System and method for producing an aerogel composite material, and aerogel composite material

Patent metadata

Field	Value
Publication number	US-10995007-B2
Application number	US-201716303642-A
Country	US
Kind code	B2
Filing date	May 22, 2017
Priority date	May 20, 2016
Publication date	May 4, 2021
Grant date	May 4, 2021

Abstract

A system and method for producing an aerogel composite material includes a reaction vessel having a movable carrier basket for receiving a plurality of fiber mats, and a plurality of plates to space the fiber mats apart from one another. Once the plates have been removed, there are gaps between the aerogel insulating boards, through which hot drying air can be blown during a drying process. The method has the advantage that the quantities of solvents and reagents to be disposed of are minimal, and in addition thereto, no complex work-up processes are necessary.

First claim

The invention claimed is:

1. A system for industrial production of a fiber-reinforced aerogel plate, comprising:
a first reservoir for a solvent,
a second reservoir for an organosilane compound,
a third reservoir for a hydrophobizing agent,
a fourth reservoir for an acid,
a fifth reservoir for a base,
a reaction vessel for receiving a plurality of fiber mats,
a cover for the reaction vessel,
a plurality of connecting lines between the first, second, third, fourth and fifth reservoirs and the reaction vessel,
a removable basket for receiving the plurality of fiber mats in the reaction vessel, and
a plurality of plates to space the plurality of fiber mats apart from each other.

2. The system according to claim 1 , further comprising a first heat exchanger device on the reaction vessel to heat or cool the reaction vessel or contents of the reaction vessel to a specific temperature.

3. The system according to claim 1 , further comprising
a connection on the reaction vessel for blowing a drying gas,
a supply line connected to a port for the drying gas, the supply connected to a heating device,
a discharge line for the drying gas, in communication with a second heat exchanger on the reaction vessel, and a blower or a pump for introducing the drying gas into or drawing it from the reaction vessel.

4. The system according claim 1 , further comprising a removable carrier basket in the reaction vessel, in which the plurality of fiber mats are arranged.

5. The system according to claim 1 , further comprising a mixer/settler with a stirrer, the mixer/settler in communication with the reaction vessel with a first line and in communication with the first reservoir with a second line.

6. The system according to claim 5 , wherein the second line is in communication with a distillation device.

7. The system according to claim 5 , wherein the mixer/settler is connected via the first line line to the third reservoir.

8. The system according to claim 3 , wherein the second heat exchanger is in communication with the reaction vessel with a recirculation line.

9. The system according to claim 1 , further comprising a separate heating/cooling circuit to heat the reaction vessel.

10. A system for the industrial production of a fiber-reinforced aerogel plate, comprising:
a plurality of reservoirs comprising:
a first reservoir for a solvent,
a second reservoir for an organosilane compound,
a third reservoir for a hydrophobizing agent,
a fourth reservoir for an acid, and
a fifth reservoir for a base,

a reaction vessel for receiving a plurality of fiber mats,
a plurality of connecting lines between said plurality of reservoirs and the reaction vessel,
wherein the reaction vessel is in communication directly or indirectly with the first reservoir and the third reservoir teach via a recirculation line.

11. The system according to claim 10 , further comprising, a first heat exchanger on the reaction vessel to heat or cool the reaction vessel or contents of the reaction vessel to a specific temperature.

12. A method for producing a fiber-reinforced aerogel plate, comprising:
preparing a silicatic sol,
hydrophobizing the gel with a hydrophobizing agent in the presence of an acid as catalyst,
arranging initially a plurality of fiber mats and a corresponding plurality of intermediate plates alternately in a reaction vessel, so that two fiber mats of the plurality of fiber mats are separated from each other by a respective intermediate plate of the plurality of intermediate plates,
adding the silicate sol to the reaction vessel until gelling is started, and
draining a reaction solution from the reaction vessel after gelling of the gel, removing the intermediate plates and drying the formed, fiber-reinforced aerogel plates at a temperature >100° C.

13. The method according to claim 12 , further comprising spacing adjacent fiber mats from each other by at least 10 mm.

14. The method according to claim 12 , further comprising arranging the fiber mats on a carrier basket, which fits into the reaction vessel.

15. The method according to claim 12 , wherein the drying of the fiber-reinforced aerogel plates takes place within the reaction vessel.

16. The method according to 15 , wherein the drying takes place by blowing a hot drying gas through the reaction vessel.

17. The method according to claim 15 , further comprising circulating the drying gas and condensing out volatiles absorbed in the drying gas.

18. The method according to any one of claim 12 , wherein the drying takes place at temperatures >120° C.

19. The method according to claim 12 , wherein the gelling, hydrophobizing and drying are carried out in the reaction vessel.

20. The method according to claim 12 , further comprising using hexamethyldisiloxane (HDMSO) as the hydrophobizing agent.

21. The method according to claim 12 , wherein in the hydrophobizing a ratio of solvent and water is at least 4%.

22. The method according to any one of claim 12 , wherein a proportion by weight of the hydrophobizing agent in a liquid hydrophobizing solution is at least 50%.

23. The method according to claim 12 , further comprising using nitric acid as the acid.

24. The method according to claim 12 , wherein the silicate sol is prepared by hydrolysis of alkoxysilanes or hydroxyalkoxysilanes.

25. The method according to to claim 12 , wherein the preparation of the sol is carried out in alcohol or an alcohol-containing solvent mixture.

26. The method according to claim 12 , further comprising adjusting a pH in the hydrophobizing to a value between 0.2 and 6.

27. The method according to claim 12 , further comprising preparing the sol by hydrolysis of tetraethoxysilane (TEOS) with a mass fraction of between 5 and 30 percent by weight of SiO 2 .

28. The method according to claim 12 , wherein the gelling occurs in a temperature range between 30° C. and 80° C.

29. The method according to claim 12 , further comprising mixing the sol with mineral fibers.

30. The method according to claim 29 , further comprising using rockwool fibers as the mineral fibers.

31. The method according to claim 12 , wherein the hydrophobization is carried out in situ without prior solvent exchange.

32. The method according to claim 12 , further comprising adding a silylating agent when preparing the silicatic sol.

33. The method according to claim 12 , further comprising forming a composite material of an aerogel and mineral fibers havinq a thermal conductivity between 8 and 25 mW/m K.

Assignees

• Rockwool Int

Inventors

• Egli Christoph
• Kym Ivo

Classifications

• C04B14/302

  Aerogels · CPC title

• C01B33/158

  Purification; Drying; Dehydrating · CPC title

• B01J19/2445

  placed in parallel · CPC title

• B01J19/0053

  Details of the reactor · CPC title

• B01J13/0091 Primary

  Preparation of aerogels, e.g. xerogels · CPC title