Sizing composition for wet use chopped strand glass fibers

Patent metadata

Field	Value
Publication number	US-11001525-B2
Application number	US-201716306598-A
Country	US
Kind code	B2
Filing date	Jun 15, 2017
Priority date	Jun 17, 2016
Publication date	May 11, 2021
Grant date	May 11, 2021

Abstract

A sizing composition including water, a polyvinylpyrrolidone film former, a silane coupling agent, a lubricant, and a surfactant is provided. The polyvinylpyrrolidone film former constitutes from 30 wt. % to 50 wt. % of the dry solids of the sizing composition. Wet use chopped strand glass fibers for use in reinforcing gypsum board are also provided. The wet use chopped strand glass fibers include chopped glass fibers having the sizing composition applied thereto. The sizing composition improves fiber bundle integrity, fiber flow rate, fiber flow rate consistency, and dispersibility of the wet use chopped strand glass fibers in a gypsum matrix or slurry.

First claim

What is claimed is:

1. A sizing composition comprising:
water;
a polyvinylpyrrolidone film former having a weight average molecular weight of 1,000,000 Da to 1,700,000 Da;
a silane coupling agent;
a lubricant comprising a condensation reaction product of a saturated fatty acid having at least 16 carbon atoms and a polyamine; and
a surfactant;
wherein the polyvinylpyrrolidone film former comprises from 30 wt. % to 50 wt. % of the dry solids of the sizing composition, and
wherein a weight ratio based on dry solids of the polyvinylpyrrolidone film former to the lubricant is from 0.8:1 to 1.7:1.

2. The sizing composition according to claim 1 , wherein the lubricant comprises from 30 wt. % to 50 wt. % of the dry solids of the sizing composition.

3. The sizing composition according to claim 1 , wherein the saturated fatty acid is stearic acid and the polyamine is tetraethylenepentamine.

4. The sizing composition according to claim 1 , wherein the silane coupling agent comprises from 2 wt. % to 10 wt. % of the dry solids of the sizing composition.

5. The sizing composition according to claim 1 , wherein the silane coupling agent is selected from the group consisting of an amino silane, a methacryloxy silane, a silane ester, a vinyl silane, an epoxy silane, a sulfur silane, a ureido silane, an isocyanato silane, an azamido silane, and combinations thereof.

6. The sizing composition according to claim 1 , wherein the silane coupling agent comprises γ-aminopropyltriethoxysilane.

7. The sizing composition according to claim 1 , wherein the surfactant comprises from 5 wt. % to 15 wt. % of the dry solids of the sizing composition.

8. The sizing composition according to claim 1 , wherein the surfactant comprises at least one of a polyethylene glycol fatty acid ester, a poloxamer, or a poloxamine.

9. The sizing composition according to claim 8 , wherein the polyethylene glycol fatty acid ester is polyethylene glycol monooleate, and wherein the polyethylene glycol moiety has a molecular weight of 380 Da to 420 Da.

10. The sizing composition according to claim 1 , wherein the sizing composition has a total solids content of 0.5 wt. % to 10 wt. %.

11. The sizing composition according to claim 1 , wherein the lubricant comprises a condensation reaction product of stearic acid and tetraethylenepentamine.

12. Glass fibers for use in reinforcing gypsum board, the glass fibers comprising:
a plurality of chopped glass fibers coated with a sizing composition, wherein the sizing composition comprises:
water;
a polyvinylpyrrolidone film former having a weight average molecular weight of 1,000,000 Da to 1,700,000 Da;
a silane coupling agent;
a lubricant comprising a condensation reaction product of a saturated fatty acid having at least 16 carbon atoms and a polyamine; and
a surfactant;
wherein the polyvinylpyrrolidone film former comprises from 30 wt. % to 50 wt. % of the dry solids of the sizing composition;
wherein a weight ratio based on dry solids of the polyvinylpyrrolidone film former to the lubricant is from 0.8:1 to 1.7:1; and
wherein the sizing composition is present on the chopped glass fibers in an amount of from 0.05% to 0.3% by weight based on the total weight of the sized chopped glass fibers.

13. The glass fibers according to claim 12 , wherein the chopped glass fibers have a moisture content of 2 wt. % to 15 wt. %.

14. The glass fibers according to claim 12 , wherein the lubricant comprises a condensation reaction product of stearic acid and tetraethylenepentamine.

15. The glass fibers according to claim 12 , wherein the surfactant comprises at least one of a polyethylene glycol fatty acid ester, a poloxamer, or a poloxamine.

16. A gypsum board comprising:
a gypsum layer having a first major surface and a second major surface, the gypsum layer comprising gypsum and a plurality of chopped glass fibers coated with a sizing composition distributed in the gypsum, wherein the sizing composition comprises:
water;
a polyvinylpyrrolidone film former having a weight average molecular weight of 1,000,000 Da to 1,700,000 Da;
a silane coupling agent;
a lubricant comprising a condensation reaction product of a saturated fatty acid having at least 16 carbon atoms and a polyamine; and
a surfactant;
wherein the polyvinylpyrrolidone film former comprises from 30 wt. % to 50 wt. % of the dry solids of the sizing composition;
wherein a weight ratio based on dry solids of the polyvinylpyrrolidone film former to the lubricant is from 0.8:1 to 1.7:1;

a first facing layer applied to the first major surface of the gypsum layer; and
a second facing layer applied to the second major surface of the gypsum layer.

17. The gypsum board according to claim 16 , wherein the lubricant comprises from 30 wt. % to 50 wt. % of the dry solids of the sizing composition.

18. The gypsum board according to claim 16 , wherein the lubricant comprises a condensation reaction product of stearic acid and tetraethylenepentamine.

19. The gypsum board according to claim 16 , wherein the surfactant comprises at least one of a polyethylene glycol fatty acid ester, a poloxamer, or a poloxamine.

Assignees

• Owens Corning Intellectual Capital Llc

Inventors

• Huang Helen
• Tazi Mohammed

Classifications

• E04C5/073

  Discrete reinforcing elements, e.g. fibres · CPC title

• E04C2/06

  reinforced · CPC title

• C08L39/06

  Homopolymers or copolymers of N-vinyl-pyrrolidones · CPC title

• C08K5/17

  Amines; Quaternary ammonium compounds · CPC title

• C08K5/09

  Carboxylic acids; Metal salts thereof; Anhydrides thereof · CPC title