High-strength hot-dip galvanized steel sheet having excellent plating surface quality and adhesion, and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-11001918-B2
Application number	US-201715852629-A
Country	US
Kind code	B2
Filing date	Dec 22, 2017
Priority date	Dec 28, 2011
Publication date	May 11, 2021
Grant date	May 11, 2021

Abstract

Provided is a method of manufacturing a hot-dip galvanized steel sheet. According to an aspect of the present invention, the method may include preparing a base steel sheet, forming a iron (Fe)-plated layer on the prepared base steel sheet, oxidation heating the steel sheet having the Fe-plated layer formed thereon at a temperature ranging from 600° C. to 800° C., maintaining the heated steel sheet at a temperature ranging from 750° C. to 900° C. for 5 seconds or more in a reducing atmosphere with a dew point of between −30° C. to 5° C. including 20 ppm or less of oxygen, 1 vol % to 20 vol % of H2, and N2 as well as unavoidable gases as a remainder, cooling the maintained steel sheet, and plating the cooled steel sheet by dipping in a hot-dip galvanizing bath.

First claim

What is claimed is:

1. A method of manufacturing a hot-dip galvanized steel sheet, the method comprising:
preparing a base steel sheet;
forming an iron-plated layer on the base steel sheet to form an iron-plated steel sheet;
oxidation heating the iron-plated steel sheet at a temperature ranging from 600° C. to 800° C. to form a heated steel sheet;
maintaining the heated steel sheet at a temperature ranging from 750° C. to 900° C. for 5 seconds or more in a reducing atmosphere with a dew point of between −30° C. to 5° C. to form a maintained steel sheet, the reducing atmosphere including 20 ppm or less of oxygen, 1 vol % to 20 vol % of H 2 , and N 2 and unavoidable gases as a remainder, respectively based on a total volume of atmospheric gas;
cooling the maintained steel sheet to form a cooled steel sheet; and
dipping the cooled steel sheet in a hot-dip galvanizing bath to form the hot-dip galvanized steel sheet,
wherein the oxidation heating is performed in a direct flame furnace by controlling an air-fuel ratio; and the air-fuel ratio is controlled as follows: (1100/(C 0.09 ×T))+(100/T)≤air-fuel ratio≤(1450/(C 0.09 ×T))+(100/T) where C is a coating weight (mg/m 2 ) of the iron-plated layer and T is a temperature (° C.) of the direct flame furnace, or
wherein the oxidation heating is performed in a radiant tube flame furnace in an atmosphere having 5 vol % or less of H 2 , 20 ppm or less of O 2 and N 2 as a remainder, respectively based on a total volume of atmospheric gas; and an oxygen content in an oxidation region in the radiant tube flame furnace is controlled as follows:

(4000/(C 0.2 ×T 0.08 ))+(3500/T)≤oxygen content (ppm)≤(5800/(C 0.2 ×T 0.08 ))+(3850/T) where C is a coating weight (mg/m 2 ) of the iron-plated layer and Tis a temperature (° C.) of the radiant tube flame furnace.

2. The method of claim 1 , wherein the base steel sheet comprises: 0.3 wt % or less of carbon (C); and 1.0 wt % to 6.0 wt % of one or more of silicon (Si), manganese (Mn), and aluminum (Al).

3. The method of claim 1 , wherein the base steel sheet comprises: one or more of chromium (Cr), nickel (Ni), copper (Cu), molybdenum (Mo), phosphorous (P), sulfur (S), antimony (Sb), titanium (Ti), niobium (Nb), and nitrogen (N), wherein each of the one or more is contained in an amount of 0.5 wt % or less.

4. The method of claim 1 , wherein the coating weight is in a range of 0.2 g/m 2 to 2 g/m 2 .

5. The method of claim 1 , wherein the forming of the iron-plated layer is performed by using an electroplating method.

6. The method of claim 1 , wherein a temperature of the hot-dip galvanizing bath is in a range of 440° C. to 480° C.

7. The method of claim 1 , further comprising: heating the hot-dip galvanized steel sheet to a temperature ranging from 480° C. to 650° C.

Assignees

• Posco

Inventors

• Kim Myung-Soo
• Kim Jong-Sang
• Kim Young-Ha
• Park Joong-Chul

Classifications

• C23C28/3225

  with at least one zinc-based layer · CPC title

• C22C38/06

  containing aluminium · CPC title

• C23C2/06

  Zinc or cadmium or alloys based thereon · CPC title

• B32B15/013

  one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium · CPC title

• C23C28/36

  including layers graded in composition or physical properties · CPC title