Porous polyolefin fibers

Patent metadata

Field	Value
Publication number	US-11001944-B2
Application number	US-201414895064-A
Country	US
Kind code	B2
Filing date	Jun 6, 2014
Priority date	Jun 12, 2013
Publication date	May 11, 2021
Grant date	May 11, 2021

Abstract

A polyolefin fiber that is formed by a thermoplastic composition containing a continuous phase that includes a polyolefin matrix polymer and nanoinclusion additive is provided. The nanoinclusion additive is dispersed within the continuous phase as discrete nano-scale phase domains. When drawn, the nano-scale phase domains are able to interact with the matrix in a unique manner to create a network of nanopores.

First claim

What is claimed is:

1. A polyolefin fiber that is formed by drawing a thermoplastic composition, wherein the thermoplastic composition contains a continuous phase that includes a polyolefin matrix polymer and a polymeric nanoinclusion additive comprising a functionalized polyolefin that is a polyepoxide and a polymeric microinclusion additive dispersed within the continuous phase in the form of discrete domains, wherein the polymeric nanoinclusion additive is in the form of nano-scale domains and the polymeric microinclusion additive is in the form of micro-scale domains, wherein a porous network is defined in the drawn thermoplastic composition that includes a plurality of nanopores adjacent to the nanoscale domains and/or the micro-scale domains, the nanopores having an average cross-sectional dimension of about 800 nanometers or less;
wherein a ratio of a melt flow rate of the polyolefin matrix polymer to a flow rate of the polymeric nanoinclusion additive is from about 0.2 to about 8; and
wherein the fiber exhibits a peak tensile stress of from about 60 to about 600 MPa, as determined in accordance with ASTM D638-10 at 23° C.

2. The polyolefin fiber of claim 1 , wherein the nanopores have an average cross-sectional dimension of from about 5 to about 700 nanometers.

3. The polyolefin fiber of claim 1 , wherein the nanopores have an average axial dimension of from about 100 to about 5000 nanometers.

4. The polyolefin fiber of claim 1 , wherein the polyolefin matrix polymer has a melt flow rate of from about 0.5 to about 80 grams per 10 minutes, determined at a load of 2160 grams and at 230° C. in accordance with ASTM D1238.

5. The polyolefin fiber of claim 1 , wherein the polyolefin matrix polymer is a propylene homopolymer, propylene/α-olefin copolymer, ethylene/α-olefin copolymer, or a combination thereof.

6. The polyolefin fiber of claim 1 , wherein the polyolefin matrix polymer is an isotactic polypropylene homopolymer or a copolymer containing at least about 90% by weight propylene.

7. The polyolefin fiber of claim 1 , wherein the continuous phase constitutes from about 60 wt. % to about 99 wt. % of the thermoplastic composition.

8. The polyolefin fiber of claim 1 , wherein the polymeric nanoinclusion additive has melt flow rate of from about 0.1 to about 100 grams per 10 minutes, determined at a load of 2160 grams and at a temperature at least about 40° C. above the melting temperature in accordance with ASTM D1238.

9. The polyolefin fiber of claim 1 , wherein the nano-scale domains have an average cross-sectional dimension of from about 1 nanometer to about 1000 nanometers.

10. The polyolefin fiber of claim 1 , wherein the nanoinclusion additive constitutes from about 0.05 wt. % to about 20 wt. % of the composition, based on the weight of the continuous phase.

11. The polyolefin fiber of claim 1 , wherein the polymeric microinclusion additive is polylactic acid.

12. The polyolefin fiber of claim 1 , wherein the polymeric microinclusion additive has a glass transition temperature of about 0° C. or more.

13. The polyolefin fiber of claim 1 , wherein the polymeric microinclusion additive has a melt flow rate of from about 5 to about 200 grams per 10 minutes, determined at a load of 2160 grams and at a temperature of 210° C.

14. The polyolefin fiber of claim 1 , wherein the ratio of the melt flow rate of the polymeric microinclusion additive to the melt flow rate of the polyolefin matrix polymer is from about 0.5 to about 10.

