Composition, color converting sheet and light-emitting diode device
US-2019031954-A1 · Jan 31, 2019 · US
US10978620B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10978620-B2 |
| Application number | US-201816203025-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 28, 2018 |
| Priority date | Nov 30, 2017 |
| Publication date | Apr 13, 2021 |
| Grant date | Apr 13, 2021 |
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Provided are a light emitting device and an illumination device. The light emitting device is provided with a light emitting element having a light emission peak wavelength in a wavelength range of 380 nm or more and 490 nm or less, a first fluorescent material which is excited by the light from the light emitting element to emit light having at least one light emission peak wavelength in a wavelength range of 580 nm or more and less than 680, and a second fluorescent material which is excited by the light from the light emitting element to emit light having at least one light emission peak wavelength in a wavelength range of 680 nm or more and 800 nm or less, wherein a ratio R/B of a photon flux R of red light in a wavelength range of 620 nm or more and less than 700 nm to a photon flux B of blue light in a wavelength range of 400 nm or more and 490 nm or less is more than 4 and 50 or less, a ratio R/Fr of the photon flux R to a photon flux Fr of far-red light in a wavelength range of 700 nm or more and 780 nm or less is 0.1 or more and 10 or less, and the second fluorescent material contains at least one fluorescent material selected from the group consisting of a first aluminate fluorescent material and a second aluminate fluorescent material.
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The invention claimed is: 1. A light emitting device comprising: a light emitting element having a light emission peak wavelength in a wavelength range of 380 nm or more and 490 nm or less; and a first fluorescent material which is excited by the light from the light emitting element to emit light having at least one light emission peak in a wavelength range of 580 nm or more and less than 680 nm, and a second fluorescent material which is excited by the light from the light emitting element to emit light having at least one light emission peak in a wavelength range of 680 nm or more and 800 nm or less, wherein the second fluorescent material contains at least one fluorescent material selected from a first aluminate fluorescent material having a composition represented by the following formula (I) and a second aluminate fluorescent material having a composition represented by the following formula (II): (Al 1-w Cr w ) 2 O 3 (I) wherein w represents a number satisfying 0<w<1, (Ln 1-x-y Ce x Cr y ) 3 (Al 1-z M z ) 5 O 12 (II) wherein Ln represents at least one rare earth element selected from the group consisting of rare earth elements except Ce, M represents at least one element selected from the group consisting of Ga and In, x, y and z each are a number satisfying 0.0002<x<0.50, 0.0001<y<0.05, and 0≤z≤0.8, and wherein the light emitting device emits light having a ratio R/B of a photon flux R to a photon flux B within a range of more than 10 and 38 or less, and a ratio R/Fr of the photon flux R to a photon flux Fr within a range of 0.1 or more and 10 or less, wherein the photon flux R is in a range of 620 nm or more and less than 700 nm, the photon flux B is in a range of 400 nm or more and 490 nm or less, and the photon flux Fr is in a range of 700 nm or more and 780 nm or less. 2. The light emitting device according to claim 1 , wherein a ratio of the second fluorescent material to a total of the first fluorescent material and the second fluorescent material is 2% by mass or more and 80% by mass or less. 3. The light emitting device according to claim 1 , wherein the first fluorescent material contains a nitride fluorescent material having a composition containing Eu, Al, Si and at least one element selected from Sr and Ca. 4. The light emitting device according to claim 3 , wherein the first fluorescent material contains a nitride fluorescent material having a composition represented by the following formula (III): (Ca 1-p-q Sr p Eu q )AlSiN 3 (III) wherein p and q each satisfy 0≤p≤1.0, 0<q<0.5, 0<p+q≤1.0. 5. The light emitting device according to claim 1 , comprising a fluorescent member containing the first fluorescent material, the second fluorescent material and a resin, wherein the fluorescent member contains the second fluorescent material in an amount of 0.5 parts by mass or more and 100 parts by mass or less relative to 100 parts by mass of the resin. 6. The light emitting device according to claim 2 , comprising a fluorescent member containing the first fluorescent material, the second fluorescent material and a resin, wherein the fluorescent member contains the second fluorescent material in an amount of 0.5 parts by mass or more and 100 parts by mass or less relative to 100 parts by mass of the resin. 7. The light emitting device according to claim 5 , wherein a total amount of the first fluorescent material and the second fluorescent material contained in the fluorescent member is 5 parts by mass or more and 150 parts by mass or less relative to 100 parts by mass of the resin therein. 8. The light emitting device according to claim 6 , wherein a total amount of the first fluorescent material and the second fluorescent material contained in the fluorescent member is 5 parts by mass or more and 150 parts by mass or less relative to 100 parts by mass of the resin therein. 9. The light emitting device according to claim 1 , which is used in combination with a light source that emits white light. 10. An illumination device comprising a combination of the light emitting device of claim 1 , and a light source that emits a light energy different from that of the light emitting device of claim 1 . 11. A plant cultivation method comprising irradiating plants with the light emitted by the light emitting device of claim 1 .
Silicon Aluminium Nitrides or Silicon Aluminium Oxynitrides · CPC title
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