Secondary battery

Patent metadata

Field	Value
Publication number	US-10992002-B2
Application number	US-201615162753-A
Country	US
Kind code	B2
Filing date	May 24, 2016
Priority date	Nov 27, 2013
Publication date	Apr 27, 2021
Grant date	Apr 27, 2021

Abstract

The present invention relates to a rechargeable battery, and a rechargeable battery including: a liquid cathode portion including a sodium-containing solution and a cathode current collector impregnated in the sodium-containing solution; an anode portion including a liquid organic electrolyte, an anode current collector impregnated in the liquid organic electrolyte, and an anode active material provided in the surface of the anode current collector; and a solid electrolyte provided between the cathode portion and the anode portion can be provided.

First claim

What is claimed is:

1. A rechargeable battery comprising:
a cathode portion including a sodium-containing solution and a cathode current collector, which is immersed within the sodium-containing solution;
an anode portion including a liquid organic electrolyte, an anode current collector immersed within the liquid organic electrolyte, and an anode active material layer comprising an anode active material provided on an outer surface of the anode current collector; and
a solid electrolyte provided between the cathode portion and the anode portion,
wherein a first side of the cathode portion comprises an inlet of the sodium-containing solution,
wherein a second side of the cathode portion comprises an outlet of a material generated from the sodium-containing solution by charge or discharge of the rechargeable battery,
wherein the organic electrolyte in the anode portion comprises a non-aqueous organic solvent and NaTFSI as sodium salt,
wherein concentration of the NaTFSI as the sodium salt is 0.1M to 2.0M,
wherein the anode active material layer provided in the outer surface of the anode current collector further comprises a conductive material and a binder, and
wherein the anode active material comprises DST (disodium terephthalate), a Cu-based, P-based, Sn-based, carbon-based material and a sodium intercalation material.

2. The rechargeable battery of claim 1 , wherein the sodium containing solution comprises seawater, and
wherein the material comprises NaOH generated by the discharge of the rechargeable battery or desalinated water generated by the charge of the rechargeable battery.

3. The rechargeable battery of claim 1 , wherein the non-aqueous organic solvent is an ester-based, ether-based, ketone-based, or alcohol-based solvent, an aprotic solvent, or a combination thereof, and the sodium salt further comprises at least one selected from the group consisting of NaClO 4 , NaPF 4 , NaPF 6 , NaAsF 6 , Na[(C 2 F 5 ) 3 PF 3 ](NaFAP), Na[B(C 2 O 4 ) 2 ](NaBOB), Na[N(SO 2 F) 2 ](NaFSI), and Na Beti (NaN[SO 2 C 2 F 5 ] 2 ).

4. The rechargeable battery of claim 1 , wherein the n-type organic material is aniline/o-nitroaniline, disodium terephthalate, aromatic dialdehyde, terephthalaldehyde, 3,4,9,10-perylene-tetracarboxylicacid-dianhydride (PTCDA), poly (2,2,6,6-tetramethylpiperidinyloxy-4-ylmethacrylate) (PTMA), or a derivative or mixture thereof.

5. The rechargeable battery of claim 1 , wherein the Cu-based, P-based, and Sn-based material is CuO, CuO/C, P, P/C, Sn, Sn/C, Sn/P, or a combination thereof.

6. The rechargeable battery of claim 1 , wherein the carbon-based material is natural graphite, artificial graphite, soft carbon, hard carbon, or a combination thereof.

7. The rechargeable battery of claim 1 , wherein sodium intercalation material is Li 4 Ti 5 O 12 , NaCo 2 O 4 , Na 2 Ti 3 O 7 , Fe 3 O 4 , TiO 2 , Sb 2 O 4 , a Sb/C composite, a SnSb/C composite, amorphous P/C composite, or a combination thereof.

8. The rechargeable battery of claim 1 , wherein the conductive material comprises at least one selected from the group consisting of:
a carbon-based material that comprises at least one selected from the group consisting of natural graphite, artificial graphite, carbon black, acetylene black, ketjen black, vapor-grown carbon fiber (VGCF), and carbon fiber;
a metal powder that comprises at least one selected from the group consisting of copper, nickel, aluminum, and silver;
metal fiber; and
a conductive polymer.

9. The rechargeable battery of claim 1 , wherein the binder is polyvinyl alcohol, carboxymethyl cellulose, hydroxypropylcellulose, polyvinyl chloride, carboxylated polyvinyl chloride, polyvinyl fluoride, a polymer including ethylene oxide, polyvinyl pyrrolidone, polyurethane, polytetrafluoroethylene, polyvinylidene fluoride, polyethylene, polypropylene, styrene butadiene rubber, acrylated styrene-butadiene rubber, an epoxy resin, nylon, or a combination thereof.

10. The rechargeable battery of claim 1 , wherein the solid electrolyte comprises an amorphous ion conductive material (phosphorus-based glass, oxide-based glass, oxide/sulfide based glass), a Na superionic conductor (NASICON), a sodium sulfide-based solid electrolyte, a sodium oxide-based solid electrolyte, a PEO-NaClO 4 polymer solid electrolyte, or a combination thereof.

11. The rechargeable battery of claim 1 , wherein the cathode current collector is carbon paper, carbon fiber, carbon fabric, carbon felt, metal membrane, or a combination thereof.

12. The rechargeable battery of claim 1 , wherein a porosity range of the cathode current collector is 1 μm to 250 μm.

13. The rechargeable battery of claim 1 , wherein Reaction Equation 1 and/or Reaction Equation 2 occurs in the cathode portion when the rechargeable battery is discharged:
Na + +H 2 O+ e − →NaOH+½H 2   [Reaction Equation 1]

Na + +½H 2 O+¼O 2 +e − →NaOH.  [Reaction Equation 2]

14. The rechargeable battery of claim 1 , wherein Reaction Equation 3 and/or Reaction Equation 4 occurs in the cathode portion when the rechargeable battery is charged:
NaCl→Na+½Cl 2   [Reaction Equation 3]

NaOH→Na+½H 2 O+¼O 2 .  [Reaction Equation 4]

15. The rechargeable battery of claim 1 , wherein the sodium-containing solution is seawater.

16. The rechargeable battery of claim 1 , wherein the outlet comprises a fresh water exhaust portion connected to the cathode portion to draw out fresh water generated in the cathode portion to the outside.

17. The rechargeable battery of claim 16 , wherein the fresh water exhaust portion comprises an exhaust pipe provided in a cathode portion and selectively opened to exhaust fresh water while or after the battery is charged.

18. The rechargeable battery of claim 1 , further comprising a hydrogen exhaust portion connected to the cathode portion to draw out hydrogen generated in the cathode portion from discharge of the battery to the outside.

19. The rechargeable battery of claim 18 , wherein the hydrogen exhaust portion comprises a gas pipe provided in an upper end of the cathode portion and selectively opened while or after the battery is discharged so as to exhaust hydrogen.

Assignees

• Ulsan Nat Inst Science & Tech Unist

Inventors

• Kim Young Sik
• Kim Jae Kwang
• Jung Mooyoung
• Han Jin Hyup
• Park Jeong Sun

Classifications

• H01M4/483

  for non-aqueous cells (H01M4/485 takes precedence) · CPC title

• H01M6/34

  Immersion cells, e.g. sea-water cells · CPC title

• H01M4/60

  of organic compounds · CPC title

• H01M2300/0028

  characterised by the solvent · CPC title

• H01M10/0562

  Solid materials · CPC title