Graphene fiber and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-10995428-B2
Application number	US-201816156367-A
Country	US
Kind code	B2
Filing date	Oct 10, 2018
Priority date	Apr 11, 2016
Publication date	May 4, 2021
Grant date	May 4, 2021

Abstract

A method of manufacturing a graphene fiber is provided. The method includes preparing a source solution including graphene oxide, supplying the source solution into a base solution containing a foreign element to form a graphene oxide fiber, separating the graphene fiber from the base solution and cleaning and drying to obtain the graphene oxide fiber containing the foreign element, and performing thermal treatment to the dried graphene oxide fiber containing the foreign element to form a graphene fiber doped with the foreign element. Elongation percentage of the graphene fiber is adjusted by concentration and spinning rate of the source solution.

First claim

What is claimed is:

1. A method of manufacturing a graphene fiber, the method comprising:
preparing a source solution including graphene oxide;
supplying the source solution into a base solution containing a foreign element to form a graphene oxide fiber;
separating the graphene fiber from the base solution and cleaning and drying to obtain the graphene oxide fiber containing the foreign element; and
performing thermal treatment to the dried graphene oxide fiber containing the foreign element to form a graphene fiber doped with the foreign element,
wherein elongation percentage of the graphene fiber is adjusted by concentration and spinning rate of the source solution.

2. The method of claim 1 , wherein the elongation percentage of the graphene fiber increases as increasing the concentration of the graphene oxide in the source solution.

3. The method of claim 1 , wherein the elongation percentage of the graphene fiber increases as decreasing the spinning rate of the source solution.

4. The method of claim 1 , wherein the obtaining of the graphene oxide fiber containing the foreign element further comprises:
drying the graphene oxide fiber simultaneously with winding.

5. The method of claim 4 , wherein the elongation percentage of the graphene fiber increases when a spinning rate of the source solution is higher than a winding rate of the graphene oxide containing the foreign element.

6. The method of claim 1 , wherein the forming of the graphene fiber comprises:
reducing the graphene oxide fiber into the graphene fiber through the thermal treatment simultaneously with doping the graphene fiber with the foreign element in the graphene oxide fiber.

7. A method of manufacturing a graphene fiber, the method comprising:
preparing a source solution including graphene oxide sheet;
supplying the source solution into a coagulation bath which includes a reducing agent partially reducing the graphene oxide sheet and a binder binding the graphene oxide sheets to obtain the graphene oxide binder;
reducing the graphene oxide fiber to form a graphene fiber; and
plating the graphene fiber with copper to form a copper plated graphene fiber.

8. The method of claim 7 , wherein the graphene oxide sheet is partially reduced by the reducing agent to form a partially reduced graphene oxide, and
wherein π-π stacking in the partially reduced graphene oxide sheets increases to increase tensile strength of the graphene oxide fiber.

9. The method of claim 7 , wherein the binder comprises a divalent or trivalent metallic ion.

10. The method of claim 7 , wherein the forming of the copper plated graphene fiber comprises:
etching the graphene fiber;
combining a catalyst metal with the graphene fiber; and
soaking the graphene fiber combined with the catalyst metal into a solution containing copper to plate the graphene fiber with copper using the method of reducing the copper by the catalyst metal.

11. The method of claim 7 , wherein the copper plated graphene fiber comprises pores provided between the graphene sheets which are reduced graphene oxide sheets, or a copper structure provided on a surface of the graphene fiber.

12. The method of claim 7 , wherein the forming of the graphene fiber comprises:
drying the graphene oxide fiber;
cleaning and drying the dried graphene oxide fiber; and
soaking the cleaned and dried graphene oxide fiber into a reducing solution and performing thermal treatment to reduce the graphene oxide fiber.

13. A method of manufacturing a graphene fiber, the method comprising:
preparing a source solution including graphene oxide sheet;
supplying the source solution into a coagulation bath which includes a reducing agent partially reducing the graphene oxide sheet and a binder binding the graphene oxide sheets to obtain the graphene oxide binder; and
reducing the graphene oxide fiber to form a graphene fiber
wherein the source solution further comprises a carbon nanotube, and the graphene fiber further comprises the carbon nanotube.

14. A method of manufacturing a graphene fiber, the method comprising:
reacting a graphene oxide, oxidizing agent and pH adjusting agent after adding into a solvent to prepare a source solution in which a graphene oxide with pores;
supplying the source solution into a base solution containing a foreign element to form a source oxide fiber;
cleaning and drying the graphene oxide fiber after separating from the base solution to obtain a graphene oxide fiber containing the foreign element;
performing thermal treatment to the dried graphene oxide fiber containing the foreign element to form a graphene fiber doped with the foreign element; and
reacting the graphene fiber with an aqueous solution containing a first oxidizing agent to form micro pores in the graphene fiber.

15. The method of claim 14 , wherein porosity of the graphene oxide increases as increasing content of the oxidizing agent in the source solution.

16. The method of claim 14 , wherein porosity of the graphene oxide increases as increasing pH of the source solution.

17. The method of claim 14 , wherein porosity of the micro pores which is formed in the graphene fiber is adjusted by content of the first oxidizing agent in the aqueous solution, and time and temperature of the reaction.

18. The method of claim 14 , wherein porosity in the graphene oxide in the source solution is adjusted by the oxidizing agent in the source solution, pH of the source solution and reaction temperature.

19. The method of claim 14 , wherein the forming of the graphene fiber comprises:
reducing the graphene oxide fiber into the graphene fiber through the thermal treatment simultaneously with doping the graphene fiber with the foreign element in the graphene oxide fiber, and
wherein electric conductivity of the graphene fiber is adjusted by content of the foreign element doped to the graphene fiber.

Assignees

• Iucf Hyu

Inventors

• Han Tae Hee
• Park Hun

Classifications

• D01D5/06

  Wet spinning methods {(D01D5/0046 takes precedence)} · CPC title

• D01F11/14

  with organic compounds, e.g. macromolecular compounds · CPC title

• D01F11/12

  with inorganic substances {; Intercalation} · CPC title

• D01D1/02

  Preparation of spinning solutions · CPC title

• D06M2101/40

  Fibres of carbon · CPC title