Separation membrane coating agent composition, separation membrane made from coating agent composition, and battery using same
US-2015207123-A1 · Jul 23, 2015 · US
US11001672B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11001672-B2 |
| Application number | US-201716099871-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 1, 2017 |
| Priority date | May 11, 2016 |
| Publication date | May 11, 2021 |
| Grant date | May 11, 2021 |
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Embodiments of the present disclosure include, a dianhydride monomer, a polyimide, a method of making a dianhydride, a method of making a polyimide, and the like. Embodiments of the present disclosure can be used in membrane-based gas separation applications.
Opening claim text (preview).
We claim: 1. A microporous polyimide comprising the following structure: wherein n is an integer, wherein each X is independently selected from the group consisting of H, a halogen, an alkyl group, an aryl group, and a heteroaryl group, wherein Y is a bivalent organic group selected from the group consisting of: wherein R is an alkyl group and each R 1 , and R 2 are independently selected from the group consisting of: H, a halogen, and an alkyl group, wherein when the bond is directed to the middle of a ring, this indicates that, optionally, 1 to 4 R 1 or R 2 groups are attached to the ring and each R 1 or R 2 group is independently selected. 2. The microporous polyimide of claim 1 , wherein the microporous polyimide is selected from the group consisting of: 3. The microporous polyimide of claim 1 , wherein the microporous polyimide has a BET surface area of at least 100 m 2 /g. 4. The microporous polyimide of claim 1 , wherein the microporous polyimide has a BET surface area of about 100 m 2 /g to 1000 m 2 /g. 5. The microporous polyimide of claim 1 , wherein Y is SBI. 6. The microporous polyimide of claim 1 , wherein Y is SBF. 7. The microporous polyimide of claim 1 , wherein Y is BIN. 8. The microporous polyimide of claim 1 , wherein Y is TP. 9. The microporous polyimide of claim 1 , wherein Y is TB. 10. The microporous polyimide of claim 1 , wherein the microporous polyimide forms a membrane for performing gas separations, wherein the membrane-based gas separations include separations of gases selected from the group consisting of: O 2 /N 2 gas separations; H 2 /N 2 gas separations; H 2 /C 1+ hydrocarbons gas separations; He/C 1+ hydrocarbons gas separations; CO 2 /C 1+ hydrocarbons gas separations; CO 2 /N 2 gas separations; and olefins/paraffins gas separations.
Polyimides; Polyamide-imides; Polyester-imides; Polyamide acids or similar polyimide precursors · CPC title
Polyimides with diamino moieties or tetracarboxylic segments containing heterocyclic moieties · CPC title
Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule · CPC title
from tetracarboxylic acids or derivatives and diamines · CPC title
characterised by the solvent(s) used · CPC title
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