Carbon dioxide electrolytic device and method of electrolyzing carbon dioxide

Patent metadata

Field	Value
Publication number	US-10981848-B2
Application number	US-201916288145-A
Country	US
Kind code	B2
Filing date	Feb 28, 2019
Priority date	Sep 18, 2018
Publication date	Apr 20, 2021
Grant date	Apr 20, 2021

Abstract

A carbon dioxide electrolytic device includes: an electrolysis cell including a cathode, an anode, cathode and anode flow paths, and a separator; a carbon dioxide source to supply carbon dioxide to the cathode flow path; a solution source to supply an electrolytic solution containing water to the anode flow path; at least one sensor to acquire at least one data of a data indicating a discharge amount per unit time of a liquid containing water to be discharged from at least one flow path and a data indicating a concentration of at least one ion in the liquid; a refresh material source including a gas source to supply a gaseous substance to the at least one flow path; and a controller programmed to stop the supply of the carbon dioxide and the electrolytic solution, and start supply of a gaseous substance from the refresh material source, in accordance with the at least one data.

First claim

What is claimed is:

1. A carbon dioxide electrolytic device, comprising:
an electrolysis cell including
a cathode to reduce a first substance containing carbon dioxide and thus produce a first product containing a carbon compound,
an anode to oxidize a second substance containing water or hydroxide ions and thus produce a second product containing oxygen,
a cathode flow path facing the cathode,
an anode flow path facing the anode, and
a separator separating the anode and the cathode;

a carbon dioxide source to supply the carbon dioxide to the cathode flow path;
a solution source to supply an electrolytic solution containing water to the anode flow path;
at least one sensor to acquire at least one data selected from the group consisting of a data indicating a discharge amount per unit time of a liquid containing water to be discharged from at least one flow path selected from the group consisting of the anode and cathode flow paths and a data indicating a concentration of at least one ion selected from the group consisting of ions in the liquid;
a power controller to apply a voltage between the anode and the cathode;
a refresh material source including a gas source to supply a gaseous substance to the at least one flow path; and
a controller programmed to stop the supply of the carbon dioxide and the electrolytic solution, and start the supply of the gaseous substance from the refresh material source to the at least one flow path, in accordance with the at least one data.

2. The device according to claim 1 , further comprising
a flow path to supply the liquid to be discharged from the cathode flow path to the anode flow path through the solution source.

3. The device according to claim 2 , further comprising:
a first tank connected to the cathode flow path and configured to store the liquid; and
a second tank connected to the anode flow path and configured to store the electrolytic solution.

4. The device according to claim 1 , wherein:
the solution source has a tank to store a solution containing the liquid; and
the at least one sensor has a liquid level sensor to acquire a data indicating a height of a liquid surface of the solution in the tank.

5. The device according to claim 1 , wherein
the at least one sensor has a sensor to acquire a data indicating a refractive index of light or a pressure inside the at least one flow path.

6. The device according to claim 1 , wherein
a refresh material source further includes a solution supply source to supply a rinse solution to the at least one flow path, and
the controller programmed to supply the rinse solution from the solution supply source and the gaseous substance from the gas source to the at least one flow path exposed from the electrolytic solution.

7. The device according to claim 1 , further comprising
a flow rate controller controlled by the controller and configured to adjust a flow rate of at least one selected from the group consisting of the rinse solution and the gaseous sub stance.

8. The device according to claim 1 , wherein
the gaseous substance contains at least one selected from the group consisting of air, carbon dioxide, oxygen, nitrogen, and argon.

9. A carbon dioxide electrolytic device, comprising:
an electrolysis cell including
a cathode to reduce a first substance containing carbon dioxide and thus produce a first product containing a first carbon compound,
an anode to oxidize a second substance containing water or hydroxide ions and thus produce a second product containing oxygen,
a cathode flow path facing the cathode,
an anode flow path facing the anode, and
a separator separating the anode and the cathode;

a carbon dioxide source to supply the carbon dioxide to the cathode flow path;
a solution source to supply an electrolytic solution containing the water to the anode flow path;
a power controller to apply a voltage between the anode and the cathode;
a refresh material source including a gas source to supply a gaseous substance to at least one flow path selected from the group consisting of the anode and cathode flow paths;
a reactor to produce a third product containing a second carbon compound by using the first product supplied through the cathode flow path;
a discharge flow path connected to the reactor;
at least one sensor to acquire at least one data selected from the group consisting of a data indicating a discharge amount per unit time of a liquid containing water to be discharged from the discharge flow path and a data indicating a concentration of at least one ion selected from the group consisting of ions in the liquid; and
a controller programmed to stop the supply of the carbon dioxide and the electrolytic solution, and start the supply of the gaseous substance from the refresh material source to the at least one flow path, in accordance with the at least one data.

10. The device according to claim 9 , further comprising
a tank connected to the discharge flow path and configured to store the liquid, wherein
the at least one sensor has a liquid level sensor to acquire a data indicating a height of a liquid surface of the liquid in the tank.

11. The device according to claim 9 , wherein
the at least one sensor has a sensor to acquire a data indicating a refractive index of light or a pressure inside the discharge flow path.

12. A method of electrolyzing carbon dioxide, comprising:
supplying carbon dioxide to a cathode flow path facing a cathode to reduce a first substance containing the carbon dioxide and thus produce a first product containing a carbon compound, and supplying an electrolytic solution containing water to an anode flow path facing an anode to oxidize a second substance containing water or hydroxide ions and thus produce a second product containing oxygen;
applying a voltage between the cathode and the anode to reduce the first substance and thus produce the first product on the cathode, and to oxidize the second substance and thus produce the second product on the anode;
acquiring at least one data selected from the group consisting of a data indicating a discharge amount per unit time of a liquid containing water to be discharged from at least one flow path selected from the group consisting of the anode and cathode flow paths and a data indicating a concentration of at least one ion selected from the group consisting of ions in the liquid; and
stopping the supply of the carbon dioxide and the electrolytic solution, and starting supply of a gaseous substance to the at least one flow path, in accordance with the at least one data.

13. A method of electrolyzing carbon dioxide, comprising:
supplying carbon dioxide to a cathode flow path facing a cathode to reduce a first substance containing the carbon dioxide and thus produce a first product containing a first carbon compound, and supplying an electrolytic solution containing water to an anode flow path facing an anode to oxidize a second substance containing water or hydroxide ions and thus produce a second product containing oxygen;
applying a voltage between the cathode and the anode to reduce the first substance and thus produce the first product on the cathode, and to oxidize the second substance and thus produce the second product on the anode;
supplying the first product to a reactor through the cathode flow path, and producing a third product containing a second carbon compound by using the first product;
acquiring at least one data selected from the group consisting of a data indicating a discharge amount per unit time of a liquid containing water to be discharged from the reactor and a data indicating a concentration of at

Assignees

• Toshiba Kk

Inventors

• Ono Akihiko
• Kudo Yuki
• Kitagawa Ryota
• Yamagiwa Masakazu
• Tamura Jun
• Mikoshiba Satoshi
• Sugano Yoshitsune
• MOTOSHIGE Asahi

Classifications

• C25B15/029

  Concentration · CPC title

• C25B15/025

  of electrolyte parameters · CPC title

• C25B3/26

  of carbon dioxide · CPC title

• C25B3/07

  Oxygen containing compounds · CPC title

• C25B3/03

  Acyclic or carbocyclic hydrocarbons · CPC title