Cement slurries with salt-tolerant fluid loss additives and methods relating thereto

Patent metadata

Field	Value
Publication number	US-10975286-B2
Application number	US-201415313364-A
Country	US
Kind code	B2
Filing date	Aug 28, 2014
Priority date	Aug 28, 2014
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

A cement slurry suitable for use in the presence of high salt concentrations may include a base fluid and dry components that include: a cementitious material, a pozzolanic material, a salt additive, and a salt-tolerant fluid loss additive. The salt-tolerant fluid loss additive may be at least one of the following zwitterionic polymers: (1) a copolymer of at least one anionic monomer and at least one cationic monomer, (2) a copolymer of at least one anionic monomer, at least one cationic monomer, and at least one zwitterionic monomer, (3) a homopolymer of a zwitterionic monomer, or (4) a copolymer of at least one zwitterionic monomer.

First claim

What is claimed is:

1. A method comprising:
introducing a cement slurry into a wellbore penetrating a salt formation, the cement slurry comprising: a base fluid and dry components that comprise a cementitious material, a pozzolanic material, a salt additive, and a salt-tolerant fluid loss additive, wherein the salt-tolerant fluid loss additive is a zwitterionic polymer comprising:
a copolymer of [3-(methacryloylamino)propyl]dimethyl(3-sulfopropyl)ammonium hydroxide inner salt and sodium 1-allyloxy-2-hydroxypropanesulphonate.

2. The method of claim 1 , wherein the at least one zwitterionic polymer is charge balanced.

3. The method of claim 1 , wherein the salt-tolerant fluid loss additive is present in an amount of about 0.001% to about 2% by weight of the dry components.

4. The method of claim 1 , wherein the salt formation comprises sodium salts, potassium salts, magnesium salts, calcium salts, or any combination thereof.

5. The method of claim 1 , wherein the cementitious material is a hydraulic cement.

6. The method of claim 1 , wherein the cementitious material is present in an amount of about 5% to about 60% by weight of the dry components.

7. The method of claim 1 , wherein the pozzolanic material is selected from the group consisting of silica fume, metakaolin, fly ash, diatomaceous earth, calcined diatomite, uncalcined diatomite, calcined fullers earth, pozzolanic clay, calcined volcanic ash, uncalcined volcanic ash, bagasse ash, pumice, pumicite, rice hull ash, natural zeolite, synthetic zeolite, slag, vitreous calcium aluminosilicate, and any combination thereof.

8. The method of claim 1 , wherein the pozzolanic material is present in an amount of about 0.001% to about 60% by weight of the dry components.

9. The method of claim 1 , wherein the salt additive is present in an amount of about 15% to about 40% by weight of the base fluid.

10. The method of claim 1 , wherein the cement slurry has a yield point in the range of about 5 to about 200 lb/100 ft2 and a plastic viscosity in the range of about 120 to about 500 cP.

11. The method of claim 1 wherein the zwitterionic polymer further comprises at least one zwitterionic polymer selected from the group consisting of: (1) a copolymer of at least one anionic monomer and at least one cationic monomer, (2) a copolymer of at least one anionic monomer, at least one cationic monomer, and at least one zwitterionic monomer, (3) a homopolymer of a zwitterionic monomer, or (4) a copolymer of at least one zwitterionic monomer,
wherein the at least one cationic monomer is selected from the group consisting of: [2-(methacryloyloxy)ethyl]trimethylammonium chloride, [3-(methacryloylamino)propyl]trimethylammonium chloride, [2-(acryloyloxy)ethyl]trimethylammonium chloride, [3-(acryloylamino)propyl]trimethylammonium chloride, [2-(methacryloyloxy)ethyl]dimethylamine hydrochloride, [3-(methacryloylamino)propyl]dimethylamine hydrochloride, [2-(acryloyloxy) ethyl]dimethylamine hydrochloride, [3-(acryloylamino)propyl]dimethylamine hydrochloride, a bromide salt thereof, a sulfate salt thereof, a methyl sulfate salt thereof, an ethyl sulfate salt thereof, and a nitrate salt thereof,
wherein the at least one anionic monomer is selected from the group consisting of: sodium 2-acrylamido-2-methylpropanesulfonate, 4-vinylbenzenesulfonic acid, sodium 4-vinylbenzenesulfonate, vinylsulfonic acid, sodium vinylsulfonate, allylsulfonic acid, sodium allylsulfonate, 3-sulfopropyl acrylate potassium salt, 3-sulfopropyl methacrylate potassium salt, N-sulfomethylacrylamide sodium salt, sodium 1-allyloxy-2-hydroxypropanesulphonate, a potassium salt thereof, a magnesium salt thereof, a calcium salt thereof, and an ammonium salt thereof, and
wherein the zwitterionic monomer is selected from the group consisting of: [3-(methacryloylamino)propyl]dimethyl(3-sulfopropyl)ammonium hydroxide inner salt, [2-(methacryloyloxy)ethyl]dimethyl(3-sulfopropyl)ammonium hydroxide inner salt, and 2-(methacryloyloxy)ethyl 2-(trimethylammonio)ethyl phosphate.

12. The method of claim 1 wherein the salt additive is sodium chloride, potassium chloride, or a combination thereof and wherein the salt additive is present in an amount of about 30% to about 40% by weight of the base fluid.

13. The method of claim 1 , wherein the salt-tolerant fluid loss additive is present in an amount of about 2.6% to about 3% by weight of the dry components.

Assignees

• Halliburton Energy Services Inc

Inventors

• Funkhouser Gary P
• Lewis Samuel J

Classifications

• C04B28/02

  containing hydraulic cements other than calcium sulfates · CPC title

• C09K8/487 Primary

  Fluid loss control additives; Additives for reducing or preventing circulation loss · CPC title

• E21B33/13

  Methods or devices for cementing, for plugging holes, crevices or the like · CPC title

• Y02W30/91

  Use of waste materials as fillers for mortars or concrete · CPC title

• C09K8/42 Primary

  Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells (compositions for plastering C09K8/50) · CPC title