PVC product and stabilizing agent thereof

Patent metadata

Field	Value
Publication number	US-11001701-B2
Application number	US-201916597906-A
Country	US
Kind code	B2
Filing date	Oct 10, 2019
Priority date	Nov 12, 2018
Publication date	May 11, 2021
Grant date	May 11, 2021

Abstract

A PVC product and a stabilizing agent thereof are provided. The stabilizing agent is composed of perchlorate, alkanolamine, and alkanolamide. The total amount of alkanolamine and alkanolamide in the stabilizing agent is 80-99 wt % of the total weight of the stabilizing agent, and the weight ratio of the total amount of alkanolamine and alkanolamide to the amount of perchlorate is 4:1 to 99:1, so that the PVC product has a lower Yellowness Index (YI) and higher transparency.

First claim

What is claimed is:

1. A stabilizing agent, comprising the following components in the following amounts based on the total weight of the stabilizing agent, and the sum of the amounts of the components being 100 wt %:
a) 1-20 wt % of perchlorate with the molecular formula of M(ClO 4 ) n , wherein M is lithium, sodium, potassium, magnesium, calcium, cesium, barium, zinc, aluminum, lanthanum, cerium, or a hydrotalcite layer-lattice cation; n is 1, 2, or 3, depending on the valence of M; and when M is a hydrotalcite layer-lattice cation, 0<n<1;
b) 30-98 wt % of alkanolamine; and
c) 1-50 wt % of alkanolamide;
wherein the alkanolamine is alkanolamine of the following formula (I),

the alkanolamide is alkanolamide of the following formula (II),

wherein R 1 is H, C 1 -C 22 alkyl, C 2 -C 22 alkenyl, C 2 -C 22 ether, C 2 -C 22 ester, C 2 -C 22 acylamino, C 2 -C 22 hydroxyl, C 4 -C 8 cycloalkyl (which is substituted with OH at β position), C 6 -C 10 aryl, or C 7 -C 10 alkaryl;
R 2 is H, C 1 -C 22 alkyl, C 2 -C 22 alkenyl, C 2 -C 22 ether, C 2 -C 22 ester, C 2 -C 22 acylamino, C 2 -C 22 hydroxyl, C 4 -C 8 cycloalkyl (which is substituted with OH at β position), C 6 -C 10 aryl, or C 7 -C 10 alkaryl;
R 3 is H, C 1 -C 22 alkyl, C 2 -C 22 alkenyl, C 6 -C 10 aryl, or CH 2 —X—R 6 , wherein X is O, S, —O—CO—, or —COO—;
R 4 is H, C 1 -C 22 alkyl, C 2 -C 22 alkenyl, C 6 -C 10 aryl, or CH 2 —X—R 6 , wherein X is O, S, —O—CO—, or —COO—;
R 5 is H or OH; and
R 6 is H, C 1 -C 22 alkyl, C 2 -C 22 alkenyl, or C 6 -C 10 aryl.

2. The stabilizing agent according to claim 1 , wherein the perchlorate has the molecular formula of NaClO 4 or KClO 4 .

3. The stabilizing agent according to claim 1 , wherein the perchlorate is zeolite.

4. The stabilizing agent according to claim 1 , wherein a weight ratio of the total amount of alkanolamine of formula (I) and alkanolamide of formula (II) to the perchlorate ranges between 4:1 and 99:1.

5. A PVC product, which is prepared by adding the stabilizing agent as claimed in claim 1 into a PVC.

6. The PVC product according to claim 5 , wherein the PVC product is a PVC pipe, a PVC sheet, or a PVC leather.

7. The PVC product according to claim 5 , wherein the total amount of alkanolamine of formula (I) and alkanolamide of formula (II) is 0.01-10 parts by weight based on 100 parts by weight of PVC.

8. The PVC product according to claim 5 , wherein the total amount of alkanolamine of formula (I) and alkanolamide of formula (II) is 0.05 to 5 parts by weight based on 100 parts by weight of PVC.

Assignees

• Nanya Plastics Corp

Inventors

• Liao Te-Chao
• Chuang Jung-Jen
• Huang zhi-ming

Classifications

• C08K3/26 Primary

  Carbonates; Bicarbonates · CPC title

• C08K3/24

  Acids; Salts thereof {(C08K3/16 takes precedence)} · CPC title

• C08K2003/343

  Peroxyhydrates, peroxyacids or salts thereof · CPC title

• C08K3/34

  Silicon-containing compounds · CPC title

• C08K5/17

  Amines; Quaternary ammonium compounds · CPC title