Lignocellulosic composites prepared with aqueous alkaline and urea solutions in cold temperatures systems and methods

Patent metadata

Field	Value
Publication number	US-10995452-B2
Application number	US-201715429058-A
Country	US
Kind code	B2
Filing date	Feb 9, 2017
Priority date	Feb 9, 2016
Publication date	May 4, 2021
Grant date	May 4, 2021

Abstract

Unique, inexpensive, and strong biocomposites are obtained from blending cellulose matrix materials with lignocellulosic reinforcement materials with the aid of alkaline aqueous solvent and cold temperatures. These lignocellulosic composites (LCs) are produced without use of any thermoplastic resins, adhesives, catalysts, plasticizers or complicated chemical or physical procedures. The LCs include a matrix and a reinforcement material. The matrix is a cellulose material (e.g., cotton, hemp, flax, or wood) that is liquefied using an aqueous alkaline solvent solution under cold temperatures to more readily adhere and/or incorporate/encapsulate the lignocellulosic reinforcements (wood chips, fibers, and other lignocellulosic sources).

First claim

What is claimed is:

1. A method of producing a lignocellulosic composite, the method comprising:
providing an alkaline solution comprising a predetermined volume of solvent, a predetermined volume of urea and a predetermined volume of water, said alkaline solution having a measurable temperature;
adding or removing heat to adjust the measurable temperature of the alkaline solution to a predetermined temperature, wherein the predetermined temperature is negative 10 degrees Celsius or lower;
combining a predetermined quantity of cellulose with the alkaline solution at said predetermined temperature to form a cellulose matrix gel;
combining a predetermined quantity of reinforcement material that comprises lignin and hemicellulose with the cellulose matrix gel;
removing substantially all of the solvent and urea by solvent exchange in water to form a dough;
molding the dough into a predetermined shape; and then
drying the dough,

wherein the predetermined quantity of cellulose is in the range of 15% to 35%, expressed as a percentage of a total of a combination of the predetermined quantity of cellulose and the predetermined quantity of reinforcement material, and
wherein the predetermined quantity of reinforcement material is in the range of 65% to 85%, expressed as a percentage of a total of a combination of the predetermined quantity of cellulose and the predetermined quantity of reinforcement material.

2. The method of claim 1 , wherein the predetermined temperature to which the alkaline solution is lowered is in the range of negative 15 degrees Celsius to negative 10 degrees Celsius.

3. The method of claim 1 , wherein the solvent comprises a metal alkaline salt.

4. The method of claim 1 , wherein the solvent comprises one or more of LiOH H 2 O, NaOH, or KOH.

5. The method of claim 1 , wherein at least 10% (by mass) of the predetermined volume of solvent comprises LiOH or other metal alkaline salt.

6. The method of claim 1 , wherein the predetermined volume of urea is in the range of 10% to 30% (by volume) of the alkaline solution.

7. The method of claim 1 , wherein the predetermined quantity of cellulose is 25% and the predetermined quantity of reinforcement material is 75%.

8. The method of claim 7 , wherein the cellulose is cotton and the reinforcement material is milled Osage orange wood (OOW).

9. The method of claim 7 , wherein the cellulose is cotton and the reinforcement material is agave fibers (AF).

10. The method of claim 7 , wherein the cellulose is cotton and the reinforcement material is 50/50 OOW/AF.

11. The method of claim 1 , wherein before the removing substantially all of the solvent and urea step, the combination of the reinforcement material and cellulose matrix gel is formed into a mold.

12. The method of claim 1 , wherein the step of combining the predetermined quantity of refined cellulose with the alkaline solution at said predetermined temperature to form the cellulose matrix gel is performed in a vacuum.

13. The method of claim 1 , wherein the step of drying the dough is performed in a vacuum.

14. The method of claim 1 , wherein the step of drying the dough is performed in an oven.

15. The method of claim 1 , wherein the cellulose comprises any one or more of cardboard, nanocellulose, crystalline cellulose, flax, cotton, recycled cotton, waste cotton, waste and stationary cellulosic fibers, shredded books, paper bags, paper towels, and stationary paper.

16. The method of claim 1 , wherein the reinforcement material comprises any one or more of wood flour, wood fibers, lumber strips, wood chips, wood sawdust, agricultural stem and branch waste materials, flax fibers, hemp fibers, Kenaf fibers, corn fibers, recycled cotton, waste cotton, press cakes derived from oil seeds, dried distiller's grain, miscellaneous cotton ginning mill waste, Kenaf fibers, shredded books, paper bags, paper towels, stationary paper, woven processed mats, non-woven processed mats, and linings or bagging obtained from tree, herbs and crops.

17. The method of claim 1 , wherein the reinforcement material comprises small particles.

18. The method of claim 1 , wherein the reinforcement material comprises high aspect ratio fibers.

19. The method of claim 1 , wherein the reinforcement material comprises low aspect ratio chips.

20. The method of claim 1 , further comprising: combining the cellulose matrix gel with a functional material.

21. The method of claim 20 , wherein said functional material is any one of magnetic particles, conductive carbons, fire retardant clays, conductive polymers, microbiologicals or insecticides.

22. The method of claim 1 , wherein the cellulose after being combined with the alkaline solution to form a cellulose matrix gel is only partially dissolved.

Assignees

• Tisserat Brent H
• Haverhals Luke
• Liu Zengshe
• Bradley Univ
• Us Agriculture

Inventors

• Tisserat Brent H
• Haverhals Luke
• Liu Zengshe

Classifications

• D21C3/02 Primary

  with inorganic bases or alkaline reacting compounds, e.g. sulfate processes · CPC title

• C08L2201/06

  Biodegradable · CPC title

• C08L97/02

  Lignocellulosic material, e.g. wood, straw or bagasse {(manufacture of articles made from lignocellulosic material by dry processes B27N)} · CPC title

• D21C3/20

  with organic solvents {or in solvent environment} · CPC title

• D21J3/00

  Manufacture of articles by pressing wet fibre pulp, or papier-mâché, between moulds · CPC title