Resonant chemical sensor comprising a functionalisation device and method for the production thereof

Patent metadata

Field	Value
Publication number	US-10983093-B2
Application number	US-201716319529-A
Country	US
Kind code	B2
Filing date	Jul 25, 2017
Priority date	Jul 28, 2016
Publication date	Apr 20, 2021
Grant date	Apr 20, 2021

Abstract

A chemical sensor including at least one resonant detection structure, the detection structure including at least one layer based on a porous material, the pores of which are covered with at least one functionalization layer that can adsorb or absorb at least one chemical species.

First claim

The invention claimed is:

1. A chemical sensor comprising:
at least one resonant detection structure, the detection structure including at least one receiving matrix based on a porous material of which the pores are covered or filled with at least one first functionalization layer based on a first microporous or nanoporous organic material provided to adsorb and/or absorb at least one first chemical species,
the porous material being coated with a closure layer of the pores, the closure layer being arranged on or above the first functionalization layer and configured to allow one or plural chemical species to penetrate inside the pores and to prevent one or plural other chemical species from penetrating inside the pores.

2. The chemical sensor according to claim 1 , the first organic material being chosen from the following materials: organic-inorganic hybrid material, polymer material.

3. The chemical sensor according to claim 1 , wherein the pores are covered with the first functionalization layer and further filled at least partially with at least one second functionalization layer arranged on and in contact with the first functionalization layer, the second functionalization layer able to adsorb and/or absorb at least one second chemical species, the second functionalization layer being based on a second organic material, different from the first organic material.

4. The chemical sensor according to claim 3 , the second material being chosen from the following materials: organic-inorganic hybrid material; microporous or nanoporous material having an organic function; polymer material.

5. The chemical sensor according to claim 3 , wherein at least one among the functionalization layers is provided to adsorb and/or absorb CO 2 , at least one other layer among the functionalization layers is provided to adsorb and/or absorb H 2 .

6. The chemical sensor according to claim 1 , the closure layer of the pores being hydrophobic.

7. The chemical sensor according to claim 1 , wherein the first organic material has an organic function based on silane or based on microporous silica rendered organic.

8. A method for producing a chemical sensor according to claim 1 , wherein the detection structure is provided with a layer of the porous material, the first functionalization layer is formed by liquid or gas phase deposition of a solution on all or a portion of the layer of porous material.

9. The method according to claim 8 , further comprising, after liquid phase deposition, rotating a support on which the layer of porous material is arranged.

10. The method according to claim 8 , further comprising, after liquid phase deposition, spreading the liquid solution by a scraper.

11. A method for producing a chemical sensor according to claim 1 , wherein the detection structure includes a layer of the porous material, the first functionalization layer is formed by compliant deposition to cover all or a portion of the pores while leaving at least one empty volume in the pores, the pores being then at least partially filled or covered with a second material to form in the volume at least one second functionalization layer arranged on and in contact with the first functionalization layer.

12. A method for producing a chemical sensor according to claim 1 , wherein a layer of the porous material is formed by anodic oxidation.

13. The method for producing a chemical sensor according to claim 12 , wherein the layer of the porous material is formed by anodic oxidation of an aluminium layer, the aluminium layer being arranged on an oxidation barrier layer.

Assignees

• Commissariat Energie Atomique

Inventors

• Claret Thierry
• Bottausci Frederic
• Parat Guy-Michel
• Vignoud Severine

Classifications

• G01N2291/0255

  (Bio)chemical reactions, e.g. on biosensors · CPC title

• B81B2201/0214

  Biosensors; Chemical sensors · CPC title

• B81C1/00206

  Processes for functionalising a surface, e.g. provide the surface with specific mechanical, chemical or biological properties · CPC title

• G01N2291/0256

  Adsorption, desorption, surface mass change, e.g. on biosensors · CPC title

• G01N2291/0257

  with a layer containing at least one organic compound · CPC title