15. The polyolefin fiber of claim 1 , wherein the ratio of the Young's modulus of elasticity of the polyolefin matrix polymer to the Young's modulus of elasticity of the polymeric microinclusion additive is from about 1 to about 250.

16. The polyolefin fiber of claim 1 , wherein the micro-scale domains have an average axial dimension of from about 1 micrometer to about 400 micrometers.

17. The polyolefin fiber of claim 1 , wherein the polymeric microinclusion additive constitutes from about 1 wt. % to about 30 wt. % of the composition, based on the weight of the continuous phase.

18. The polyolefin fiber of claim 1 , wherein the thermoplastic composition further comprises an interphase modifier.

19. The polyolefin fiber of claim 1 , wherein the porous network further includes micropores.

20. The polyolefin fiber of claim 1 , wherein the total pore volume of the polyolefin fiber is from about 15% to about 80% of the total volume of the fiber, as measured for one cubic centimeter of fiber.

21. The polyolefin fiber of claim 1 , wherein nanopores constitute about 20 vol. % or more of the total pore volume of the polyolefin fiber.

22. The polyolefin fiber of claim 1 , wherein after drawing, the thermoplastic composition has a density of about 0.90 g/cm 3 or less.

23. A nonwoven web comprising the polyolefin fiber of claim 1 .

24. A method for forming a polyolefin fiber, the method comprising:
forming a thermoplastic composition that contains a continuous phase that includes a polyolefin matrix polymer and a polymeric nanoinclusion additive comprising a functionalized polyolefin that is a polyepoxide and a polymeric microinclusion additive dispersed within the continuous phase in the form of discrete domains, wherein the polymeric nanoinclusion additive is in the form of nano-scale domains and the polymeric microinclusion additive is in the form of micro-scale domains;
extruding the composition through a die to form the fiber; and drawing the fiber at a temperature that is lower than the melting temperature of the matrix polymer, thereby forming a porous network that includes a plurality of nanopores adjacent to the nano-scale domains and/or the micro-scale domains, the nanopores having an average cross-sectional dimension of about 800 nanometers or less;
wherein a ratio of a melt flow rate of the polyolefin matrix polymer to a flow rate of the polymeric nanoinclusion additive is from about 0.2 to about 8;
wherein the fiber exhibits a peak tensile stress of from about 60 to about 600 MPa, as determined in accordance with ASTM D638-10 at 23° C.

25. The method of claim 24 , wherein the thermoplastic composition is stretched to a draw ratio of from about 1.1 to about 3.0.

26. A method for forming a nonwoven web, the method comprising:
forming a thermoplastic composition that contains a continuous phase that includes a polyolefin matrix polymer and a polymeric nanoinclusion additive comprising a functionalized polyolefin that is a polyepoxide and a polymeric microinclusion additive dispersed within the continuous phase in the form of discrete domains, wherein the polymeric nanoinclusion additive is in the form of nano-scale domains and the polymeric microinclusion additive is in the form of micro-scale domains;
extruding the blend through a die to form a plurality of fibers;
randomly depositing the plurality of fibers onto a surface to form a nonwoven web; and
drawing the fibers before and/or after the nonwoven web is formed at a temperature that is lower than the melting temperature of the matrix polymer, thereby forming a porous network that includes a plurality of nanopores adjacent to the nano-scale domains and/or the micro-scale domains, the nanopores having an average cross-sectional dimension of about 800 nanometers or less;
wherein a ratio of a melt flow rate of the polyolefin matrix polymer to a flow rate of the polymeric nanoinclusion additive is from about 0.2 to about 8

Assignees

• Kimberly Clark Co

Inventors

• Topolkaraev Vasily A
• Mceneany Ryan J
• Carrillo Antonio J
• Mleziva Mark M

Classifications

• B01D71/261

  Polyethylene · CPC title

• B01D69/087

  Details relating to the spinning process · CPC title

• B01D71/481

  Polyarylates · CPC title

• B01D71/262

  Polypropylene · CPC title

• B01D69/14111

  with nanoscale dispersed material, e.g. nanoparticles · CPC title