Ultraviolet-shielding glass sheet and vehicle window pane using the glass sheet

Patent metadata

Field	Value
Publication number	US-10988404-B2
Application number	US-201716305763-A
Country	US
Kind code	B2
Filing date	May 30, 2017
Priority date	May 30, 2016
Publication date	Apr 27, 2021
Grant date	Apr 27, 2021

Abstract

The present invention provides a glass sheet having a good property of blocking transmission of ultraviolet light, having a low to moderate visible transmittance, being relatively thin, being capable of substantially blocking transmission of solar ultraviolet light, and also having a good solar shielding property. The glass sheet of the present invention has a thickness of 1 to 5 mm, a Tuv 380 of 1.5% or less, a Tuv 400 of 2.5% or less, a visible transmittance (YA) of 5 to 40%, and a solar transmittance (TG) of 5 to 45%, and is formed from a glass composition, wherein the glass composition includes: 1.0 to 5.0 wt % T-Fe 2 O 3 ; 1.0 to 5.0 wt % TiO 2 ; and 50 to 600 wt. ppm CoO as coloring components in addition to predetermined base composition, a FeO ratio is 5 to 40%, and the sum of T-Fe 2 O 3 multiplied by 2 and TiO 2 is 7.0% or more.

First claim

The invention claimed is:

1. An ultraviolet-shielding glass sheet, having:
a thickness of 1 to 5 mm;
an ultraviolet transmittance (Tuv 380) as determined according to ISO 9050:1990 of 1.5% or less,
an ultraviolet transmittance (Tuv 400) as determined according to ISO 13837:2008 convention A of 2.5% or less,
a visible transmittance (YA) as measured using CIE standard illuminant A according to JIS R 3106:1998 of 5 to 40%, and
a solar transmittance (TG) as determined according to JIS R 3106:1998 of 5 to 45%,
the ultraviolet-shielding glass sheet comprising a glass composition, wherein
the glass composition comprises a base composition comprising:

65 to 71 wt % SiO 2 ;
0 to 5 wt % B 2 O 3 ;
1.0 to 5 wt % Al 2 O 3 ;
0 to 20 wt % MgO;
0 to 20 wt % CaO;
10 to 20 wt % Na 2 O;
0.5 to 5 wt % K 2 O; and
0.05 to 0.5 wt % SO 3 ,
the glass composition has a RO content of 5 wt % or more, wherein the RO content is the total content of MgO, CaO, SrO, and BaO,
the glass composition comprises, as coloring components:
1.0 to 5.0 wt % T-Fe 2 O 3 representing total iron oxide calculated as Fe 2 O 3 ;
1.0 to 5.0 wt % TiO 2 ; and
50 to 600 wt. ppm cobalt oxide calculated as CoO,
the glass composition has a FeO ratio of 5 to 40%, the FeO ratio representing a weight ratio of FeO calculated as Fe 2 O 3 to the T-Fe 2 O 3 , and

the glass composition satisfies 2×[T-Fe 2 O 3 ]+[TiO 2 ]≥7.0 wherein [T-Fe 2 O 3 ] represents the content of the T-Fe 2 O 3 in terms of wt % and [TiO 2 ] represents the content of the TiO 2 in terms of wt %.

2. The ultraviolet-shielding glass sheet according to claim 1 , comprising 1.0 to 4.0 wt % T-Fe 2 O 3 as the coloring component.

3. The ultraviolet-shielding glass sheet according to claim 2 , comprising 1.0 to 3.0 wt % T-Fe 2 O 3 as the coloring component.

4. The ultraviolet-shielding glass sheet according to claim 1 , comprising 1.0 to 4.0 wt % TiO 2 as the coloring component.

5. The ultraviolet-shielding glass sheet according to claim 4 , comprising 1.0 to 3.0 wt % TiO 2 as the coloring component.

6. The ultraviolet-shielding glass sheet according to claim 5 , comprising more than 2.2 wt % and 3.0 wt % or less TiO 2 as the coloring component.

7. The ultraviolet-shielding glass sheet according to claim 6 , comprising 2.4 to 3.0 wt % T-Fe 2 O 3 as the coloring component.

8. The ultraviolet-shielding glass sheet according to claim 7 , wherein the glass composition comprises, as the coloring components per 1 cm 2 of the glass sheet:
12.5 to 35.0 mg T-Fe 2 O 3 ;
12.5 to 35.0 mg TiO 2 ; and
50 to 400 μg cobalt oxide calculated as CoO, and
the glass composition satisfies 43≤2×{T-Fe 2 O 3 }+{TiO 2 }≤105 wherein {T-Fe 2 O 3 } represents the amount of the T-Fe 2 O 3 in terms of mg per 1 cm 2 of the glass sheet and {TiO 2 } represents the amount of the TiO 2 in terms of mg per 1 cm 2 of the glass sheet.

