according to claim 1 further comprising, after the application step on the outer surface of the metal coating of the aqueous solution and an optional drying step to form a layer consisting of the amino acid or the mixture of amino acids and optionally the acid or the mixture of acids, a step of applying a film of grease or oil on a layer outer surface of the layer.

17. The method according to claim 1 further comprising, after the application step on the outer surface of the metal coating of the aqueous solution, an optional drying step and an optional step of applying a film of grease or oil, a step of shaping the metal sheet.

18. The method according to claim 1 further comprising, after the application step on the outer surface of the metal coating of the aqueous solution, an optional drying step, an optional step of applying a film of grease or oil, and an optional step for shaping the metal sheet, a step of applying locally an adhesive on a layer consisting of the amino acid or the mixture of amino acids and optionally the acid or the mixture of acids, the layer being on the outer surface of the metal coating.

19. The method according to claim 1 wherein the acid is phosphoric acid in a neutral form and in a salt form, or a mixture thereof.

20. A method for preparing a metal sheet comprising the steps of:
providing a steel substrate, at least one face of the steel substrate being coated with a metal coating comprising at least 40% by weight of zinc;
applying on an outer surface of the metal coating an aqueous solution consisting of a mixture of:
water,
an amino acid selected from the group consisting of: alanine, arginine, aspartic acid, cysteine, lysine, methionine, proline, threonine, valine, each amino acid being in neutral or salt form, and mixtures of said amino acids, each amino acid in the mixture independently in a neutral or salt form, and
optionally of a base, a mixture of bases, an acid, or a mixture of acids;

the aqueous solution being free of compound comprising a metal from the group IIIB or from the group IVB and comprising less than 0.005 g/L of iron ions; and
a mass percentage as dry extract of the amino acid in neutral or salt form or of the mixture of amino acids in neutral or salt forms in the aqueous solution being greater than or equal to 50%, then
thermally degassing that obtains a metal sheet including a layer consisting of the amino or the mixture of said amino acids and optionally the base, the mixture of bases, the acid, or the mixture of acids.

21. A method for preparing a metal sheet comprising the steps of:
providing a steel substrate, at least one face of the steel substrate being coated with a metal coating comprising at least 40% by weight of zinc;
applying on an outer surface of the metal coating an aqueous solution consisting of a mixture of:
water,
an amino acid selected from the group consisting of: alanine, arginine, aspartic acid, cysteine, lysine, methionine, proline, threonine, valine, each amino acid being in neutral or salt form, and mixtures of said amino acids, each amino acid in the mixture independently in a neutral or salt form, an

Assignees

• Arcelormittal

Inventors

• Rachiele Lydia
• Derule Herve
• Thai Delphine

Classifications

• C23C2/06 Primary

  Zinc or cadmium or alloys based thereon · CPC title

• C23C22/82

  After-treatment · CPC title

• C23C22/53

  Treatment of zinc or alloys based thereon · CPC title

• C09J2400/20

  Presence of organic materials · CPC title

• C25D5/48

  After-treatment of electroplated surfaces · CPC title