Slurry composition for non-aqueous secondary battery positive electrode, positive electrode for non-aqueous secondary battery, and non-aqueous secondary battery

Patent metadata

Field	Value
Publication number	US-10985375-B2
Application number	US-201716331669-A
Country	US
Kind code	B2
Filing date	Sep 8, 2017
Priority date	Sep 20, 2016
Publication date	Apr 20, 2021
Grant date	Apr 20, 2021

Abstract

Provided is a slurry composition for a non-aqueous secondary battery positive electrode that has excellent stability and enables formation of a positive electrode mixed material layer that causes a non-aqueous secondary battery to display excellent output characteristics. The slurry composition contains a positive electrode active material and a copolymer. The proportion constituted by nickel among transition metal in the positive electrode active material is at least 30.0 mol % and not more than 100.0 mol %. The copolymer includes a nitrile group-containing monomer unit in a proportion of at least 70.0 mass % and not more than 96.0 mass % and a basic group-containing monomer unit in a proportion of at least 0.1 mass % and not more than 5.0 mass %.

First claim

The invention claimed is:

1. A slurry composition for a non-aqueous secondary battery positive electrode comprising a positive electrode active material and a copolymer, wherein
a proportion constituted by nickel among transition metal in the positive electrode active material is at least 30.0 mol % and not more than 100.0 mol %, and
the copolymer includes a nitrile group-containing monomer unit and an amide group-containing monomer unit, percentage content of the nitrile group-containing monomer unit in the copolymer when all repeating units in the copolymer are taken to be 100 mass % is at least 70.0 mass % and not more than 96.0 mass %, and percentage content of the amide group-containing monomer unit in the copolymer when all repeating units in the copolymer are taken to be 100 mass % is at least 0.1 mass % and not more than 5.0 mass %.

2. The slurry composition for a non-aqueous secondary battery positive electrode according to claim 1 , wherein the copolymer further includes an acidic group-containing monomer unit, and percentage content of the acidic group-containing monomer unit in the copolymer when all repeating units in the copolymer are taken to be 100 mass % is at least 0.1 mass % and not more than 10.0 mass %.

3. The slurry composition for a non-aqueous secondary battery positive electrode according to claim 1 , wherein the copolymer further includes a (meth)acrylic acid ester monomer unit, and percentage content of the (meth)acrylic acid ester monomer unit in the copolymer when all repeating units in the copolymer are taken to be 100 mass % is at least 1.0 mass % and not more than 20.0 mass %.

4. The slurry composition for a non-aqueous secondary battery positive electrode according to claim 1 , wherein the positive electrode active material is a lithium-containing composite metal oxide represented by a formula (A1): LiNi a Co b Mn c O 2 , where 0.3≤a≤1.0, 0≤b≤0.5, 0≤c≤0.5, and 0.9≤a+b+c≤1.1, or a formula (A2): LiNi x Co y Al z O 2 , where 0.7≤x≤1.0, 0≤y≤0.3, 0≤z≤0.1, and 0.9≤x+y+z≤1.1.

5. The slurry composition for a non-aqueous secondary battery positive electrode according to claim 1 , further comprising a conductive material, wherein the conductive material includes conductive carbon fiber.

6. The slurry composition for a non-aqueous secondary battery positive electrode according to claim 1 , wherein the copolymer has a weight-average molecular weight of at least 100,000 and not more than 1,500,000.

7. A positive electrode for a non-aqueous secondary battery comprising a positive electrode mixed material layer formed using the slurry composition for a non-aqueous secondary battery positive electrode according to claim 1 .

8. The positive electrode for a non-aqueous secondary battery according to claim 7 , wherein the positive electrode mixed material layer has a density of at least 2.5 g/cm 3 and not more than 3.8 g/cm 3 .

9. A non-aqueous secondary battery comprising a positive electrode, a negative electrode, an electrolyte solution, and a separator, wherein the positive electrode is the positive electrode for a non-aqueous secondary battery according to claim 7 .

Assignees

• Zeon Corp

Inventors

• ANNAKA Koji
• Ishii Takuya

Classifications

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/622 Primary

  being polymers · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/131 Primary

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title

• H01M10/052

  Li-accumulators · CPC title