Porous polyether sulfone film and production method therefor

Patent metadata

Field	Value
Publication number	US-11001691-B2
Application number	US-201716320418-A
Country	US
Kind code	B2
Filing date	Jul 25, 2017
Priority date	Jul 25, 2016
Publication date	May 11, 2021
Grant date	May 11, 2021

Abstract

Provided are: a porous polyether sulfone film having macrovoids and having excellent dimensional stability; and a production method therefor. Provided is a porous polyether sulfone film having a surface layer (a), a surface layer (b), and a macrovoid layer interposed between the surface layer (a) and the surface layer (b). The macrovoid layer has a partition wall joined to the surface layers (a) and (b) and a plurality of macrovoids surrounded by the partition wall and the surface layers (a) and (b). The surface layer (a) and the surface layer (b) have pores connected to the macrovoids.

First claim

The invention claimed is:

1. A porous polyethersulfone film having a surface layer (a), a surface layer (b), and a macrovoid layer sandwiched between the surface layer (a) and the surface layer (b),
wherein the macrovoid layer has a partition wall bonded to the surface layers (a) and (b); and a plurality of macrovoids surrounded by the partition wall and the surface layers (a) and (b), the macrovoids having an average pore diameter in a film plane direction of 10 μm to 500 μm;
wherein the partition wall of the macrovoid layer has a thickness of 0.1 μm to 50 μm;
wherein each of the surface layers (a) and (b) has a thickness of 0.1 μm to 50 μm;
wherein one of the surface layers (a) and (b) has a plurality of fine pores having an average pore diameter of more than 5 μm and not more than 200 μm, while the other has a plurality of fine pores having an average pore diameter of not less than 0.01 μm and not more than 200 μm;
wherein a surface opening ratio of one of the surface layers (a) and (b) is not less than 15%, while the surface opening ratio of the other surface layer is not less than 10%;
wherein the fine pores in the surface layers (a) and (b) communicate with the plurality of macrovoids; and
wherein the porous polyethersulfone film has a total film thickness of 5 μm to 500 μm, and a porosity of 50% to 95%.

2. The porous polyethersulfone film according to claim 1 , wherein a mean flow pore diameter measured by a palm porometer is 5 to 200 μm.

3. The porous polyethersulfone film according to claim 1 , wherein the partition wall of the macrovoid layer, and the surface layers (a) and (b) have generally the same thickness.

4. The porous polyethersulfone film according to claim 1 , wherein a Gurley value is not more than 20 secs.

5. The porous polyethersulfone film according to claim 1 , wherein in a cross section of the porous polyethersulfone film cut perpendicularly to the film plane direction, a cross-sectional area of the macrovoid having an average pore diameter in the film plane direction of 10 μm to 500 μm is not less than 50% of a film cross-sectional area.

6. The porous polyethersulfone film according to claim 1 , wherein in a cross section of the porous polyethersulfone film cut perpendicularly to the film plane direction, not less than 60% of a total number of the macrovoids has a ratio (L/d) of 0.5 to 3 of a length (L) in the film plane direction to a length (d) in the film thickness direction.

7. The porous polyethersulfone film according to claim 1 , wherein a glass transition temperature of the porous polyethersulfone film is 200° C. or higher, or a clear transition temperature of the porous polyethersulfone film is not observed.

8. The method for manufacturing a porous polyethersulfone film according to claim 1 , the method comprising the steps of:
casting a polyethersulfone solution (A) containing 0.3% by mass to 60% by mass of a polyethersulfone having a logarithmic viscosity of 0.5 to 1.0, and 40% by mass to 99.7% by mass of an organic polar solvent in a film shape, and dipping or bringing into contact with a coagulating solvent containing a nonsolvent of polyethersulfone as an essential component to fabricate a coagulated film having a vacancy; and
performing a heat treatment of the coagulated film having a vacancy obtained in the step to coarsen the vacancy to obtain a porous polyethersulfone film;
wherein the heat treatment comprises heating up the coagulated film having the vacancy to a glass transition temperature of the polyethersulfone or higher, or to 240° C. or higher.

9. The method for manufacturing a porous polyethersulfone film according to claim 8 , wherein the heat treatment is performed at a heating rate of 10° C./min or higher in a temperature region of 80° C. or higher.

10. The method for manufacturing a porous polyethersulfone film according to claim 1 ,
the method comprising the steps of:
casting a polyethersulfone solution (A) containing 0.3% by mass to 60% by mass of a polyethersulfone having a logarithmic viscosity of 0.5 to 1.0, and 40% by mass to 99.7% by mass of an organic polar solvent in a film shape, and dipping or bringing into contact with a coagulating solvent containing water as an essential component to fabricate a coagulated film having a vacancy; and
performing a heat treatment of the coagulated film having a vacancy obtained in the step to coarsen the vacancy to obtain a porous polyethersulfone film;
wherein the heat treatment comprises heating up the coagulated film having the vacancy to a glass transition temperature of the polyethersulfone or higher, or to 240° C. or higher.

11. The method for manufacturing a porous polyethersulfone film according to claim 10 , wherein a ratio of water in the coagulating solvent is 20% by mass to 100% by mass.

Assignees

• Ube Industries

Inventors

• Ohya Shusei
• Matsuo Makoto
• Bamba Keita

Classifications

• B01D67/00165

  Composition of the coagulation baths · CPC title

• C12M29/04

  Filters; Permeable or porous membranes or plates, e.g. dialysis · CPC title

• C08J2381/06

  Polysulfones; Polyethersulfones · CPC title

• C08J2201/0544

  the non-solvent being aqueous · CPC title

• C08J9/28 Primary

  by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum · CPC title