Methods for making paper or board, a board tray and pulp particles coated with foamable polymer for use in the same

Patent metadata

Field	Value
Publication number	US-10975522-B2
Application number	US-201716076197-A
Country	US
Kind code	B2
Filing date	Feb 6, 2017
Priority date	Feb 12, 2016
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

The invention concerns a method of manufacturing paper or board, the paper or board obtained by the method, and a method of producing a tray from the board. In a fibrous stock for papermaking is incorporated an amount of polymer coated fibrous particles, which even have a foaming agent such as moisture contained therein. A web is formed from the fibrous stock on a forming fabric of a paper or board machine, followed by pressing and drying to a finished paper or board. As the paper or board is sufficiently heated the foaming agent within the particles evaporates, causing expansion and foaming of the polymer coating, which adds to malleability of the board as it is moulded into a shaped article such as a board tray. The invention even covers production of doubly coated fibrous particles for use in said methods, the inner coating layer being of a foamable polymer with a higher melt flow rate and the outer coating layer being of a non-foaming polymer of a lower melt flow rate.

First claim

The invention claimed is:

1. A method of manufacturing paper or board, comprising the steps of
(i) coating pulp fibres and a foaming agent with polymer, to produce polymer-coated foamable particles,
(ii) incorporating an amount of said particles into a fibrous stock for papermaking,
(iii) forming a web from said fibrous stock on a forming fabric of a paper or board machine,
(iv) pressing and drying said web to a paper or board layer, and
(v) heating said paper or board layer to have the foaming agent contained in the polymer-coated foamable particles to produce vapour or gas, which foams said polymer.

2. The method of claim 1 , wherein the foaming agent is moisture, which evaporates and foams the polymer.

3. The method of claim 1 , wherein a melt flow rate of the polymer is at least about 15 g/10 min at 190° C.

4. The method of claim 1 , wherein the polymer comprises low density polyethylene (LDPE).

5. The method of claim 1 , wherein
at step (i) said polymer-coated foamable particles are provided with a further polymer to form a double-layer coating having an inner layer and an outer layer, a melt viscosity of the polymer of the inner layer being higher than a melt viscosity of the further polymer of the outer layer, and
at step (v) the polymer of the inner layer is foamed by means of the foaming agent while the further polymer of the outer layer remains substantially unfoamed.

6. The method of claim 1 , wherein the pulp fibres in said polymer-coated foamable particles have a length of 1 to 50 mm.

7. The method of claim 1 , wherein a share of polymer in said polymer-coated foamable particles is 5 to 65 wt-%.

8. The method of claim 1 , wherein said polymer-coated foamable particles are added to the fibrous stock at a headbox of the paper or board machine, by mixing the polymer-coated foamable particles with liquid circulated in the process, to form 5 to 25% of the dry weight of the fibrous stock supplied onto the forming fabric.

9. The method of claim 1 , wherein said polymer-coated foamable particles are incorporated in a middle layer of a multilayer board.

10. The method of claim 1 , wherein a temperature at step (v) to foam the polymer is about 110 to 150° C.

11. The method of claim 1 , wherein the paper or board is provided with a further polymer coating layer on both sides thereof before the heating, which induces foaming in the polymer-coated foamable particles incorporated in the fibrous stock.

12. The method of claim 11 , wherein the further polymer used for coating the paper or board has a lower melt viscosity than the polymer of the particles incorporated in the fibrous stock.

13. The method of claim 11 , wherein foaming of the polymer is carried out before the newly produced paper or board is reeled.

14. The method of claim 1 , wherein a temperature at step (v) to foam the polymer is 115 to 125° C.

15. A method of manufacturing a board article, such as a tray or a plate, from board produced in accordance to step (i) to (iv) in claim 1 , comprising the steps of
(i) placing the board produced in step (iv) in claim 1 over a mould, which has a recess shaped to accord with the article being produced,
(ii) drawing the board against the mould by means of vacuum,
(iii) during step (ii), heating the board to induce foaming in the polymer-coated foamable particles incorporated in the board, and
(iv) cooling the newly moulded article to solidify the polymer within the board.

16. A method of producing polymer coated particles for use in the method of claim 5 , comprising the steps of
(i) suspending fibrous cellulosic particles of a length of 1 to 50 mm in a solution containing a foamable first thermoplastic polymer and a first solvent,
(ii) precipitating said first thermoplastic polymer onto said fibrous particles by means of added water and phase inversion, to obtain fibrous particles with enclosed humidity and a first polymer coating layer,
(iii) suspending the polymer-coated particles obtained at step (ii) in a solution containing a second thermoplastic polymer and a second solvent, said second thermoplastic polymer having a melt viscosity lower than the melt viscosity of said first thermoplastic polymer, and
(iv) precipitating said second thermoplastic polymer onto said fibrous particles by means of added water and phase inversion, to obtain fibrous particles with a double-layer polymer coating having an inner first polymer coating layer and an outer second polymer coating layer, in which the inner first polymer coating layer is foamable while the outer second polymer coating layer remains unfoamed.

Assignees

• Stora Enso Oyj

Inventors

• Räsänen Jari
• Hiltunen Mari
• Harlin Ali
• Koskela Hanna
• Laine Christiane
• Kela Laura

Classifications

• D21H21/22

  Agents rendering paper porous, absorbent or bulky · CPC title

• B32B2307/3065

  Flame resistant or retardant, fire resistant or retardant · CPC title

• D21F11/002 Primary

  by using a foamed suspension · CPC title

• B32B3/30

  characterised by a layer formed with recesses or projections, e.g. {hollows, grooves, protuberances, ribs (apertured layer B32B3/266; layer with cavities or internal voids B32B3/26)} · CPC title

• B32B2307/718

  Weight, e.g. weight per square meter · CPC title