Method of dispersing nanoparticles in different mediums and methods to achieve superior thermoelectric performances in carbon nanotube polymer systems

Patent metadata

Field	Value
Publication number	US-10978629-B2
Application number	US-201515527699-A
Country	US
Kind code	B2
Filing date	Dec 7, 2015
Priority date	Dec 5, 2014
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

Provided herein is a method for forming a composite. The method can include mixing a plurality of carbon nanotubes (CNTs) and a plurality of magnetic nanoparticles in a non-polar medium. At least some of the plurality of CNTs form entangled CNTs. The method also includes attaching first ones of the plurality of magnetic nanoparticles to exposed surfaces of the entangled CNTs; disentangling the entangled CNTs to form a plurality of dispersed CNTs; and aligning the plurality of dispersed CNTs. The disentangling of the entangled CNTs to form a plurality of dispersed CNTs includes exposing the plurality of magnetic nanoparticles and the plurality of entangled CNTs to electromagnetic energy.

First claim

What is claimed is:

1. A fiber reinforced polymer composite, comprising:
a plurality of composite plies extending in a parallel-plane direction, wherein each composite ply comprises a plurality of continuous microfibers aligned in the parallel-plane direction,
a plurality of aligned carbon nanotubes (CNTs) extending across an inter-ply interface disposed between adjacent ones of the plurality of composite plies, wherein each of the aligned carbon nanotubes extends into the composite ply on each side of the inter-ply interface, and
a plurality of magnetic nanoparticles bonded to surfaces of the plurality of aligned CNTs, wherein the plurality of magnetic nanoparticles comprise a coating comprising a charged polymer.

2. The fiber reinforced polymer composite of claim 1 , wherein the plurality of aligned carbon nanotubes comprise up to about 5% by weight of the fiber reinforced polymer composite.

3. The fiber reinforced polymer composite of claim 1 , wherein the plurality of aligned carbon nanotubes comprise single walled carbon nanotubes, multi-walled carbon nanotubes, or a combination thereof.

4. The fiber reinforced polymer composite of claim 1 , wherein the magnetic nanoparticles comprise iron, nickel, or cobalt.

5. The fiber reinforced polymer composite of claim 1 , wherein the magnetic nanoparticles comprise iron oxide.

6. The fiber reinforced polymer composite of claim 1 , wherein the magnetic nanoparticles comprise a functional group that reacts with surfaces of the plurality of aligned carbon nanotubes.

7. The fiber reinforced polymer composite of claim 1 , wherein the plurality of magnetic nanoparticles are bonded to surfaces of the plurality of aligned CNTs by van der walls forces.

8. The fiber reinforced polymer composite of claim 1 , wherein magnetic nanoparticles comprise an amount of at least about 0.01 wt % of the fiber reinforced polymer composite.

9. The fiber reinforced polymer composite of claim 1 , wherein the fiber reinforced polymer composite comprises an improved cross-plane electrical conductivity compared to a fiber reinforced polymer composite without the plurality of aligned carbon nanotubes extending across the inter-ply interface disposed between adjacent ones of the plurality of composite plies.

10. The fiber reinforced polymer composite of claim 1 , wherein the fiber reinforced polymer composite comprises an improved delamination resistance compared to a fiber reinforced polymer composite without the plurality of aligned carbon nanotubes extending across the inter-ply interface disposed between adjacent ones of the plurality of composite plies.

11. A fiber reinforced polymer composite, comprising:
a plurality of composite plies extending in a parallel-plane direction, wherein each composite ply comprises a plurality of continuous microfibers aligned in the parallel-plane direction,
a plurality of aligned carbon nanotubes (CNTs) extending across an inter-ply interface disposed between adjacent ones of the plurality of composite plies, wherein each of the aligned carbon nanotubes extends into the composite ply on each side of the inter-ply interface, and
a plurality of magnetic nanoparticles bonded to surfaces of the plurality of aligned CNTs, wherein the plurality of magnetic nanoparticles comprise a functional group that reacts with surfaces of the plurality of aligned carbon nanotubes.

12. The fiber reinforced polymer composite of claim 11 , wherein the plurality of aligned carbon nanotubes comprise up to about 5% by weight of the fiber reinforced polymer composite.

13. The fiber reinforced polymer composite of claim 11 , wherein the plurality of aligned carbon nanotubes comprise single walled carbon nanotubes, multi-walled carbon nanotubes, or a combination thereof.

14. The fiber reinforced polymer composite of claim 11 , wherein the magnetic nanoparticles comprise iron, nickel, or cobalt.

15. The fiber reinforced polymer composite of claim 11 , wherein the magnetic nanoparticles comprise iron oxide.

16. The fiber reinforced polymer composite of claim 11 , wherein the plurality of magnetic nanoparticles comprise a coating comprising a charged polymer.

17. The fiber reinforced polymer composite of claim 11 , wherein the plurality of magnetic nanoparticles are bonded to surfaces of the plurality of aligned CNTs by van der walls forces.

18. The fiber reinforced polymer composite of claim 11 , wherein magnetic nanoparticles comprise an amount of at least about 0.01 wt % of the fiber reinforced polymer composite.

19. The fiber reinforced polymer composite of claim 11 , wherein the fiber reinforced polymer composite comprises an improved cross-plane electrical conductivity compared to a fiber reinforced polymer composite without the plurality of aligned carbon nanotubes extending across the inter-ply interface disposed between adjacent ones of the plurality of composite plies.

20. The fiber reinforced polymer composite of claim 11 , wherein the fiber reinforced polymer composite comprises an improved delamination resistance compared to a fiber reinforced polymer composite without the plurality of aligned carbon nanotubes extending across the inter-ply interface disposed between adjacent ones of the plurality of composite plies.

Assignees

• Unm Rainforest Innovations

Inventors

• Tehrani Mehran

Classifications

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• C08K2003/0856

  Iron · CPC title

• C08J7/0423

  with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder · CPC title

• C08K3/08

  Metals · CPC title