Tear resistant nanofiber sheet

Patent metadata

Field	Value
Publication number	US-11001950-B2
Application number	US-201916364955-A
Country	US
Kind code	B2
Filing date	Mar 26, 2019
Priority date	May 17, 2018
Publication date	May 11, 2021
Grant date	May 11, 2021

Abstract

One or more nanofiber yarns can be placed in contact with one or more nanofiber sheets. The nanofiber yarns, which include single-ply and multi-ply nanofiber yarns, provide added mechanical stability to a nanofiber sheet that decreases the likelihood of a nanofiber sheet wrinkling, folding, or otherwise becoming stuck to itself. Furthermore, the nanofiber yarns integrated with the nanofiber sheet can also act as a mechanism to prevent the propagation of tears through the nanofiber sheet. In some cases, an infiltrating material can be infiltrated into interstitial spaces defined by the nanofibers within both the nanofiber yarns and the nanofiber sheets. The infiltrating material can then form a continuous network throughout the nanofiber yarns and the nanofiber sheet.

First claim

What is claimed is:

1. A nanofiber sheet assembly comprising:
a nanofiber yarn having a circumference and a length;
a nanofiber sheet in direct contact with the nanofiber yarn; and
an infiltrating material disposed within the nanofiber yarn and the nanofiber sheet, wherein the nanofiber yarn has a surface topography corresponding to twisted fibers within the nanofiber yarn and at least a portion of the nanofiber sheet conforms to a surface topography of the nanofiber yarn, the nanofiber sheet having surface indentations in at least one of an inner surface and an outer surface of the nanofiber sheet, and
nanofibers of the nanofiber sheet are aligned substantially parallel to one another along their longitudinal axes and end-to-end in a plane that is parallel to the inner and outer surfaces of the nanofiber sheet.

2. The nanofiber sheet assembly of claim 1 , wherein the nanofiber sheet is in direct contact with at least half of the circumference of the nanofiber yarn along at least some of the length of the nanofiber yarn.

3. The nanofiber sheet assembly of claim 1 , wherein the nanofiber sheet assembly is configured to be resistant to one or more of folding, wrinkling, and tearing.

4. The nanofiber sheet assembly of claim 1 , wherein the nanofiber sheet is in direct contact with at least 75% of the circumference of the nanofiber yarn.

5. The nanofiber sheet assembly of claim 1 , wherein the nanofiber sheet is in direct contact with at least 90% of the circumference of the nanofiber yarn.

6. The nanofiber sheet assembly of claim 1 , wherein the nanofiber yarn comprises a plurality of single-ply nanofiber yarns, multi-ply nanofiber yarns, or both.

7. The nanofiber sheet assembly of claim 1 , wherein the infiltrating material is disposed within a first plurality of interstitial spaces defined by nanofibers within the nanofiber yarn and within a second plurality of interstitial spaces defined by nanofibers within the nanofiber sheet.

8. The nanofiber sheet assembly of claim 7 , wherein the infiltrating material forms a continuous network connecting the nanofiber yarn and the nanofiber sheet.

9. The nanofiber sheet assembly of claim 1 , wherein the infiltrating material is a polymer.

10. The nanofiber sheet assembly of claim 9 , wherein the polymer is an elastomeric network polymer.

11. The nanofiber sheet assembly of claim 1 , wherein the nanofiber sheet is a first nanofiber sheet in contact with a first portion of the circumference of the length of the nanofiber yarn and a second nanofiber sheet in contact with a second portion of the circumference of the length of the nanofiber yarn, the first portion and the second portion comprising greater than 95% of the circumference.

12. The nanofiber sheet assembly of claim 1 , further comprising a polymer sheet connected to an assembly of the nanofiber yarn, the nanofiber sheet, and the infiltrating material.

