Apparatus and method for waste gas scrubbing

Patent metadata

Field	Value
Publication number	US-10994244-B2
Application number	US-201816607135-A
Country	US
Kind code	B2
Filing date	Apr 18, 2018
Priority date	Apr 25, 2017
Publication date	May 4, 2021
Grant date	May 4, 2021

Abstract

A device for waste gas scrubbing in a urea plant may be configured such that a waste gas passes along a transportation direction in the duct. The duct may include a first region for removing urea dust particles from the waste gas and a second region for removing chemical compounds from the waste gas, which can be integrated by an acid-base reaction into an aqueous liquid phase. A cross-sectional area of the duct extending perpendicular to the transportation direction in the second region may be greater than a cross-sectional area extending perpendicular to the transportation direction in the first region. Further, the device may be configured such that the duct extends horizontally at least in sections and/or the transportation direction of the waste gas through the duct extends horizontally in an installed state.

First claim

What is claimed is:

1. A device for waste gas scrubbing in a urea plant, the device comprising:
a duct with an inlet opening and an outlet opening, wherein the device is configured such that a waste gas passes along a transportation direction in the duct, wherein the duct extends horizontally at least in sections and/or the transportation direction of the waste gas through the duct extends horizontally in an installed state of the device, wherein the duct comprises:
a first region comprising a first surface enlargement structure disposed in the duct for removing urea dust particles from the waste gas, and
a second region comprising a second surface enlargement structure disposed in the duct for removing chemical compounds from the waste gas, which are configured to be integrated by an acid-base reaction into an aqueous liquid phase,

wherein a cross-sectional area of the duct extending perpendicular to the transportation direction in the second region is greater than a cross-sectional area of the duct extending perpendicular to the transportation direction in the first region,
wherein the first region comprises a first spraying device for spraying a first solvent, wherein the second region comprises a second spraying device for spraying a second solvent.

2. The device of claim 1 wherein the cross-sectional area in the second region has at least one of a greater height or a greater width than the cross-sectional area of the first region.

3. The device of claim 1 wherein at least one of the first spraying device or the second spraying device comprises a distributor pipe.

4. The device of claim 3 wherein the distributor pipe comprises spray nozzles that are configured to be supplied with one of the solvents via a common feed line.

5. The device of claim 1 wherein at least one of the first spraying device or the second spraying device is disposed so as to spray into a flow of the waste gas from above transversely to the transportation direction of the flow of the waste gas upstream in front of the respective first or second surface enlargement structure.

6. The device of claim 1 wherein at least one of the first spraying device or the second spraying device is disposed upstream in front of the respective first or second surface enlargement structure such that the at least one of the first spraying device or the second spraying device sprays into the respective first or second surface enlargement structure in the transportation direction of a flow of the waste gas.

7. The device of claim 1 wherein at least one of the first surface enlargement structure or the second surface enlargement structure comprises as least one of:
Raschig rings, Pall rings, saddle elements, spring-typical bodies, or combinations thereof;
plates, corrugated plates, formed plates, or combinations thereof; or
metal, glass, plastic, carbon fibers, or combinations thereof.

8. A device for waste gas scrubbing in a urea plant, the device comprising:
a duct with an inlet opening and an outlet opening, wherein the device is configured such that a waste gas passes along a transportation direction in the duct, wherein the duct extends horizontally at least in sections and/or the transportation direction of the waste gas through the duct extends horizontally in an installed state of the device, wherein the duct comprises:
a first region comprising a first surface enlargement structure disposed in the duct for removing urea dust particles from the waste gas, and
a second region comprising a second surface enlargement structure disposed in the duct for removing chemical compounds from the waste gas, which are configured to be integrated by an acid-base reaction into an aqueous liquid phase,

wherein a cross-sectional area of the duct extending perpendicular to the transportation direction in the second region is greater than a cross-sectional area of the duct extending perpendicular to the transportation direction in the first region,
wherein at least one of:
the first region is configured to remove urea dust particles in multiple steps; or
the second region is configured to remove the chemical compounds in multiple steps, wherein one of the chemical compounds is ammonia.

9. A method for waste gas scrubbing in a urea plant, the method comprising:
guiding a waste gas through a duct having a first region for removing urea dust particles and a second region for removing chemical compounds from the waste gas, which are configured to be integrated by an acid-base reaction into an aqueous liquid phase; and
transporting the waste gas through the second region at a lesser speed than in the first region due to an enlargement of a cross-sectional area of the duct that extends perpendicular to a transportation direction in the second region,
wherein the duct extends horizontally at least in sections and/or the transportation direction of the waste gas through the duct extends horizontally.

10. The method of claim 9 comprising removing ammonia, which is one of the chemical compounds, by way of an acid washing solution in the second region.

11. The method of claim 10 wherein the acid washing solution includes an acid.

12. The method of claim 10 wherein the acid washing solution includes at least one of sulfuric acid, nitric acid, hydrochloric acid, or phosphoric acid.

13. The method of claim 9 comprising:
transporting the waste gas at a speed of greater than 1 m/s through the first region; and
transporting the waste gas at a speed of less than 1 m/s through the second region.

14. The method of claim 13 wherein the waste gas entering through an inlet opening of the duct has a temperature of at most 140° C.

Assignees

• Thyssenkrupp Ind Solutions Ag
• Thyssenkrupp Ag
• thysseukrupp AG

Inventors

• Gehrke Helmut
• Schmitz Martina
• Buss Stephan

Classifications

• B01D2251/502

  Hydrochloric acid · CPC title

• B01D53/75 Primary

  Multi-step processes · CPC title

• B01D53/56

  Nitrogen oxides (B01D53/60 takes precedence) · CPC title

• B01D53/68

  Halogens or halogen compounds · CPC title

• B01D2251/604

  Hydroxides · CPC title