Thermoplastic resin composition, method for producing same, and molded product formed therefrom

Patent metadata

Field	Value
Publication number	US-10995208-B2
Application number	US-201716345798-A
Country	US
Kind code	B2
Filing date	Oct 30, 2017
Priority date	Oct 31, 2016
Publication date	May 4, 2021
Grant date	May 4, 2021

Abstract

A thermoplastic resin composition of the present invention comprises: approximately 100 parts by weight of a thermoplastic resin including a repeat unit represented by Chemical Formula 1, a repeat unit represented by Chemical Formula 2, and a repeat unit represented by Chemical Formula 3; and approximately 5 to 40 parts by weight of a reinforcing filler. The thermoplastic resin composition is excellent in terms of heat resistance, stiffness, lightweight properties, and external appearance, and exhibits excellent balance between said physical properties.

First claim

The invention claimed is:

1. A thermoplastic resin composition comprising:
100 parts by weight of a thermoplastic resin comprising a repeat unit represented by Formula 1, a repeat unit represented by Formula 2, and a repeat unit represented by Formula 3; and
about 5 parts by weight to about 40 parts by weight of reinforcing fillers,

wherein R 1 and R 2 are each independently a hydrogen atom, a methyl group or an ethyl group, and Ar is a substituted or unsubstituted C 6 to C 20 aryl group;

wherein R 3 is

 wherein R 4 is a C 1 to C 5 alkylene group, R 5 is a C 1 to C 30 linear alkyl group, and * indicates a linking site.

2. The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin comprises about 54 wt % to about 94 wt % of the repeat unit represented by Formula 1, about 5 wt% to about 45 wt % of the repeat unit represented by Formula 2, and about 0.1 wt % to about 8 wt % of the repeat unit represented by Formula 3.

3. The thermoplastic resin composition according to claim 1 , wherein the thermoplastic resin is prepared through melting and kneading of an aromatic vinyl copolymer comprising the repeat unit represented by Formula 1 and the repeat unit represented by Formula 2 and a compound represented by Formula 4 at about 150° C. to about 350° C.,

where R 4 and R 5 are the same as defined in Formula 3.

4. The thermoplastic resin composition according to claim 1 , wherein the reinforcing fillers comprise carbon fibers, glass fibers, and/or mineral fillers.

5. The thermoplastic resin composition according to claim 1 , further comprising: a rubber-modified vinyl graft copolymer and an aromatic vinyl-vinyl cyanide copolymer.

6. The thermoplastic resin composition according to claim 5 , wherein the rubber-modified vinyl graft copolymer is prepared through graft polymerization of an aromatic vinyl monomer and a monomer copolymerizable with the aromatic vinyl monomer to a rubber polymer.

7. The thermoplastic resin composition according to claim 5 , wherein the aromatic vinyl-vinyl cyanide copolymer is a copolymer of a monomer mixture comprising about 20 wt % to about 95 wt % of an aromatic vinyl monomer, about 5 wt % to about 40 wt % of a vinyl cyanide monomer, and about 75 wt % or less of a monomer copolymerizable with the aromatic vinyl monomer.

8. The thermoplastic resin composition according to claim 5 , wherein the thermoplastic resin composition comprises about 5 to about 40 parts by weight of the rubber-modified vinyl graft copolymer and about 5 to about 40 parts by weight of the aromatic vinyl-vinyl cyanide copolymer relative to 100 parts by weight of the thermoplastic resin.

9. The thermoplastic resin composition according to claim 1 , wherein a molded product produced from the thermoplastic resin composition has a heat deflection temperature of about 105° C. to about 170° C., as measured in accordance with ASTM D648 and a tensile strength of about 70 MPa to about 150 MPa, as measured in accordance with ASTM D638.

10. A method of preparing a thermoplastic resin composition, comprising:
preparing a thermoplastic resin composition comprising: 100 parts by weight of a thermoplastic resin comprising a repeat unit represented by Formula 1, a repeat unit represented by Formula 2 and a repeat unit represented by Formula 3; and about 5 parts by weight to about 40 parts by weight of reinforcing fillers by melting and kneading an aromatic vinyl copolymer comprising the repeat unit represented by Formula 1 and the repeat unit represented by Formula 2, a compound represented by Formula 4, and the reinforcing fillers at about 150° C. to about 350° C.,

wherein R 1 and R 2 are each independently a hydrogen atom, a methyl group or an ethyl group, and Ar is a substituted or unsubstituted C 6 to C 20 aryl group;

wherein R 3 is

 wherein R 4 is a C 1 to C 5 alkylene group, R 5 is a C 1 to C 30 linear alkyl group, and * indicates a linking site;

wherein R 4 is a C 1 to C 5 alkylene group and R 5 is a C 1 to C 30 linear alkyl group.

11. The method of preparing a thermoplastic resin composition according to claim 10 , further comprising: mixing a rubber-modified vinyl graft copolymer and an aromatic vinyl-vinyl cyanide copolymer before melting and kneading.

12. The method of preparing a thermoplastic resin composition according to claim 11 , wherein the thermoplastic resin composition further comprises about 5 to about 40 parts by weight of the rubber-modified vinyl graft copolymer and about 5 to about 40 parts by weight of the aromatic vinyl-vinyl cyanide copolymer relative to 100 parts by weight of the thermoplastic resin.

13. A molded product produced from the thermoplastic resin composition according to claim 1 .

Assignees

• Lotte Advanced Mat Co Ltd

Inventors

• Bae Yun Seok
• Ban Kyun Ha
• Hong Chang Min

Classifications

• C08K3/00

  Use of inorganic substances as compounding ingredients · CPC title

• C08F222/06

  Maleic anhydride · CPC title

• C08K7/02

  Fibres or whiskers · CPC title

• C08L25/08 Primary

  Copolymers of styrene (C08L29/08, C08L35/06, C08L55/02 take precedence) · CPC title

• C08L53/02

  of vinyl-aromatic monomers and conjugated dienes · CPC title