Aqueous pigment ink for textile inkjet printing, method for producing printed textile item, and ink set

Patent metadata

Field	Value
Publication number	US-10995230-B2
Application number	US-201816105497-A
Country	US
Kind code	B2
Filing date	Aug 20, 2018
Priority date	May 18, 2018
Publication date	May 4, 2021
Grant date	May 4, 2021

Abstract

An aqueous pigment ink for textile inkjet printing is disclosed that contains a pigment, a first water-dispersible resin, a second water-dispersible resin and water, wherein the first water-dispersible resin is at least one resin selected from the group consisting of a water-dispersible urethane resin, a water-dispersible (meth)acrylic resin and a water-dispersible styrene/(meth)acrylic resin, the second water-dispersible resin is a water-dispersible polyester resin, the total amount of the first water-dispersible resin and the second water-dispersible resin is from 2 to 18% by mass relative to the total mass of the ink, and the mass ratio of the second water-dispersible resin relative to the first water-dispersible resin (second water-dispersible resin/first water-dispersible resin) is from 0.1 to 5.0. A method for producing a printed textile item and an ink set are also disclosed.

First claim

What is claimed is:

1. An aqueous pigment ink for textile inkjet printing comprising a pigment, a first water-dispersible resin, a second water-dispersible resin, and water, wherein
the first water-dispersible resin is at least one resin selected from the group consisting of a water-dispersible urethane resin, a water-dispersible (meth)acrylic resin and a water-dispersible styrene/(meth)acrylic resin,
the first water-dispersible resin comprises the water-dispersible urethane resin,
the second water-dispersible resin is a water-dispersible polyester resin,
a glass transition temperature of the second water dispersible resin is 5° C. or higher,
a total amount of the first water-dispersible resin and the second water-dispersible resin is from 2 to 18% by mass relative to a total mass of the ink, and
a mass ratio of the second water-dispersible resin relative to the first water-dispersible resin (second water-dispersible resin/first water-dispersible resin) is from 0.1 to 5.0.

2. The aqueous pigment ink for textile inkjet printing according to claim 1 , wherein a glass transition temperature of the first water-dispersible resin is 10° C. or lower.

3. The aqueous pigment ink for textile inkjet printing according to claim 1 , wherein a number average molecular weight of the second water-dispersible resin is at least 10,000.

4. The aqueous pigment ink for textile inkjet printing according to claim 1 , wherein the first water-dispersible resin comprises an anionic water-dispersible urethane resin.

5. The aqueous pigment ink for textile inkjet printing according to claim 1 , wherein the second water-dispersible resin comprises an anionic water-dispersible resin.

6. The aqueous pigment ink for textile inkjet printing according to claim 1 , further comprising a basic substance.

7. The aqueous pigment ink for textile inkjet printing according to claim 6 , wherein the basic substance comprises at least one selected from the group consisting of sodium hydroxide and an ethanolamine.

8. The aqueous pigment ink for textile inkjet printing according to claim 6 , wherein an amount of the basic substance, relative to the total mass of the ink, is from 0.01% by mass to 5.0% by mass.

9. A method for producing a printed textile item, the method comprising performing inkjet printing to a fabric using the aqueous pigment ink for textile inkjet printing according to claim 1 .

10. The method for producing a printed textile item according to claim 9 , wherein the fabric is a fabric containing polyester fibers.

11. The method for producing a printed textile item according to claim 10 , wherein the fabric is a fabric containing at least 30% by mass of polyester fibers.

12. A method for producing a printed textile item, comprising performing inkjet printing to a fabric using an aqueous pigment ink for textile inkjet printing,
wherein the aqueous pigment ink comprises a pigment, a first water-dispersible resin, a second water-dispersible resin, and water,
the first water-dispersible resin is at least one resin selected from the group consisting of a water-dispersible urethane resin, a water-dispersible (meth)acrylic resin and a water-dispersible styrene/(meth)acrylic resin,
the second water-dispersible resin is a water-dispersible polyester resin,
a total amount of the first water-dispersible resin and the second water-dispersible resin is from 2 to 18% by mass relative to a total mass of the ink, and
a mass ratio of the second water-dispersible resin relative to the first water-dispersible resin (second water-dispersible resin/first water-dispersible resin) is from 0.1 to 5.0, and
prior to performing inkjet printing, applying a pretreatment agent comprising a cationic substance.

13. The method for producing a printed textile item according to claim 12 , wherein the cationic substance comprises a cationic polymer.

14. The method for producing a printed textile item according to claim 13 , wherein the cationic polymer comprises at least one selected from the group consisting of a polyallylamine and a salt thereof.

15. An ink set comprising an aqueous pigment ink for textile inkjet printing including a pigment, a first water-dispersible resin, a second water-dispersible resin, and water, wherein
the first water-dispersible resin is at least one resin selected from the group consisting of a water-dispersible urethane resin, a water-dispersible (meth)acrylic resin and a water-dispersible styrene/(meth)acrylic resin,
the second water-dispersible resin is a water-dispersible polyester resin,
a total amount of the first water-dispersible resin and the second water-dispersible resin is from 2 to 18% by mass relative to a total mass of the ink, and
a mass ratio of the second water-dispersible resin relative to the first water-dispersible resin (second water-dispersible resin/first water-dispersible resin) is from 0.1 to 5.0, and

a pretreatment agent comprising a cationic substance.

16. The ink set according to claim 15 , wherein the cationic substance comprises a cationic polymer.

17. The ink set according to claim 16 , wherein the cationic polymer comprises at least one selected from the group consisting of a polyallylamine and a salt thereof.

18. The ink set according to claim 15 , wherein the aqueous pigment ink for textile inkjet printing further comprises a basic substance, and the first water-dispersible resin comprises the water-dispersible urethane resin.

Assignees

• Riso Kagaku Corp

Inventors

• Yamazaki Takahisa
• Hayashi Akiko
• Uozumi Shunsuke
• Kinoe Kokoro

Classifications

• D06P5/30 Primary

  Ink jet printing · CPC title

• B41J3/4078

  Printing on textile · CPC title

• C09D11/033

  characterised by the solvent · CPC title

• D06P1/5285

  Polyurethanes; Polyurea; Polyguanides · CPC title

• C09D11/38

  characterised by non-macromolecular additives other than solvents, pigments or dyes · CPC title