System and method for rare gas recovery

Patent metadata

Field	Value
Publication number	US-10995982-B2
Application number	US-201716063467-A
Country	US
Kind code	B2
Filing date	Jan 4, 2017
Priority date	Jan 11, 2016
Publication date	May 4, 2021
Grant date	May 4, 2021

Abstract

A system and method for argon and nitrogen extraction and liquefaction from a low-pressure tail gas of an ammonia production plant is provided. The preferred tail gas of the ammonia production plant comprises methane, nitrogen, argon, and hydrogen. The disclosed system and method provides for the methane rejection via rectification and hydrogen rejection by way of a side stripper column or phase separator. The resulting nitrogen and argon containing stream is separated and liquefied in a double column distillation system.

First claim

What is claimed is:

1. A method for recovering xenon or krypton from a pre-purified feed gas comprising hydrogen, nitrogen, methane, argon, and xenon or krypton, the method comprising the steps of:
directing the pre-purified feed gas to a rectification column;
separating the pre-purified feed gas in the rectification column to produce a methane rich liquid column bottoms containing the xenon or krypton and an argon depleted, hydrogen-nitrogen rich gas overhead;
expanding the methane rich liquid column bottoms to yield a methane rich, two phase stream comprising greater than 90% vapor fraction;
warming the methane rich, two phase stream to at or near saturation;
directing the warmed, methane rich, two phase stream and a rare gas lean stream to an auxiliary wash column, wherein the rare gas lean stream is either (i) a liquid stream extracted from the rectification column, or (ii) a liquid nitrogen stream;
rectifying the warmed, methane rich, two phase stream and the rare gas lean stream in the auxiliary wash column to produce a liquid bottoms rare gas concentrate and a methane rich overhead; and
separating xenon or krypton from the liquid bottoms rare gas concentrate to produce a xenon or krypton stream.

2. The method of claim 1 , wherein the pre-purified feed gas contains greater than about 50% nitrogen by mole fraction.

3. The method of claim 1 wherein the pre-purified feed gas is a high pressure feed gas having a pressure of between about 300 psia to 500 psia.

4. The method of claim 1 wherein the pre-purified feed gas is a low pressure feed gas having a pressure of less than or equal to about 150 psia.

5. The method of claim 1 , further comprising the step of directing the argon depleted, hydrogen-nitrogen rich gas overhead back to the rectification column.

6. The method of claim 1 , wherein the pre-purified feed gas is a tail gas from an ammonia plant.

7. The method of claim 6 , further comprising the step of directing the argon depleted, hydrogen-nitrogen rich gas overhead back to the ammonia plant.

8. The method of claim 6 , further comprising the step of directing the argon depleted, hydrogen-nitrogen rich gas overhead back to a synthesis gas stream in the ammonia plant.

9. The method of claim 6 , further comprising the step of directing the methane rich overhead from the auxiliary wash column back to the ammonia plant.

10. The method of claim 6 , further comprising the step of directing the argon depleted, hydrogen-nitrogen rich gas overhead back to a cryogenic purifier in the ammonia plant.

11. The method of claim 10 wherein the methane rich overhead from the auxiliary wash column is recycled as a fuel gas back to a steam reforming section of the ammonia product plant.

Assignees

• Praxair Technology Inc

Inventors

• Howard Henry E

Classifications

• F25J2270/42

  Quasi-closed internal or closed external nitrogen refrigeration cycle · CPC title

• F25J2215/36

  Xenon · CPC title

• F25J2215/34

  Krypton · CPC title

• F25J3/028

  separation of noble gases (from air F25J3/04642; in general C01B23/00) · CPC title

• F25J2200/06

  in a classical double column flow-sheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column · CPC title