Method for separating hydrocarbons from polymer

Patent metadata

Field	Value
Publication number	US-10988555-B2
Application number	US-201716319969-A
Country	US
Kind code	B2
Filing date	Sep 18, 2017
Priority date	Sep 21, 2016
Publication date	Apr 27, 2021
Grant date	Apr 27, 2021

Abstract

The present invention is directed to a process for separating an olefin copolymer from volatile gases using a flash separator. The flash separator can be used with a solution or high pressure process. The mass transport of volatile gases from the viscous polymer melt is increased.

First claim

The invention claimed is:

1. A flash separator comprising
a. an inlet located at an upper part of the flash separator for feeding a reaction solution into the flash separator,
b. optionally the inlet is circumvented with an outlet pipe,
c. a first outlet within a lower part of the flash separator, and
d. a second outlet within the upper part of the flash separator
wherein the inlet has a generally cylindrical wall that is perforated with multiple holes having a size of from 15 μm to 1500 μm.

2. A process for separating hydrocarbons from a reaction solution comprising a polymer and said hydrocarbons, comprising steps of: passing the reaction solution into the flash separator according to claim 1 thereby producing a stream of droplets falling downward within the flash separator; withdrawing a first solution stream comprising a majority of the polymer through the first outlet; and withdrawing a second solution stream comprising mainly hydrocarbons through the second outlet thereby establishing an upward moving gas stream within the flash separator.

3. The process according to claim 2 wherein a size of the droplets is sufficiently large so that the droplets are not entrained by the upward moving gas stream.

4. The process according to claim 2 wherein a pressure within the flash separator is from 1 to 500 bar.

5. The process according to claim 4 wherein a temperature within the flash separator is from 100 to 400° C.

6. The process according to claim 5 comprising a step of heating the reaction solution before passing it to the flash separator.

7. The process according to claim 6 comprising a step of reducing a pressure of the reaction solution before passing it to the flash separator.

8. The process according to claim 2 wherein a temperature within the flash separator is from 100 to 400° C.

9. The process according to claim 2 comprising a step of heating the reaction solution before passing it to the flash separator.

10. The process according to claim 2 comprising a step of reducing a pressure of the reaction solution before passing it to the flash separator.

11. The process according to claim 2 wherein the polymer is an olefin copolymer.

12. The process according to claim 11 wherein the reaction solution comprises from 10 to 35 wt % of the olefin copolymer.

13. The process according to claim 12 wherein the reaction solution comprises ethylene and at least one polar comonomer.

14. The process according to claim 11 wherein an amount of comonomer in the reaction solution is at least 1 wt %.

15. The process according to claim 14 wherein the reaction solution comprises ethylene and at least one polar comonomer.

16. The process according to claim 11 wherein the olefin copolymer is a low density polyethylene.

17. The process according to claim 11 wherein the reaction solution comprises ethylene and at least one polar comonomer.

18. The process according to claim 17 wherein the polar comonomer is selected from the group consisting of alkyl-acrylates, vinyl acetates, vinyl silanes, and mixtures thereof.

19. The process according to claim 11 wherein the olefin copolymer is produced in a solution process.

20. The process according to claim 19 wherein the reaction solution comprises an alpha-olefin.

Assignees

• Borealis Ag

Inventors

• Kanellopoulos Vasileios
• Al-Haj Ali Mohammad
• Krallis Apostolos

Classifications

• Y02P20/54

  using solvents, e.g. supercritical solvents or ionic liquids · CPC title

• C08F6/003 Primary

  from polymer solutions, suspensions, dispersions or emulsions without recovery of the polymer therefrom · CPC title

• C08F6/001 Primary

  Removal of residual monomers by physical means · CPC title

• B01D3/06

  Flash distillation · CPC title

• C08F6/005

  from solid polymers · CPC title