Fractionation system using compact co-current contacting systems

Patent metadata

Field	Value
Publication number	US-11000795-B2
Application number	US-201815964866-A
Country	US
Kind code	B2
Filing date	Apr 27, 2018
Priority date	Jun 15, 2017
Publication date	May 11, 2021
Grant date	May 11, 2021

Abstract

A fractionation system for removing heavy hydrocarbons in a gas stream. A stripping section receives a predominantly liquid phase of a feed gas stream. First and second co-current contacting systems are located in-line within a pipe. The first co-current contacting system receives a predominantly vapor phase of the feed gas stream. Each co-current contacting system includes a co-current contactor and a separation system. Each co-current contactor includes a droplet generator and a mass transfer section. The droplet generator generates droplets from a liquid and disperses the droplets into a gas stream. The mass transfer section provides a mixed, two-phase flow having a vapor phase and a liquid phase. The separation system separates the vapor phase from the liquid phase.

First claim

What is claimed is:

1. A fractionation system for removing heavy hydrocarbons in a gas stream, comprising:
a feed gas inlet through which a feed gas stream is introduced, wherein the feed gas stream is subsequently separated into a predominantly liquid phase and a predominantly vapor phase;
a stripping section configured to receive the predominantly liquid phase of the feed gas stream; and
first and second co-current contacting systems located in-line within a pipe, the first co-current contacting system configured to receive the predominantly vapor phase of the feed gas stream, each of the first and second co-current contacting systems comprising:
a co-current contactor including a droplet generator and a mass transfer section, the droplet generator configured to generate droplets from a liquid and to disperse the droplets into a gas stream, and the mass transfer section configured to provide a mixed, two-phase flow having a vapor phase and a liquid phase; and
a separation system configured to separate the vapor phase from the liquid phase;

wherein the second co-current contacting system is configured to receive the vapor phase of the co-current contactor in the first co-current contacting system, and wherein the droplet generator of the first co-current contacting system is configured to receive the liquid phase of the co-current contactor in the second co-current contacting system; and further comprising:
an in-line flash separator arranged to receive the predominantly vapor phase of the feed gas stream prior to said predominantly vapor phase being sent through the first co-current contacting system, the in-line flash separator configured to separate liquids from the predominantly vapor phase.

2. The fractionation system of claim 1 , further comprising a flash reflux line connected to the in-line flash separator and to the stripping section, the flash reflux line configured to convey liquids separated from the predominantly vapor phase in the in-line flash separator to the stripping section.

3. The fractionation system of claim 1 , wherein the in-line flash separator comprises a cyclonic separator.

4. The fractionation system of claim 1 , further comprising an agglomerator situated at an input of the in-line flash separator.

5. The fractionation system of claim 1 , wherein the separation system of at least one of the first and second co-current contacting systems comprises a cyclonic separator.

6. The fractionation system of claim 1 , wherein the feed gas stream comprises a natural gas stream, and wherein the heavy hydrocarbons comprise at least one of propane, butane, hexane, and heptane.

7. The fractionation system of claim 1 , further comprising:
a plurality of co-current contacting systems connected in series, said plurality of co-current contacting systems including the first and second co-current contacting systems and a last co-current contacting system; and
a reflux drum configured to receive a vapor phase from the last co-current contacting system and separate a reflux liquid from said vapor phase;
wherein the last co-current contacting system comprises
a co-current contactor including a droplet generator and a mass transfer section, the droplet generator configured to generate droplets from the reflux liquid and to disperse the droplets into a gas stream received from a previous co-current contacting system, and the mass transfer section configured to provide a mixed, two-phase flow having a vapor phase and a liquid phase; and
a separation system configured to separate the vapor phase from the liquid phase, wherein the vapor phase is sent to the reflux drum and the liquid phase comprises the liquid from which droplets are generated in a co-current contactor of a previous co-current contacting system.

8. The fractionation system of claim 7 , further comprising a reflux cooler situated between the last co-current contacting system and the reflux drum, the reflux cooler configured to cool the vapor phase of the last co-current contacting system prior to being sent to the reflux drum.

9. The fractionation system of claim 1 , wherein the droplet generator in the co-current contactor in at least one of the first and second co-current contacting systems comprises:
an annular support ring securing the droplet generator in-line within the pipe;
a plurality of spokes extending from the annular support ring, the annular support ring having a plurality of liquid channels configured to allow a liquid stream to flow through the plurality of spokes and out of injection orifices disposed on the plurality of spokes; and
a gas entry cone supported by the plurality of spokes and configured to allow
a first portion of the predominantly vapor phase of the feed gas stream to flow through a hollow section of the gas entry cone and through gas exit slots included in the plurality of spokes, and
a second portion of the predominantly vapor phase of the feed gas stream to flow around the gas entry cone and between the plurality of spokes, wherein the second portion of the gas stream is separate from the first portion of the gas stream.

10. The fractionation system of claim 9 , wherein a downstream portion of the gas entry cone comprises a blunt ended cone.

11. The fractionation system of claim 9 , wherein a downstream portion of the gas entry cone comprises a tapered ended cone.

12. A method of removing heavy hydrocarbons in a gas stream, comprising:
introducing a feed gas stream into a feed gas inlet, wherein the feed gas stream is subsequently separated into a predominantly liquid phase and a predominantly vapor phase;
receiving the predominantly liquid phase of the feed gas stream into a stripping section;
receiving the predominantly vapor phase of the feed gas stream into a first co-current contacting system located in-line within a pipe with a second co-current contacting system, each of the first and second co-current contacting systems comprising a co-current contactor including a droplet generator and a mass transfer section, and a separation system;
using each droplet generator, generating droplets from a liquid and dispersing the droplets into a gas stream;
in each mass transfer section, providing a mixed, two-phase flow having a vapor phase and a liquid phase; and
in each separation system, separating the vapor phase from the liquid phase;
wherein the second co-current contacting system is configured to receive the vapor phase of the co-current contactor in the first co-current contacting system, and wherein the droplet generator of the first co-current contacting system is configured to receive the liquid phase of the co-current contactor in the second co-current contacting; and further comprising:
receiving the predominantly vapor phase of the feed gas stream in an in-line flash separator prior to sending the predominantly vapor phase through the first co-current contacting system; and
separating liquids from the predominantly vapor phase in the in-line flash separator.

13. The method of claim 12 , wherein the droplet generator in the co-current contactor in at least one of the first and second co-current contacting systems includes an annular support ring securing the droplet generator in-line within the pipe, a plurality of spokes extending from the annular support ring, and a gas entry cone supported by the plurality of spokes, the method further comprising:
flowing a liquid stream through liquid channels disposed in the annular support ring, through the plurality of spokes, and out of injection orifices disposed on the plurality of spokes; and
flowing a first portion of the predominantly vapor phase of the feed gas stream th

Assignees

• Yeh Norman K
• Grave Edward J
• Ramkumar Shwetha
• Juarez Juan C
• Exxonmobil Upstream Res Co

Inventors

• Yeh Norman K
• Grave Edward J
• Ramkumar Shwetha
• Juarez Juan C

Classifications

• B01D3/143 Primary

  by two or more of a fractionation, separation or rectification step · CPC title

• B01D53/18

  Absorbing units; Liquid distributors therefor (B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32) · CPC title

• C10L3/101

  Removal of contaminants · CPC title

• C10L2290/545

  Washing, scrubbing, stripping, scavenging for separating fractions, components or impurities during preparation or upgrading of a fuel · CPC title

• B01D53/1406 Primary

  Multiple stage absorption · CPC title