9. The ultraviolet-shielding glass sheet according to claim 6 , comprising 2.0 wt % or more and less than 2.4 wt % T-Fe 2 O 3 as the coloring component.

10. The ultraviolet-shielding glass sheet according to claim 9 , wherein the glass composition comprises, as the coloring components per 1 cm 2 of the glass sheet:
12.5 to 35.0 mg T-Fe 2 O 3 ;
12.5 to 35.0 mg TiO 2 ; and
50 to 400 μg cobalt oxide calculated as CoO, and
the glass composition satisfies 43≤2×{T-Fe 2 O 3 }+{TiO 2 }≤105 wherein {T-Fe 2 O 3 } represents the amount of the T-Fe 2 O 3 in terms of mg per 1 cm 2 of the glass sheet and {TiO 2 } represents the amount of the TiO 2 in terms of mg per 1 cm 2 of the glass sheet.

11. The ultraviolet-shielding glass sheet according to claim 5 , comprising 1.0 to 2.2 wt % TiO 2 as the coloring component.

12. The ultraviolet-shielding glass sheet according to claim 11 , comprising, as the coloring components:
2.4 to 3.0 wt % T-Fe 2 O 3 ; and
300 to 600 wt. ppm cobalt oxide calculated as CoO.

13. The ultraviolet-shielding glass sheet according to claim 12 , comprising 305 to 450 wt. ppm cobalt oxide calculated as CoO as the coloring component.

14. The ultraviolet-shielding glass sheet according to claim 1 , further comprising 0 to 200 wt. ppm ZnO in the base composition.

15. The ultraviolet-shielding glass sheet according to claim 1 , further comprising 0 to 2 wt. ppm Se as the coloring component, wherein
the FeO ratio is 22 to 32%.

16. The ultraviolet-shielding glass sheet according to claim 1 , further comprising 5 to 50 wt. ppm Se as the coloring component, wherein
the FeO ratio is 18 to 28%.

17. The ultraviolet-shielding glass sheet according to claim 1 , comprising a compressive stress layer formed by thermal tempering in a surface thereof, the ultraviolet-shielding glass sheet having a thickness of 1.0 to 3.5 mm.

18. The ultraviolet-shielding glass sheet according to claim 17 , having a Tuv 400 of 1.5% or less.

19. A vehicle window pane, comprising the ultraviolet-shielding glass sheet according to claim 17 .

20. The ultraviolet-shielding glass sheet according to claim 1 , comprising no compressive stress layer formed by thermal tempering in a surface thereof, the ultraviolet-shielding glass sheet having a Tuv 400 of 2.0% or less.

21. An ultraviolet-shielding laminated glass sheet comprising:
a first glass sheet, a second glass sheet, and an interlayer disposed for glass lamination between the first glass sheet and the second glass sheet, wherein
at least one selected from the first glass sheet and the second glass sheet is the ultraviolet-shielding glass sheet according to claim 1 .

22. A vehicle window pane, comprising the ultraviolet-shielding laminated glass sheet according to claim 21 .

23. The ultraviolet-shielding glass sheet according to claim 1 , comprising 3 to 20 wt % MgO and 5 to 20 wt % CaO as the basic component.

24. The ultraviolet-shielding glass sheet according to claim 1 , wherein the glass composition is substantially free of SrO and BaO.

25. The ultraviolet shielding glass according to claim 1 , wherein the RO content is 20 wt % or less.

Assignees

• Nippon Sheet Glass Co Ltd

Inventors

• Seto Hiromitsu

Classifications

• C03C3/087 Primary

  containing calcium oxide, e.g. common sheet or container glass · CPC title

• C03B2201/40

  doped with transition metals other than rare earth metals, e.g. Zr, Nb, Ta or Zn · CPC title

• B60J1/00

  Windows; Windscreens; Accessories therefor (B60J10/00 takes precedence; air curtains instead of windows B60J9/04 {; sealing strips for windshields B60J10/70; sealing sash guides for sliding window panes B60J10/74; glass partitions inside vehicles to protect occupants against personal attack B60R21/12}) · CPC title

• C03C2201/40

  containing transition metals other than rare earth metals, e.g. Zr, Nb, Ta or Zn · CPC title

• C03C4/02

  for coloured glass · CPC title