Method of calibrating an X ray diffraction analysis system
US-10386508-B2 · Aug 20, 2019 · US
US10983070B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10983070-B2 |
| Application number | US-201916448227-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 21, 2019 |
| Priority date | Jun 22, 2018 |
| Publication date | Apr 20, 2021 |
| Grant date | Apr 20, 2021 |
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The invention is a method for characterizing an object ( 20 ), comprising the following steps: a) placing the object between a radiation source ( 10 ) and a radiation detector ( 30 ); b) irradiating the object with the radiation source and detecting radiation transmitted by the object ( 14 ) using the radiation detector, the radiation detector defining a plurality of pixels; c) for each pixel ( 30 i ), forming an energy spectrum (S i ) of the detected radiation, each spectrum comprising at least two distinct energy bands; d) from each spectrum formed in c), estimating, in each pixel, at least two equivalent thicknesses ({circumflex over (L)} i,1 . . . {circumflex over (L)} i,M ,{circumflex over (L)}′ i,1 . . . {circumflex over (L)}′ i,M ) respectively associated with at least two basic materials (mat 1 . . . mat M ,mat′ 1 . . . mat′ M ); wherein the method comprises, following d), the following steps: e) from the equivalent thicknesses resulting from d), calculating a structural parameter (P i ) of the object in various pixels ( 30 i ); f) spatially smoothing the structural parameter calculated in a plurality of pixels; g) from the structural parameter smoothed in each pixel, and from each spectrum formed in c), estimating, in each pixel, regularized equivalent thicknesses ({circumflex over (L)} i,m=1 |P i * . . . {circumflex over (L)} i,m=M |P i *,{circumflex over (L)}′ i,m=1 |P i * . . . {circumflex over (L)} i,m=M |P i *).
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The invention claimed is: 1. A method for characterizing an object, comprising: a) placing the object between a radiation source and a radiation detector, the radiation source being configured to emit ionizing electromagnetic radiation that propagates to the object; b) irradiating the object with the radiation source and detecting radiation transmitted by the object using the radiation detector, the radiation detector comprising a plurality of pixels, each pixel being associated with one portion of the object; c) for each pixel, forming an energy spectrum of the detected radiation, each spectrum comprising at least two distinct energy bands; d) from each spectrum formed in c), estimating, in each pixel, at least two equivalent thicknesses respectively associated with at least two basic materials; wherein the method comprises, following d): e) from the equivalent thicknesses resulting from d), calculating a structural parameter of the object in various pixels, the structural parameter of the object being for each pixel: a thickness of that portion of the object which is associated with the pixel; or representative of a composition of that portion of the object which is associated with the pixel. f) spatially smoothing the structural parameter calculated in a plurality of pixels, so as to associate, with each pixel, a smoothed structural parameter; g) from the structural parameter smoothed in each pixel, and from each spectrum formed in c), estimating, in each pixel, regularized equivalent thicknesses respectively associated with each basic material; h) characterizing the object from the regularized equivalent thicknesses estimated in g). 2. The method as claimed in claim 1 , wherein d) and/or g) comprise(s), for each pixel, taking into account calibration spectra, each calibration spectrum being associated with a thickness of each basic material. 3. The method as claimed in claim 2 , wherein d) and/or g) also comprise, for each pixel: calculating a likelihood function from the spectrum formed by the pixel in c) and from the calibration spectra, each calibration spectrum being associated with at least one calibration material of a known thickness; determining an equivalent thickness of each calibration material maximizing the likelihood function, each calibration material forming a basic material. 4. The method as claimed in claim 3 , wherein d) and/or g) comprise(s) a change of basis, between a start basis, formed by the calibration materials, and an end basis, formed by the basic materials representative of the object, so as to obtain an equivalent thickness of each material of the end basis. 5. The method as claimed in claim 1 , wherein d) comprises: grouping adjacent pixels together, in order to form a group of pixels; associating, with each group of pixels, a grouped spectrum, combining the spectra formed for each pixel of the group of pixels; such that d) is implemented, for at least one pixel of a group of pixels, from the grouped spectrum associated with the group of pixels. 6. The method as claimed in claim 1 , wherein the structural parameter represents a composition of that portion of the object which is associated with each pixel, and wherein the structural parameter, determined in each pixel: is an effective atomic number, determined from the equivalent thicknesses estimated in d); or comprises a ratio between an equivalent thickness of a basic material and the sum of the equivalent thicknesses estimated in d). 7. The method as claimed in claim 1 , wherein h) comprises a characterization of the various portions of the object respectively associated with various pixels. 8. The method as claimed in claim 7 , wherein the characterization comprises: forming an image showing the regularized equivalent thickness of a basic material; and/or determining an effective atomic number from the regularized equivalent thicknesses of each basic material; and/or a ratio between a regularized equivalent thickness of a basic material and the sum of the regularized equivalent thicknesses of each basic material. 9. The method as claimed in claim 1 , wherein, in b), the detector is moved with respect to the object or the object is moved with respect to the detector. 10. A device for characterizing an object, comprising: a radiation source, configured to emit ionizing electromagnetic radiation; a holder, intended to receive the object, such that the object is placed between the radiation source and the detector; a detector, comprising pixels, the detector being configured to detect ionizing electromagnetic radiation and to form, in a plurality of pixels, a spectrum of the detected radiation; a processor, configured to receive the spectra formed by the detector and to implement d) to h) of a method as claimed in claim 1 .
multispectral imaging-multiple energy imaging · CPC title
and forming images of the material · CPC title
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