Polarizer protection film, polarizing plate including same, and liquid crystal display device including polarizing plate

Patent metadata

Field	Value
Publication number	US-11002886-B2
Application number	US-201616096648-A
Country	US
Kind code	B2
Filing date	Dec 23, 2016
Priority date	Apr 25, 2016
Publication date	May 11, 2021
Grant date	May 11, 2021

Abstract

Provided are a polarizer protection film, a polarizing plate comprising the same, and a liquid crystal display device comprising the polarizing plate. The polarizer protection film has: a moisture permeability ranging from approximately 0 g/m 2 /24 hr to approximately 100 g/m 2 /24 hr; a value for a MD-direction shrinkage rate/a TD-direction shrinkage rate, ranging from 0.8 to 1.3; an in-plane phase difference (Re) ranging from approximately 0 nm to approximately 350 nm; a thickness-direction phase difference (Rth) ranging from approximately 2500 nm to approximately 8000 nm; and a thickness of approximately 10 μm to approximately 60 μm.

First claim

The invention claimed is:

1. A protective film for polarizer, having a water vapor transmission rate of about 0 g/m 2 /24 hr to about 100 g/m 2 /24 hr; a ratio of shrinkage in the machine direction to shrinkage in the transverse direction of about 0.9 to about 1.3; an in-plane retardation Re of about 0 nm to about 350 nm; an out-of-plane retardation Rth of about 2,500 nm to about 8,000 nm; and a thickness of about 10 μm to about 60 μm, the shrinkage in each of the machine direction and the transverse direction being measured after heating the protective film for polarizer having a size of 60 mm×60 mm (machine direction×transverse direction) for 250 hours at 85° C.,
wherein the protective film for polarizer is a polyester-based film, and the polyester is polyethylene terephthalate.

2. The protective film for polarizer according to claim 1 , wherein the protective film for polarizer comprises polyester-based material.

3. The protective film for polarizer according to claim 2 , wherein the protective film for polarizer comprises a polyethylene terephthalate resin, a polyethylene naphthalate resin, or a copolymer thereof.

4. The protective film for polarizer according to claim 3 , wherein the protective film for polarizer has a triple co-extruded structure comprising the polyethylene terephthalate resin, the polyethylene naphthalate resin, or the copolymer thereof.

5. A liquid crystal display, comprising:
a liquid crystal cell;
a backlight unit;
a lower polarizing plate interposed between the liquid crystal cell and the backlight unit; and
an upper polarizing plate disposed on a viewer side of the liquid crystal cell,
wherein at least one of the upper polarizing plate and the lower polarizing plate comprises the protective film for polarizer according to claim 1 .

6. The liquid crystal display according to claim 5 , wherein the liquid crystal display further comprises a functional layer disposed on one surface of the protective film for polarizer,
wherein the functional layer comprises at least one of a hard-coating layer, an anti-reflection layer, an anti-glare layer, and a diffusion layer.

7. The liquid crystal display according to claim 6 , wherein the functional layer is disposed on the protective film for polarizer of the upper polarizing plate.

8. The liquid crystal display according to claim 7 , wherein the functional layer is disposed on a viewer side of the protective film for polarizer.

9. The protective film for polarizer according to claim 1 , wherein the ratio of shrinkage in the machine direction to shrinkage in the transverse direction is about 0.9 to about 1.1.

10. The protective film for polarizer according to claim 1 , wherein a sum of the shrinkage in the machine direction and the shrinkage in the transverse direction is less than 1%.

11. The protective film for polarizer according to claim 1 , wherein the protective film for polarizer has the in-plane retardation Re of about 0 nm to about 350 nm and the out-of-plane retardation Rth of about 2,500 nm to about 8,000 nm after being stretched in the machine direction to an elongation of about 3.0 to about 3.5 and in the transverse direction to an elongation of about 2.5 to about 4.5.

12. A polarizing plate comprising:
a polarizer comprising a polyvinyl alcohol resin; and
a protective film for polarizer stacked on at least one surface of the polarizer,
wherein the protective film for polarizer has a water vapor transmission rate of about 0 g/m 2 /24 hr to about 100 g/m 2 /24 hr; a ratio of shrinkage in the machine direction to shrinkage in the transverse direction of about 0.9 to about 1.3; an in-plane retardation Re of about 0 nm to about 350 nm; an out-of-plane retardation Rth of about 2,500 nm to about 8,000 nm; and a thickness of about 10 μm to about 60 μm, the shrinkage in each of the machine direction and the transverse direction being measured after heating the protective film for polarizer having a size of 60 mm×60 mm (machine direction×transverse direction) for 250 hours at 85° C., and
wherein the protective film for polarizer is a polyester-based film, and the polyester is polyethylene terephthalate.

13. The polarizing plate according to claim 12 , wherein the protective film for polarizer comprises polyester-based material.

14. The polarizing plate according to claim 13 , wherein the protective film for polarizer comprises a polyethylene terephthalate resin, a polyethylene naphthalate resin, or a copolymer thereof.

15. The polarizing plate according to claim 14 , wherein the protective film for polarizer has a triple co-extruded structure comprising the polyethylene terephthalate resin, the polyethylene naphthalate resin, or the copolymer thereof.

16. The polarizing plate according to claim 12 , wherein the polarizing plate further comprises a functional layer disposed on one surface of the protective film for polarizer,
wherein the functional layer comprises at least one of a hard-coating layer, an anti-reflection layer, an anti-glare layer, and a diffusion layer.

17. The polarizing plate according to claim 12 , wherein the ratio of shrinkage in the machine direction to shrinkage in the transverse direction is about 0.9 to about 1.1.

18. The polarizing plate according to claim 12 , wherein a sum of the shrinkage in the machine direction and the shrinkage in the transverse direction is less than 1%.

19. The polarizing plate according to claim 12 , wherein the protective film for polarizer has the in-plane retardation Re of about 0 nm to about 350 nm and the out-of-plane retardation Rth of about 2,500 nm to about 8,000 nm after being stretched in the machine direction to an elongation of about 3.0 to about 3.5 and in the transverse direction to an elongation of about 2.5 to about 4.5.

Assignees

• Samsung Sdi Co Ltd

Inventors

• Kim Ran
• Yu So Hee
• Lee Seung Kyu

Classifications

• G02B5/305 Primary

  including organic materials, e.g. polymeric layers · CPC title

• G02B1/14 Primary

  Protective coatings, e.g. hard coatings · CPC title

• G02F2201/54

  Arrangements for reducing warping-twist · CPC title

• B29D11/00644

  polarizing · CPC title

• G02B5/30

  Polarising elements (light-modulating devices with active elements G02F1/00) · CPC title