Isomerization zone in alkylate complex

Patent metadata

Field	Value
Publication number	US-10995045-B2
Application number	US-201816154985-A
Country	US
Kind code	B2
Filing date	Oct 9, 2018
Priority date	Oct 9, 2018
Publication date	May 4, 2021
Grant date	May 4, 2021

Abstract

An alkylation process including an upfront isomerization zone is described. 100% n-butane or field butanes can be converted into a blend of approximately 60 wt % isobutane and 40 wt % n-butane in the isomerization zone. This blend can be used as the feed to all types of alkylation zones. It stabilizes the feed composition so that the dehydrogenation zone and alkylation zone always operate with the same feed.

First claim

What is claimed is:

1. A process for dehydrogenation and alkylation, comprising:
passing a hydrocarbon feed stream comprising n-butane to an isomerization zone to generate an isomerization zone product stream comprising approximately 60 wt % isobutane and 40 wt % n-butane;
passing the isomerization zone product stream to a distillation column to generate a distillation overhead stream comprising C4− hydrocarbons and a distillation bottom stream comprising C5+ hydrocarbons;
passing a first portion of the distillation overhead stream to a dehydrogenation zone to generate a dehydrogenation zone product stream comprising mixed butenes, iso-butane and n-butane, wherein the mixed butenes comprise approximately 60 wt % isobutene and 40 wt % n-butene;
passing the dehydrogenation zone product stream and a second portion of the distillation overhead stream to an alkylation zone to produce an alkylation zone product stream;
passing the alkylation zone product stream to a separation zone to generate an isobutane stream, an n-butane stream, and an alkylate product stream; and
passing the n-butane stream to the isomerization zone.

2. The process of claim 1 wherein the separation zone comprises a deisobutanizer and a debutanizer and wherein passing the alkylation zone product stream to the separation zone comprises:
passing the alkylation zone product stream to the deisobutanizer to generate the isobutane stream and a deisobutanizer bottoms stream; and
passing the deisobutanizer bottoms stream to the debutanizer to generate the n-butane stream and the alkylate product stream.

3. The process of claim 1 wherein the separation zone comprises a distillation column and wherein passing the alkylation zone product stream to the separation zone comprises:
passing the alkylation zone product stream to the distillation column to generate the isobutane stream, the n-butane stream, and the alkylate product stream.

4. The process of claim 1 further comprising:
passing the distillation bottom stream to the separation zone.

5. The process of claim 1 further comprising:
passing the isobutane stream to the alkylation zone.

6. The process of claim 1 further comprising:
passing a portion of the isobutane stream to the dehydrogenation zone.

7. The process of claim 1 further comprising:
passing a portion of the isomerization zone product stream to the alkylation zone.

8. The process of claim 1 wherein passing the dehydrogenation zone product stream to the alkylation zone comprises:
passing the dehydrogenation zone product stream to a selective hydrogenation zone to generate a selective hydrogenation zone product stream; and
passing the selective hydrogenation zone product stream to the alkylation zone.

9. The process of claim 8 wherein the selective hydrogenation zone is operated to generate a ratio of 2-butene to 1-butene greater than 8 to 1 on a weight basis.

10. The process of claim 1 wherein passing the dehydrogenation zone product stream to the alkylation zone comprises:
passing the dehydrogenation zone product stream to a dehydrogenation fractionation zone to generate a light stream, a heavies stream, and a dehydrogenation fractionation product stream; and
passing the dehydrogenation fractionation product stream to the alkylation zone.

11. The process of claim 1 , wherein the alkylation zone is a sulfuric acid alkylation zone, a hydrofluoric acid alkylation zone, or an ionic liquid alkylation zone.

12. The process of claim 1 , further comprising:
passing a portion of the n-butane stream to a second isomerization zone to generate a second isomerization zone product stream; and
passing the second isomerization zone product stream to the separation zone.

13. The process of claim 1 , further comprising:
passing a separation zone side cut stream comprising n-butane to a third isomerization zone to generate a third isomerization zone product stream; and
passing the third isomerization zone product stream to the separation zone.

14. The process of claim 1 , further comprising at least one of:
sensing at least one parameter of the process and generating a signal or data from the sensing;
generating and transmitting a signal; or
generating and transmitting data.

15. The process of claim 1 wherein the hydrocarbon feed stream comprises at least 50% n-butane by weight.

16. A process for dehydrogenation and alkylation, comprising:
passing a hydrocarbon feed stream comprising n-butane to an isomerization zone to generate an isomerization zone product stream comprising approximately 60 wt % isobutane and 40 wt % n-butane;
passing the isomerization zone product stream to a distillation column to generate a distillation overhead stream comprising C4− hydrocarbons and a distillation bottom stream comprising C5+ hydrocarbons;
passing a first portion of the distillation overhead stream to a dehydrogenation zone to generate a dehydrogenation zone product stream comprising mixed butenes, iso-butane, and n-butane, wherein the mixed butenes comprise approximately 60 wt % isobutene and 40 wt % n-butene;
passing the dehydrogenation zone product stream and a second portion of the distillation overhead stream to an alkylation zone to produce an alkylation zone product stream;
passing the alkylation zone product stream to a deisobutanizer to generate an isobutane stream and a deisobutanizer bottoms stream; and
passing the deisobutanizer bottoms stream to a debutanizer to generate an n-butane stream and an alkylate product stream.

17. The process of claim 16 wherein passing the dehydrogenation zone product stream to the alkylation zone comprises:
passing the dehydrogenation zone product stream to a selective hydrogenation zone to generate a selective hydrogenation zone product stream;
passing the selective hydrogenation zone product stream to a dehydrogenation fractionation zone to generate a dehydrogenation fractionation product stream; and
passing the dehydrogenation fractionation product stream to the alkylation zone.

Assignees

• Uop Llc

Inventors

• Digiulio Christopher
• Luebke Charles P
• Shecterle David J

Classifications

• C07C5/32

  by dehydrogenation with formation of free hydrogen · CPC title

• C07C5/27

  Rearrangement of carbon atoms in the hydrocarbon skeleton · CPC title

• C07C2/56 Primary

  Addition to acyclic hydrocarbons · CPC title

• C07C11/107

  with six carbon atoms · CPC title

• C07C5/327 Primary

  Formation of non-aromatic carbon-to-carbon double bonds only · CPC title