Fluidized-bed-type reactor, and method for manufacturing trichlorosilane

Patent metadata

Field	Value
Publication number	US-11007499-B2
Application number	US-201816652050-A
Country	US
Kind code	B2
Filing date	Nov 16, 2018
Priority date	Nov 20, 2017
Publication date	May 18, 2021
Grant date	May 18, 2021

Abstract

A fluidized-bed reactor ( 1 A) includes a reaction vessel ( 10 A) configured to contain metallurgical grade silicon powder and a hydrogen chloride gas, and a portion of a side wall (w) which portion extends along at least 80% of a height extending from a gas feed opening ( 21 ), which is provided in a lower part of the reaction vessel ( 10 A), to a top face of a fluid bed ( 40 ) has such a tapered shape that a cross section of the reaction vessel ( 10 A) which cross section is taken perpendicular to a height direction of the reaction vessel ( 10 A) increases in area in an upward direction.

First claim

The invention claimed is:

1. A fluidized-bed reactor for producing trichlorosilane by causing metallurgical grade silicon powder and a hydrogen chloride gas to react with each other, comprising a
reaction vessel configured to contain the metallurgical grade silicon powder and the hydrogen chloride gas,
the reaction vessel having a side wall surrounding a fluid bed which is formed by a flow of the metallurgical grade silicon powder which is caused to flow by the hydrogen chloride gas,
the reaction vessel having a gas feed opening which is provided in a lower part of the reaction vessel and through which the hydrogen chloride gas is supplied,
a portion of the side wall which portion extends along at least 80% of a height extending from the gas feed opening to a top face of the fluid bed having such a tapered shape that a cross section of the reaction vessel which cross section is taken perpendicular to a height direction of the reaction vessel increases in area in an upward direction,

a distributor plate having the gas feed opening and configured to disperse the hydrogen chloride gas from the gas feed opening,
the distributor plate being provided in the lower part of the reaction vessel,
the side wall having the tapered shape from a boundary between the fluid bed and the distributor plate.

2. The fluidized-bed reactor as set forth in claim 1 , wherein the side wall has the tapered shape throughout the height extending from the gas feed opening to the top face of the fluid bed.

3. The fluidized-bed reactor as set forth in claim 1 , wherein a taper angle of the tapered shape is an angle between the height direction and the portion of the side wall which portion has the tapered shape, the taper angle being not less than 3.0° and not more than 7.0°.

4. The fluidized-bed reactor as set forth in claim 1 , wherein:
the reaction vessel further has a freeboard section formed by an outer wall which extends from the side wall along the height direction;
the reaction vessel has an outlet which is provided in an upper part of the reaction vessel and through which a product of a reaction between the metallurgical grade silicon powder and the hydrogen chloride gas is discharged;
the freeboard section guides, to the outlet, the product ascending from the fluid bed; and
a ratio L/D of a length L of the freeboard section along the height direction to a diameter D of a cross section of the freeboard section which cross section is taken perpendicular to the height direction is not less than 1.5.

5. A method for producing trichlorosilane, comprising the step of causing the metallurgical grade silicon powder and the hydrogen chloride gas to react with each other with use of a fluidized-bed reactor recited in claim 1 .

Assignees

• Tokuyama Corp

Inventors

• Hirota Kenji
• Ogihara Katsuya

Classifications

• B01J2208/00548

  Flow · CPC title

• B01J2208/00132

  Tubes · CPC title

• B01J8/1872

  Details of the fluidised bed reactor (B01J8/1836 takes precedence) · CPC title

• B01J8/1827

  the fluidising gas being a reactant · CPC title

• Y02E60/36

  Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title