Iridium oxide electrodeposited porous titanium composite layer of polymer electrolyte membrane water electrolysis apparatus, method for preparing the same, and polymer electrolyte membrane water electrolysis apparatus using the same

Patent metadata

Field	Value
Publication number	US-10975476-B2
Application number	US-201816198286-A
Country	US
Kind code	B2
Filing date	Nov 21, 2018
Priority date	Nov 29, 2017
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

The present disclosure relates to an IrO2 electrodeposited porous titanium composite layer of a polymer electrolyte membrane water electrolysis apparatus serving as both a diffusion layer and an oxygen electrode, the apparatus including: a porous titanium (Ti) layer; and an electrodeposited iridium oxide (IrO2) layer on the porous Ti layer. The IrO2 layer may be uniformly deposited on a porous Ti layer through an electrolysis process, and the electrodeposited IrO2 layer may play multiple roles as not only a catalyst layer toward oxygen evolution reaction (OER) on the surface of the Ti layer, but also a corrosion-protection layer which prevents an inner Ti layer from corrosion.

First claim

What is claimed is:

1. An IrO 2 electrodeposited porous titanium composite layer of a polymer electrolyte membrane water electrolysis apparatus serving as both a diffusion layer and an oxygen electrode, the apparatus comprising:
a porous titanium (Ti) layer; and
an electrodeposited iridium oxide (IrO 2 ) layer on the porous Ti layer;
wherein the porous Ti layer is in a form of titanium mesh having a porosity of 60% to 70%;
wherein the electrodeposited IrO 2 layer comprises amorphous iridium oxide having a density of 7 to 9 g/cm 3 ; and
wherein the electrodeposited IrO 2 layer has a thickness of 10 to 210 nm.

2. The composite layer of the polymer electrolyte membrane water electrolysis apparatus according to claim 1 , wherein the IrO 2 layer comprises iridium oxide loaded at 0.01 to 1.05 mg/cm 2 onto the porous Ti layer.

3. The composite layer of the polymer electrolyte membrane water electrolysis apparatus according to claim 1 , wherein the IrO 2 layer comprises iridium oxide loaded at 0.1 to 0.5 mg/cm 2 onto the porous Ti layer.

4. The composite layer of the polymer electrolyte membrane water electrolysis apparatus according to claim 1 , wherein the IrO 2 layer is uniformly deposited on the porous Ti layer, and thus physically blocks the porous Ti layer from the external oxidative environment.

5. A polymer electrolyte membrane water electrolysis apparatus comprising the composite layer of the polymer electrolyte membrane water electrolysis apparatus according to claim 1 .

6. The polymer electrolyte membrane water electrolysis apparatus according to claim 5 , wherein the polymer electrolyte membrane water electrolysis apparatus exhibits a current density of 0.07 to 0.96 A/cm 2 at 1.6 V and 120° C.

7. The polymer electrolyte membrane water electrolysis apparatus according to claim 5 , wherein the polymer electrolyte membrane water electrolysis apparatus exhibits a current density of 0.16 to 0.96 A/cm 2 .

8. The polymer electrolyte membrane water electrolysis apparatus according to claim 5 , wherein the polymer electrolyte membrane water electrolysis apparatus is a high-temperature polymer electrolyte membrane water electrolysis apparatus which is operated at 200° C. or less.

9. The polymer electrolyte membrane water electrolysis apparatus according to claim 8 , wherein the polymer electrolyte membrane water electrolysis apparatus is a high-temperature polymer electrolyte membrane water electrolysis apparatus which is operated at 60° C. or more.

10. A method for preparing an IrO 2 electrodeposited porous titanium composite layer of a polymer electrolyte membrane water electrolysis apparatus serving as both a diffusion layer and an oxygen electrode according to claim 1 , the method comprising:
electrodepositing an iridium oxide (IrO 2 ) layer on a porous titanium (Ti) layer.

11. The method according to claim 10 , wherein the porous Ti layer comprises one or more selected from a group consisting of Ti layers in a form of titanium paper and mesh.

12. The method according to claim 10 , wherein the electrodeposition is performed at a deposition potential of 0.5 to 0.9 V SCE .

13. The method according to claim 10 , wherein the electrodeposition is performed for 1 min or more and less than 10 min.

14. The method according to claim 10 , wherein the electrodeposition is performed for 3 min or more and 8 min or less.

Assignees

• Korea Inst Sci & Tech

Inventors

• Jang Jong Hyun
• Choe Seunghoe
• Na Youngseung
• Lee Hye Jin
• Lim Ahyoun
• Kim Hyoung-Juhn
• Henkensmeier Dirk
• Yoo Sung Jong
• Kim Jin Young
• Lee So Young
• Park Hyun Seo

Classifications

• C25D9/06 Primary

  by anodic processes · CPC title

• C25B11/052

  Electrodes comprising one or more electrocatalytic coatings on a substrate · CPC title

• C25B11/063

  Valve metal, e.g. titanium · CPC title

• C25B1/04 Primary

  by electrolysis of water · CPC title

• C25B9/23

  comprising ion-exchange membranes in or on which electrode material is embedded · CPC title