500 MPA yield strength-graded, high-stretchability hot-dip aluminum-zinc and color-coated steel plate and manufacturing method therefore

Patent metadata

Field	Value
Publication number	US-10982296-B2
Application number	US-201615754635-A
Country	US
Kind code	B2
Filing date	Jul 25, 2016
Priority date	Aug 28, 2015
Publication date	Apr 20, 2021
Grant date	Apr 20, 2021

Abstract

An aluminium-zinc-hot-dipped and colour-coated steel plate having yield strength of ≥500 MPa and a high elongation and a manufacturing method thereof, with the chemical components in mass percentage of a substrate of the steel plate being: 0.07-0.15% of C, 0.02-0.5% of Si, 1.3-1.8% of Mn, N≤0.004%, S≤0.01%, Ti≤0.15%, Nb≤0.050%, and the balance being Fe and other inevitable impurities, and meanwhile satisfying the conditions of: (C+Mn/6)≥0.3%; Mn/S≥150; Nb satisfying 0.01%≤(Nb-0.22C-1.1N)≤0.05% where no Ti is contained; Ti satisfying 0.5≤Ti/C≤1.5 where no Nb is contained; and 0.04%≤(Ti+Nb)≤0.2% where Ti and Nb are added in combination. The steel plate has a tensile strength of ≥550 MPa, an elongation after fracture of ≥15%, a good strength and toughness and an excellent corrosion resistance.

First claim

The invention claimed is:

1. An aluminium-zinc-hot-dipped steel plate having a yield strength of ≥500 MPa and a high elongation, with the chemical components in mass percentage of a substrate of the steel plate consisting of: 0.07-0.15% of C, 0.02-0.5% of Si, 1.3-1.8% of Mn, N≤0.004%, S≤0.01%, Ti≤0.15%, Nb≤0.050%, and the balance being Fe and other inevitable impurities, wherein said chemical components satisfy formulae provided as follows:
(C+Mn/6)≥0.3%;
Mn/S≥150;
0.01%≤(Nb-0.22C-1.1 N)≤0.05%;
0.5≤Ti/C≤1.5; and
0.04%≤(Ti+Nb)≤0.2%; and
wherein the steel plate has a microstructure which is a complex phase structure comprising ferrite, cementite, fine precipitates, bainite, martensite and deformed banded grains.

2. The aluminium-zinc-hot-dipped steel plate of claim 1 , wherein said steel plate has a tensile strength of ≥550 MPa and an elongation after fracture of ≥15%.

3. The aluminium-zinc-hot-dipped steel plate of claim 1 , wherein the aluminium-zinc-hot-dipped steel plate has fine, uniform silver-white spangles on its surface.

4. The aluminium-zinc-hot-dipped steel plate of claim 3 , wherein the spangles has a grain diameter that is less than 10 mm.

5. The aluminium-zinc-hot-dipped steel plate of claim 4 , wherein the spangles have a grain diameter that is less than 5 mm.

6. The aluminium-zinc-hot-dipped steel plate of claim 1 , wherein the aluminium-zinc-hot-dipped steel plate has a dipping layer with the components in weight percentage being: 48-58% of Al, 40-50% of Zn, 1.0-2.0% of Si, 0.005-0.050% of Ti, and the balance being inevitable impurities.

7. A steel plate comprising the aluminium-zinc-hot-dipped steel plate of claim 1 with a coating layer coated on its surface.

8. The steel plate of claim 7 , wherein the coating layer comprises a fluorocarbon, a polyester, a silicon-modified polyester, a highly weather resistant polyester, or a polyvinylidene fluoride.

9. The steel plate of claim 7 , wherein the aluminium-zinc-hot-dipped steel plate has a tensile strength of ≥550 MPa and an elongation after fracture of ≥15%.

10. The steel plate of claim 7 , wherein the aluminium-zinc-hot-dipped steel plate has fine, uniform silver-white spangles on its surface.

11. The steel plate of claim 7 , wherein the spangles have a grain diameter that is less than 10 mm.

12. The steel plate of claim 7 , wherein the aluminium-zinc-hot-dipped steel plate has a dipping layer with the components in weight percentage being: 48-58% of Al, 40-50% of Zn, 1.0-2.0% of Si, 0.005-0.050% of Ti, and the balance being inevitable impurities.

13. A method for producing the aluminium-zinc-hot-dipped steel plate of claim 1 , said method comprising the steps of:
1) smelting and casting the components according to claim 1 to obtain the cast slab;
2) hot-rolling and pickling the casting slab from step 1, wherein the heating tapping temperature is 1150-1280° C., the finish rolling temperature of the hot rolling is 800-900° C. and the hot rolling coiling temperature is 500-650° C.; and a cooling method after the hot rolling, which method is water cooling;
3) cold-rolling to form a steel strip with a rolling reduction of 70-80%;
4) continuous annealing in a non-oxidation continuous annealing aluminium-zinc-hot-dipping furnace comprising a direct-fired heating section, a radiant tube heating section, a soaking section, a pre-hot-dipping cooling section, a hot tension roller zone and a hot-dipping section, and post-hot-dipping cooling, wherein the duration in the direct-fired heating section is 20-60 s, with the heating temperature being 650-710° C.; the duration in the radiant tube heating section is 30-60 s, with the heating temperature being 750-840° C.; the duration in the temperature holding section is 1-10 s, with the soaking temperature being 750-840° C.; the duration in the post-hot-dipping cooling section is 8-15 s; the duration in the hot tension roller zone and the hot-dipping section is 8-12 s; and the post-hot-dipping cooling rate is ≥20° C./s;
5) hot-dipping the steel strip in a zinc pot for a hot-dipping treatment to obtain a high-strength low-alloy aluminium-zinc-hot-dipped steel strip, with the components in weight percentage of the hot-dipping liquid being: 48-58% of Al, 40-50% of Zn, 1.0-2.0% of Si, 0.005-0.050% of Ti and the balance being inevitable impurities, and the zinc pot temperature being 550-610° C.; and
6) skin pass rolling and withdrawing-straightening, the temper rolling ratio being 0.25%±0.2 and a withdrawing-straightening ratio being 0.2%±0.2.

14. The method of claim 13 , further comprising step 7: coating with a coating layer selected from the group consisting of a fluorocarbon, a polyester, a silicon-modified polyester, a highly weather resistant polyester, and a polyvinylidene fluoride.

15. The method of claim 14 , wherein, after being coated, the coating surface does not have the defects of bubbles, cracks and holidays.

16. The method of claim 13 , wherein cold gas jet cooling or gas-mist jet cooling is used for the post-hot-dipping cooling in step 4).

17. The method of claim 13 , wherein said steel plate has a tensile strength of ≥550 MPa and an elongation after fracture of ≥15%.

18. The method of claim 13 , the aluminium-zinc-hot-dipped steel plate has fine, uniform silver-white spangles on its surface.

19. The method of claim 18 , wherein the spangles has a grain diameter that is less than 10 mm.

Assignees

• Baoshan Iron & Steel

Inventors

• Li Jun
• Xu Dechao
• Liu Xin
• Ding Zhilong
• Ren Yuling
• Ye Xuewei
• Hu Hengfa
• Chen Hongming

Classifications

• C21D8/02

  during manufacturing of plates or strips (C21D8/12 takes precedence) · CPC title

• Y02P10/20

  Recycling · CPC title

• C21D2211/008

  Martensite · CPC title

• C23C2/12

  Aluminium or alloys based thereon · CPC title

• C22C30/06

  containing zinc · CPC title