Viscoelastic amphoteric surfactant based composition for increasing oil well production

Patent metadata

Field	Value
Publication number	US-10975331-B2
Application number	US-201916272875-A
Country	US
Kind code	B2
Filing date	Feb 11, 2019
Priority date	Nov 28, 2012
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

Alkaline or neutral viscoelastic cleaning compositions are disclosed which use non polymer thickening agents. According to the invention, cleaning compositions have been developed using viscoelastic surfactants in a neutral, acidic or alkaline cleaning formulations. These provide the dual benefit of thickening as well as an additional cleaning, thereby improving performance. Applicants have also identified several pseudo linking agents which when, used with viscoelastic surfactants provide viscoelasticity in alkaline cleaning compositions.

First claim

What is claimed is:

1. A method of increasing oil production from a well, comprising:
injecting into a well a hydraulic fracking fluid comprising of an oil/aqueous solution a neutral or alkaline viscoelastic composition, comprising:
(a) a source of alkalinity,
(b) a non polymer viscoelastic surfactant selected from the formulas of the group of:

wherein R 1 represents a hydrophobic moiety of alkyl, alkylarylalkyl, alkoxyalkyl, alkylaminoalkyl and alkylamidoalkyl, wherein alkyl represents a group that contains from about 16 to about 22 carbon atoms which may be branched or straight chained and which may be saturated or unsaturated;
wherein R 2 and R 3 are independently an aliphatic chain having from 1 to about 30 atoms in which the aliphatic group can be branched or straight chained, saturated or unsaturated; and
wherein R 4 is a hydrocarbyl radical (e.g. alkylene) with chain length 1 to 4, and/or mixtures thereof
(c) a pseudo linker, wherein the pseudo linker is magnesium sulfate, magnesium acetate, aluminum sulfate, ethylenediaminetetraacetic acid (EDTA), diethylenetriaminepentaacetic acid (DTPA), sodium tripolyphosphate (STPP), neutralized aminotris(methylenephosphonic acid) (ATMP), neutralized 1-hydroxyethane 1,1-diphosphonic acid (HEDP), and/or neutralized 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTC).

2. The nonpolymer viscoelastic surfactant of claim 1 wherein said surfactant has the following formula:

wherein R 1 has been previously defined herein, and
wherein X + is an inorganic cation such as Na + , K + , NH 4 + associated with a carboxylate group or hydrogen atom in an acidic medium.

3. The method of claim 1 wherein said pseudo linker is present in a ratio greater than 1:1 of active percent by weight of linker to active percent by weight of surfactant of said viscoelastic composition.

4. The method of claim 1 wherein said neutral or alkaline viscoelastic composition increases the permeability of said well.

Assignees

• Ecolab Usa Inc

Inventors

• Man Victor Fuk-Pong
• Denoma Michael Charles
• Killeen Yvonne Marie
• Viall Susan Maloney

Classifications

• C11D1/75

  Amino oxides · CPC title

• C11D3/361

  Phosphonates, phosphinates or phosphonites · CPC title

• C11D1/90 Primary

  Betaines · CPC title

• C11D1/94

  Mixtures with anionic, cationic or non-ionic compounds · CPC title

• C11D3/365

  containing carboxyl groups · CPC title