Magnetic material and manufacturing method therefor

Patent metadata

Field	Value
Publication number	US-10978228-B2
Application number	US-201716087854-A
Country	US
Kind code	B2
Filing date	Mar 24, 2017
Priority date	Mar 25, 2016
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

Provided is a new magnetic material with high magnetic stability, as well as a manufacturing method therefor, said magnetic material having a higher saturation magnetization than ferrite-based magnetic materials, and having a higher electrical resistivity than existing metal-based magnetic materials, thus solving problems such as that of eddy current loss. Ti-ferrite nanoparticles obtained through wet synthesis are reduced within hydrogen, and grains are allowed to grow while simultaneously using a phase separation phenomenon due to a disproportionation reaction to produce a magnetic material powder in which an α-(Fe, Ti) phase and a Ti-enriched phase are nano-dispersed. This powder is then sintered to produce a solid magnetic material.

First claim

The invention claimed is:

1. A magnetic material, comprising a first phase having crystals with a bcc structure containing Fe and Ti and a second phase containing Ti, the second phase having a Ti content that is, when a sum of the Fe and the Ti contained in the second phase is taken to be 100 atom %, larger than a Ti content when a sum of the Fe and the Ti contained in the first phase is taken to be 100 atom %,
wherein the second phase comprises a phase having crystals with a bcc structure containing Fe and Ti, and the Ti content when the sum of the Fe and the Ti contained in the phase is taken to be 100 atom %, is an amount of 2 times or more and 10 5 times or less relative to the Ti content when the sum of the Fe and the Ti contained in the first phase is taken to be 100 atom % and/or the Ti content when the sum of the Fe and the Ti contained in the second phase is taken to be 100 atom % is 2 atom % or more and 100 atom % or less, and
wherein the magnetic material is in a powder form, and when the magnetic material is soft magnetic, the magnetic material has an average powder particle diameter of 10 nm or more and 5 mm or less, and when the magnetic material is semi-hard magnetic, the magnetic material has an average powder particle diameter of 10 nm or more and 10 μm or less.

2. The magnetic material according to claim 1 , wherein the magnetic material is soft magnetic.

3. The magnetic material according to claim 1 , wherein the first phase has a composition represented by a composition formula Fe 100−x Ti x (where x is 0.001≤x≤33 in terms of atomic percentage).

4. The magnetic material according to claim 1 , wherein the first phase has a composition represented by a composition formula Fe 100-x (Ti 100−y M y ) x/100 (where x and y are 0.001≤x≤33 and 0.001≤y<50 in terms of atomic percentage, and M is one or more of Zr, Hf, Mn, V, Nb, Ta, Cr, Mo, W, Ni, Co, Cu, Zn, and Si).

5. The magnetic material according to claim 1 , wherein the second phase comprises at least any one of a Ti-ferrite phase and a wustite phase.

6. The magnetic material according to claim 1 , wherein the second phase comprises a TiO 2 phase.

7. The magnetic material according to claim 1 , wherein the first phase and the second phase which have crystals with a bcc structure containing Fe and Ti have a volume fraction of 5% by volume or more based on the whole magnetic material.

8. The magnetic material according to claim 1 , wherein an average crystal grain size of the first phase, the second phase, or the whole magnetic material is 1 nm or more and less than 10 μm.

9. The magnetic material according to claim 1 , wherein at least the first phase has a bcc phase having a composition represented by a composition formula Fe 100−x Ti x (where x is 0.001≤x≤1 in terms of atomic percentage), and the bcc phase has a crystallite size of 1 nm or more and 100 nm or less.

10. The magnetic material according to claim 1 , wherein at least one of the first phase and the second phase is ferromagnetically coupled with adjacent phases.

11. The magnetic material according to claim 1 , wherein the first phase and the second phase are continuously bonded to each other directly or via a metal phase or an inorganic phase to form a massive state as the whole magnetic material.

12. The magnetic material according to claim 5 , wherein the magnetic material has a composition in a range of, based on the composition of the whole magnetic material, 20 atom % or more and 99.998 atom % or less of Fe, 0.001 atom % or more and 50 atom % or less of Ti, and 0.001 atom % or more and 55 atom % or less of O.

13. A method for producing the magnetic material according to claim 1 , comprising reducing a titanium ferrite powder having an average powder particle diameter of 1 nm or more and less than 1 μm in a reducing gas containing hydrogen gas at a reduction temperature of 400° C. or more and 1290° C. or less.

14. A method for producing the magnetic material according to by claim 1 , comprising reducing a titanium ferrite powder having an average powder particle diameter of 1 nm or more and less than 1 μm in a reducing gas containing hydrogen gas, and forming the first phase and the second phase by a disproportionation reaction.

15. A method for producing the magnetic material according to claim 11 , comprising reducing a titanium ferrite powder having an average powder particle diameter of 1 nm or more and less than 1 μm in a reducing gas containing hydrogen gas at a reduction temperature of 400° C. or more and 1290° C. or less to produce a magnetic material, and sintering the magnetic material.

16. A method for producing a soft magnetic or semi-hard magnetic material, comprising producing a magnetic material according to claim 13 , and performing annealing at least once after the reduction step.

17. A method for producing a soft magnetic or semi-hard magnetic material, comprising producing a magnetic material according to claim 14 , and performing annealing at least once after the reduction step.

18. A method for producing a soft magnetic or semi-hard magnetic material, comprising producing a magnetic material according to claim 15 , and performing annealing at least once after the reduction step.

19. A method for producing the magnetic material according to claim 11 , comprising reducing a titanium ferrite powder having an average powder particle diameter of 1 nm or more and less than 1 μm in a reducing gas containing hydrogen gas to produce a magnetic material, forming the first phase and the second phase by a disproportionation reaction, and sintering the magnetic material.

Assignees

• Aist

Inventors

• Imaoka Nobuyoshi
• Ozaki Kimihiro

Classifications

• H01F1/14791 Primary

  Fe-Si-Al based alloys, e.g. Sendust · CPC title

• B22F1/16

  Metallic particles coated with a non-metal (coated with lubricating or binding agents or with organic material B22F1/10) · CPC title

• B22F1/08

  Metallic powder characterised by particles having an amorphous microstructure · CPC title

• B22F3/00 Primary

  Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor {; Presses and furnaces} · CPC title

• H01F1/34

  non-metallic substances, e.g. ferrites · CPC title