Ethoxylated amines for use in subterranean formations

Patent metadata

Field	Value
Publication number	US-10995262-B2
Application number	US-202016828584-A
Country	US
Kind code	B2
Filing date	Mar 24, 2020
Priority date	Nov 16, 2015
Publication date	May 4, 2021
Grant date	May 4, 2021

Abstract

Methods for treating subterranean formations are provided. In one embodiment, the methods comprise providing a treatment fluid comprising an aqueous base fluid and a surfactant comprising an ethoxylated amine or derivative thereof; introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation; and producing fluids from the wellbore during or subsequent to introducing the treatment fluid into the wellbore.

First claim

What is claimed is:

1. A method comprising:
providing a treatment fluid comprising:
an aqueous base fluid; and
a surfactant comprising an ethoxylated amine or derivative thereof having the structural formula:

wherein R is a C 1 to C 7 alkyl chain;
wherein each of x and y is independently an integer from 1 to 25;
introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation; and
producing fluids from the wellbore during or subsequent to introducing the treatment fluid into the wellbore.

2. The method of claim 1 , wherein the ethoxylated amine or derivative thereof inhibits corrosion in at least a portion of the subterranean formation.

3. The method of claim 1 , wherein the surfactant is present in the treatment fluid in an amount from about 1×10 −5 gpt up to about 50 gpt based on the total volume of the treatment fluid.

4. The method of claim 1 , wherein the treatment fluid further comprises an additional surfactant.

5. The method of claim 4 , wherein the additional surfactant is selected from the group consisting of: an alkyl polyglycoside, an alkoxylated alkyl alcohol, an alkoxylated alkyl alcohol salt, an alkoxylated alkyl phenol, an alkoxylated alkyl phenol salt, an alkyl sulfonate, an aryl sulfonate, a sulfate, a phosphate, a carboxylate, a polyoxyalkyl glycol, a fatty alcohol, a polyoxyethylene glycol sorbitan alkyl ester, a sorbitan alkyl ester, a polysorbate, a glucoside, a quaternary amine compound, an amine oxide, and any combination thereof.

6. The method of claim 1 , wherein the treatment fluid further comprises a solvent.

7. The method of claim 6 , wherein the solvent is selected from the group consisting of: a non-aqueous solvent, a non-aromatic solvent, an alcohol, glycerol, carbon dioxide, isopropanol, any combination, and any derivative thereof.

8. The method of claim 1 , wherein the subterranean formation comprises an unconventional reservoir.

9. The method of claim 1 , further comprising:
allowing the surfactant to reduce capillary pressure in at least a portion of the subterranean formation.

10. The method of claim 1 , wherein the amount of fluids produced from the wellbore during or subsequent to introducing the treatment fluid comprising the surfactant is greater than the amount of fluids that would be produced during or subsequent to introducing the same treatment fluid without the surfactant.

11. The method of claim 1 , further comprising:
allowing the surfactant to alter a wettability of a surface of the formation.

12. The method of claim 1 , further comprising:
allowing the surfactant to reduce interfacial tension between a fluid in the formation and a surface in the formation.

13. The method of claim 1 , further comprising:
allowing the surfactant to remove at least a portion of an oil block, a water block, or both.

14. A method comprising:
providing a treatment fluid comprising:
an aqueous base fluid; and
a surfactant comprising an ethoxylated amine or derivative thereof having the structural formula:

wherein R is a C 1 to C 7 alkyl chain;
wherein each of x and y is independently an integer from 1 to 25; and
introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation at or above a pressure sufficient to create or enhance one or more fractures in the subterranean formation.

15. The method of claim 14 , further comprising:
producing fluids from the wellbore.

16. The method of claim 14 , further comprising:
allowing the surfactant to reduce capillary pressure in at least a portion of the subterranean formation.

17. The method of claim 14 , further comprising:
allowing the surfactant to remove at least a portion of an oil block, a water block, or both.

18. The method of claim 14 , wherein the ethoxylated amine or derivative thereof inhibits corrosion in at least the portion of the subterranean formation.

19. A method comprising:
providing a treatment fluid comprising:
an aqueous base fluid; and
a surfactant comprising an ethoxylated amine or derivative thereof having the structural formula:

wherein R is a C 1 to C 7 alkyl chain;
wherein each of x and y is independently an integer from 1 to 25;
introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation comprising an unconventional reservoir; and
producing fluids from the wellbore during or subsequent to introducing the treatment fluid into the wellbore, wherein the amount of fluids produced from the wellbore during or subsequent to introducing the treatment fluid comprising the surfactant is greater than the amount of fluids that would be produced during or subsequent to introducing the same treatment fluid without the surfactant.

20. The method of claim 19 , further comprising:
allowing the surfactant to remove at least a portion of an oil block, a water block, or both.

Assignees

• Multi Chem Group Llc

Inventors

• Peng Yang
• Yue Zhiwei
• He Kai
• Rane Jayant
• Xu Liang

Classifications

• C09K8/68

  containing organic compounds · CPC title

• C09K8/602 Primary

  containing surfactants · CPC title

• C09K2208/32

  Anticorrosion additives · CPC title

• C09K8/86

  containing organic compounds · CPC title

• E21B37/00

  Methods or apparatus for cleaning boreholes or wells (E21B21/00 takes precedence) · CPC title