Bimodal polypropylene random copolymer

Patent metadata

Field	Value
Publication number	US-10995205-B2
Application number	US-201916982915-A
Country	US
Kind code	B2
Filing date	Apr 9, 2019
Priority date	Apr 10, 2018
Publication date	May 4, 2021
Grant date	May 4, 2021

Abstract

The application provides a bimodal polypropylene random copolymer with good response to nucleating agents, increased crystallization temperature, good mechanical and optical properties, as well as low amounts of extractables and good processability in the sense of high Melt Flow Rate. The present invention further relates to articles made thereof, and the use of the bimodal polypropylene random copolymer for specific applications. It also relates to a process for the preparation of said bimodal polypropylene random copolymer.

First claim

The invention claimed is:

1. A bimodal polypropylene random copolymer of propylene and 2.5-7.0 wt. % of ethylene as comonomer produced in the presence of a single site based catalyst, having a Melt Flow Rate 20.0-120.0 g/10 min when determined according to ISO1133 at 230° C. and 2.16 kg and comprising
a. 25.0-70.0 wt. % of a first polypropylene fraction being a propylene homopolymer or a random copolymer of propylene and ethylene as comonomer comprising up to 2.0 wt. % of comonomer and
b. 30.0-75.0 wt. % of a second polypropylene fraction being a random copolymer of propylene and ethylene as comonomer comprising 3.0-10.0 wt. % of comonomer,
and wherein the bimodal polypropylene random copolymer is characterised by a
Crystallization Temperature (Tc) according to ISO 11357 of at least 115° C. and
2.0-15.0 wt. % of the bimodal polypropylene random copolymer being soluble in cold xylene (XCS) when measured according to ISO 16152.

2. The bimodal polypropylene random copolymer according to claim 1 , having a hexane-soluble fraction of at most 2.5 wt. % when determined according to FDA method (C6 FDA) and/or by an overall migration (OM) of at most 10.0 mg/dm 2 when determined according to EN ISO 1186.

3. The bimodal polypropylene random copolymer according to claim 1 , comprising at least one nucleating agent.

4. The bimodal polypropylene random copolymer according to claim 1 , having a molecular weight distribution MWD of 2.0-4.0.

5. The bimodal polypropylene random copolymer according to claim 1 , having a Solidification temperature Ts 400 at a cooling rate of 400 K/s of at least 30° C.

6. The bimodal polypropylene random copolymer according to according to claim 1 , further comprising a soluble nucleating agent and a particulate nucleating agent.

7. The bimodal polypropylene random copolymer according to claim 1 , wherein the soluble nucleating agent is present in the range of 100-3000 ppm based on the bimodal polypropylene random copolymer.

8. A moulded article comprising the bimodal polypropylene random copolymer according to claim 1 .

9. The moulded article according to claim 8 , wherein the moulded article is a medical, pharmaceutical or diagnostic article.

10. A process for preparing a bimodal polypropylene random copolymer according to claim 1 , by sequential polymerization in the presence of a metallocene catalyst, wherein
preparing in a bulk phase reactor in a first polymerization stage a first polypropylene fraction, said first polypropylene fraction being a propylene homopolymer or a propylene-ethylene random copolymer having an ethylene content in the range of 0.0 to 2.0 wt. %,
transferring said first polypropylene fraction to a second polymerization stage in which a second polypropylene fraction is prepared in a gas phase reactor (GPR), said second polypropylene fraction being a propylene-ethylene random copolymer having an ethylene content in the range of 3.0-10.0 wt. %,
wherein a mixture of said first polypropylene fraction and said second polypropylene fraction being subjected to a deactivation and purification step followed by compounding and incorporation of the at least one nucleating agents.

11. The process according to claim 10 , wherein a particulate nucleating agent is incorporated by using a nucleation masterbatch.

Assignees

• Borealis Ag

Inventors

• Gahleitner Markus
• Wang Jingbo
• Bernreitner Klaus
• Mileva Daniela
• Hoff Matthias
• Leskinen Pauli

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L2314/06

  Metallocene or single site catalysts · CPC title

• C08L23/12 Primary

  Polypropene · CPC title

• C08F210/06

  Propene · CPC title

• C08F4/65927

  two cyclopentadienyl rings being mutually bridged · CPC title