Method for comprehensively processing noble lead

Patent metadata

Field	Value
Publication number	US-10982299-B2
Application number	US-201916357369-A
Country	US
Kind code	B2
Filing date	Mar 19, 2019
Priority date	Dec 27, 2018
Publication date	Apr 20, 2021
Grant date	Apr 20, 2021

Abstract

A method for comprehensively processing noble lead provided and utilizes two instances of vacuum distillation to realize an open circuit of arsenic, lead, antimony and bismuth and the high-efficiency enrichment of precious metals of gold and silver, and can obtain elemental arsenic, a lead-bismuth-antimony alloy, a silver alloy and a copper alloy, respectively. The lead-bismuth-antimony alloy, the silver alloy and the copper alloy are processed by oxidation refining, electrorefining and chlorination refining to obtain refined lead, refined antimony, antimony trioxide, electrolytic silver and electrolytic copper, and to realize gold enrichment. The entire process has advantages of high metal direct yield, low energy consumption, short flow chart, simple equipment, etc., and vacuum distillation belongs to a physical process in which the alloy can be separated only by means of the difference in saturated vapor pressure between the metals, without generation of wastewater, waste gas and waste residue.

First claim

What is claimed is:

1. A method for comprehensively processing a noble lead, comprising:
(1) subjecting the noble lead to a first vacuum distillation to obtain a volatile matter and a residue, wherein constituent elements of the noble lead comprise lead, antimony, arsenic, bismuth, copper, silver and gold,
subjecting the volatile matter to two-stage condensation to obtain a lead-bismuth-antimony alloy and elemental arsenic respectively;
subjecting the lead-bismuth-antimony alloy to oxidation refining to obtain antimony trioxide and a lead-bismuth alloy; then electrolyzing the lead-bismuth alloy to obtain refined lead and bismuth anode mud; then sequentially subjecting the bismuth anode mud to reduction smelting and vacuum distillation to obtain silver and raw bismuth; and finally subjecting the raw bismuth to chlorination refining to obtain refined bismuth and lead chloride;
(2) subjecting the residue obtained in step (1) to a second vacuum distillation to obtain a silver alloy and a copper alloy;
subjecting the silver alloy to oxidation refining to obtain antimony trioxide and dore silver; and then subjecting the dore silver to electrorefining to obtain electrolytic silver and silver anode mud; and
(3) subjecting the copper alloy to oxidation refining to obtain antimony trioxide and blister copper, then subjecting the blister copper to electrorefining to obtain electrolytic copper and copper anode mud; then subjecting the copper anode mud to acid leaching to obtain a copper salt and a gold-rich silver slag; finally subjecting the gold-rich silver slag to electrorefining to obtain electrolytic silver and silver anode mud; and returning the copper salt to the electrorefining;
wherein in step (1) a mass content of the constituent elements of the noble lead is: 20-40% of Pb, 10-20% of Sb, 15%-40% of As, 5-10% of Bi, 5-10% of Cu, 10-15% of Ag, and 5-1500 g/t of Au;
wherein for the first vacuum distillation of step (1), a temperature is 750-950° C., a time is 3-5 hours, and a pressure is 1-100 Pa;
wherein for the chlorination refining in step (1), a temperature is 350-500° C., and a time is 5-6 hours; and during the chlorination refining, a pressure of the chlorine is 0.31-0.5 kPa;
wherein for the second vacuum distillation of step (2), a temperature is 1,100-1,500° C., a time is 2-4 hours, and a pressure is 1-100 Pa.

2. The method of claim 1 , wherein the two-stage condensation of step (1) comprises first-stage condensation and second-stage condensation, a temperature for the first-stage condensation is 300-500° C.; and a temperature for the second-stage condensation is 25-250° C.

3. The method of claim 1 , wherein for the oxidation refining of step (1), a temperature is 800-1200° C., a time is 6-24 hours, an oxidation atmosphere is air, an air flow is 5-20 Nm 3 /min, and a pressure is 150-300 kPa.

4. The method of claim 1 , wherein in step (1), during the electrolyzation of the lead-bismuth alloy, a current density is 180-200 A/m 2 , a voltage is 0.3-0.6 V, a time is 24-48 hours, a temperature is 40-55° C., and an electrolyte circulation speed is 20-30 L/min.

5. The method of claim 1 , wherein in step (1), during the reduction smelting and vacuum distillation of the bismuth anode mud, a reducing agent for the reduction smelting is anthracite, and a mass of the reducing agent is 0.5-5% by mass of the bismuth anode mud; and for the vacuum distillation, a temperature is 800-1050° C., a time is 2.5-3.5 hours, and a pressure is 1-100 Pa.

6. The method of claim 1 , further comprising conducting gold extraction treatment on the silver anode mud obtained from step (2) and the silver anode mud obtained from step (3).

Assignees

• Univ Kunming Science & Technology
• Kunming Dingbang Tech Co Ltd

Inventors

• Yang Bin
• Liu Dachun
• Jiang Wenlong
• Zha Guozheng
• Xu Baoqiang
• Dai Weiping
• Li Yifu
• Yu Qingchun
• Chen Xiumin
• Yang Hongwei
• Tian Yang
• Deng Yong
• Wang Fei
• Xiong Heng
• Yang Jia
• Qu Tao
• Kong Lingxin

Classifications

• C22B7/001

  Dry processes · CPC title

• C22B11/021 Primary

  Recovery of noble metals from waste materials · CPC title

• Y02P10/20

  Recycling · CPC title

• C22B13/06

  Refining · CPC title

• C22B30/04

  Obtaining arsenic {(extraction of metal compounds by leaching in organic solutions C22B3/16; treatment or purification of solutions by adsorption on solids C22B3/24, by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42)} · CPC title