Transient electronics using thermoresponsive materials

Patent metadata

Field	Value
Publication number	US-10978396-B2
Application number	US-201715817873-A
Country	US
Kind code	B2
Filing date	Nov 20, 2017
Priority date	Sep 30, 2016
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

A composite element and methods of fabrication thereof are provided. The composite element can include a binder material and one or more electrical traces supported by the binder material, where a composition of the binder material is a thermoresponsive material and where each of the one or more electrical traces comprises an interconnected network of nanoparticles.

First claim

What is claimed is:

1. A transient electrical circuitry system comprising:
binder material comprising a thermoresponsive material exhibiting lower critical solution temperature (LCST) behavior; and
one or more electrical traces supported by the binder material, wherein each of the one or more electrical traces comprises an interconnected network of nanoparticles;
wherein the binder material is in the form of a gel, while the thermoresponsive material is above the LCST, resulting in a maintaining of electrically conductive function of the one or more electrical traces; and
wherein the binder material is in the form of a liquid, when the thermoresponsive material is below the LCST, resulting in a loss of the electrically conductive function of the one or more electrical traces.

2. The transient electrical circuitry system of claim 1 , wherein at least one of the one or more electrical traces is at least partially embedded into the binder material.

3. The transient electrical circuitry system of claim 1 , wherein at least one of the one or more electrical traces is disposed at a surface of the binder material.

4. The transient electrical circuitry system of claim 1 , wherein the nanoparticles comprise nanowires.

5. The transient electrical circuitry system of claim 1 , wherein the nanoparticles comprise silver nanoparticles.

6. The transient electrical circuitry system of claim 1 , wherein the thermoresponsive material is a polymer.

7. The transient electrical circuitry system of claim 6 , wherein the polymer is selected from the group consisting of methyl cellulose and poly(N-isopropylacrylamide).

8. The transient electrical circuitry system of claim 1 , wherein the one or more electrical traces defines one or more passive electrical components.

9. The transient electrical circuitry system of claim 1 , wherein the binder material is shaped to have first and second opposing surfaces, and wherein the one or more electrical traces is disposed at the first and the second opposing surfaces, while the binder material is in the form of the gel.

10. A method for fabricating a transient electrical circuitry system, the method comprising:
forming at least one patterned layer on a substrate comprising one or more openings defining one or more exposed portions of the substrate;
depositing a nanoparticle layer over the at least one patterned layer and the one or more exposed portions of the substrate;
removing the at least one patterned layer and a portion of the nanoparticle layer above the at least one patterned layer so as to define a patterned nanoparticle layer on the substrate;
depositing a binder material over the substrate and the patterned nanoparticle layer so as to at least partially embed the patterned nanoparticle layer into the binder material; and
separating the binder material from the substrate,
wherein the binder material comprises a thermoresponsive material exhibiting lower critical solution temperature (LCST) behavior;
wherein the patterned nanoparticle layer is in the form of one or more electrical traces;
wherein the binder material is in the form of a gel, while the thermoresponsive material is above the LCST, resulting in a maintaining of electrically conductive function of the one or more electrical traces; and
wherein the binder material is in the form of a liquid, when the thermoresponsive material is below the LCST, resulting in a loss of the electrically conductive function of the one or more electrical traces.

11. The method of claim 10 , wherein the forming comprises depositing one or more masking layers and photolithographically patterning the one or more masking layers to define the at least one patterned layer.

12. The method of claim 11 , wherein the depositing of the nanoparticle layer comprises applying a suspension of nanoparticles over the at least one patterned layer and the one or more exposed portions of the substrate.

13. The method of claim 12 , wherein the nanoparticles comprise nanowires.

14. The method of claim 12 , wherein the nanoparticles comprise silver nanoparticles.

15. The method of claim 10 , wherein the thermoresponsive material is a polymer.

16. The method of claim 15 , wherein the polymer is selected from the group consisting of methyl cellulose and poly(N-isopropylacrylamide).

17. The method of claim 10 , wherein the one or more exposed portions of the substrate further defines one or more shapes for one or more passive electrical components.

18. The method of claim 10 , further comprising:
forming a second transient electrical circuitry system comprising the binder material and one or more other electrical traces supported by the binder material;
attaching the second transient electrical circuitry system to the transient electrical circuitry system.

19. A transient electrical circuitry system comprising:
binder material comprising a thermoresponsive polymeric material exhibiting lower critical solution temperature (LCST) behavior, the thermoresponsive polymeric material being selected from the group consisting of methyl cellulose and poly(N-isopropylacrylamide); and
one or more electrical traces supported by the binder material, wherein each of the one or more electrical traces comprises an interconnected network of nanoparticles, the nanoparticles comprising nanowires or silver nanoparticles;
wherein the binder material is in the form of a gel, while the thermoresponsive polymeric material is above the LCST, resulting in a maintaining of electrically conductive function of the one or more electrical traces; and
wherein the binder material is in the form of a liquid, when the thermoresponsive polymeric material is below the LCST, resulting in a loss of the electrically conductive function of the one or more electrical traces.

Assignees

• Univ Vanderbilt

Inventors

• Bellan Leon
• Zhang Xin

Classifications

• H10P76/2041

  Photolithographic processes · CPC title

• H10P50/287

  by chemical means · CPC title

• H10P14/46

  using a liquid · CPC title

• H10W70/695

  Organic materials · CPC title

• H10W70/69

  Insulating materials thereof · CPC title