13. The nanofiber sheet assembly of claim 1 , wherein a thickness of the nanofiber sheet is less than 0.1 μm.

14. The nanofiber sheet assembly of claim 1 , wherein a diameter of the nanofiber yarn is less than 5 μm.

15. The nanofiber sheet assembly of claim 1 , wherein the infiltrating material is disposed within the nanofiber yarn and the nanofiber sheet through an infiltration process, wherein the infiltration process comprises providing a fluid selected from at least one of: a polymer, a polymer solvated in a solvent, and a polymer solvated in a solvent with nanoparticles suspended therein.

16. The nanofiber sheet assembly of claim 1 , further comprising:
the nanofiber yarn forming a corresponding elongated depression in the inner surface of the nanofiber sheet and a corresponding elongated protuberance on the outer surface of the nanofiber sheet.

17. A nanofiber sheet assembly comprising:
a nanofiber yarn having a circumference and a length;
a nanofiber sheet in direct contact with the nanofiber yarn; and
an infiltrating material disposed within the nanofiber yarn and the nanofiber sheet, wherein the nanofiber yarn comprises a plurality of nanofiber yarns arranged into a spaced parallel array, and
nanofibers of the nanofiber sheet are aligned substantially parallel to one another along their longitudinal axes and end-to-end in a plane that is parallel to inner and outer surfaces of the nanofiber sheet,
wherein the nanofiber sheet is in direct contact with at least half of the circumference of the nanofiber yarn along at least some of the length of the nanofiber yarn.

18. A nanofiber sheet assembly comprising:
a nanofiber yarn having a circumference and a length;
a nanofiber sheet in direct contact with the nanofiber yarn; and
an infiltrating material disposed within the nanofiber yarn and the nanofiber sheet, wherein the nanofiber yarn comprises a plurality of nanofiber yarns woven into an orthogonal array, and
nanofibers of the nanofiber sheet are aligned substantially parallel to one another along their longitudinal axes and end-to-end in a plane that is parallel to inner and outer surfaces of the nanofiber sheet.

19. A method for fabricating a nanofiber sheet assembly comprising:
providing a nanofiber yarn having a circumference and a length;
placing a nanofiber sheet and the nanofiber yarn in contact with one another, wherein the nanofiber yarn has a surface topography corresponding to twisted fibers within the nanofiber yarn and at least a portion of the nanofiber sheet conforms to a surface topography of the nanofiber yarn, the nanofiber sheet having surface indentations in at least one of an inner surface and an outer surface of the nanofiber sheet; and
forming nanofibers of the nanofiber sheet to be aligned substantially parallel to one another along their longitudinal axes and end-to-end in a plane that is parallel to inner and outer surfaces of the nanofiber sheet, and
infiltrating an infiltration material into both of the nanofiber yarn and the nanofiber sheet to form a continuous network of the infiltration material throughout both of the nanofiber yarn and the nanofiber sheet.

20. The method of claim 19 , further comprising causing the nanofiber sheet to conform to at least half of the circumference of the nanofiber yarn along at least a portion of the length of the nanofiber yarn.

21. The method of claim 20 , wherein causing the nanofiber sheet to conform includes causing the nanofiber sheet to conform to a surface topography of the nanofiber yarn.

22. The method of claim 19 , wherein the infiltrating comprises infiltrating the infiltration material within a first plurality of interstitial spaces defined by nanofibers within the nanofiber yarn and a within a second plurality of interstitial spaces defined by nanofibers within the nanofiber sheet.

Assignees

• Lintec America Inc

Inventors

• Lima Marcio D

Classifications

• B32B2250/20

  All layers being fibrous or filamentary · CPC title

• B32B37/24

  with at least one layer not being coherent before laminating, e.g. made up from granular material sprinkled onto a substrate (B32B37/15 takes precedence) · CPC title

• B32B37/1284

  Application of adhesive · CPC title

• D06N7/0097

  Web coated with fibres, e.g. flocked · CPC title

• B32B2260/023

  Two or more layers · CPC title