Resin composition and use thereof

Patent metadata

Field	Value
Publication number	US-10975223-B2
Application number	US-201615558987-A
Country	US
Kind code	B2
Filing date	Mar 24, 2016
Priority date	Mar 31, 2015
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

[Effect] The resin composition of the present invention is excellent in crosslinking properties and the resin composition and its crosslinked shaped article of the present invention can be used, without any limitation, in various applications known as applications of rubber composition, and can be suitably used, for example, for interior and exterior parts for automobiles and applications requiring heat resistance.

First claim

The invention claimed is:

1. A resin composition comprising
(A) 100 parts by mass of an ethylene/α-olefin/non-conjugated polyene copolymer and
(B) 0.1 to 5 parts by mass of an organic peroxide,
wherein the ethylene/α-olefin/non-conjugated polyene copolymer (A) comprises structural units derived from ethylene (a1), an α-olefin (a2) having 3 to 20 carbon atoms, and a non-conjugated polyene (a3) comprising intramolecularly two or more partial structures in total selected from the group consisting of structures represented by the following general formulae (I) and (II),

and satisfies the following requirements from (i) to (v):
(i) a molar ratio of ethylene/α-olefin is from 55/45 to 99.9/0.1;
(ii) a weight fraction of the structural unit derived from the non-conjugated polyene (a3) is from 0.07% by weight to 10% by weight in 100% by weight of the ethylene/α-olefin/non-conjugated polyene copolymer;
(iii) a weight-average molecular weight (Mw) of the ethylene/α-olefin/non-conjugated polyene copolymer, a weight fraction of the structural unit derived from the non-conjugated polyene (a3) (weight fraction of (a3)), and a molecular weight of the non-conjugated polyene (a3) (molecular weight of (a3)) satisfy the following Formula (1),
4.5≤Mw×weight fraction of ( a 3)/100/molecular weight of ( a 3)≤40;  Formula (1)

(iv) a ratio of a complex viscosity η* (ω=0.1) (Pa·sec) at a frequency of ω=0.1 rad/s to a complex viscosity η% (ω=100) (Pa·sec) at a frequency of ω=100 rad/s, both obtained by linear viscoelastic measurement (190° C.) by using a rheometer, represented by P( η*(ω=0.1 )/η* (ω=100) ), an intrinsic viscosity represented by [η], and the weight fraction of the structural unit derived from the non-conjugated polyene (a3) (weight fraction of (a3)) satisfy the following Formula (2),
P /([η] 2.9 )≤weight fraction of ( a 3)×6;  Formula (2)

and
(v) a number of long-chain branches per 1000 carbon atoms (LCB 1000C ) and a natural logarithmic number of the weight-average molecular weight (Mw) represented by [Ln(Mw)], obtained by using 3D-GPC, satisfy the following Formula (3),
LCB 1000C ≤1−0.07×Ln(Mw).

2. The resin composition according to claim 1 , wherein the ethylene/α-olefin/non-conjugated polyene copolymer (A) has an intrinsic viscosity [η] of 1.0 to 4.0 dl/g which is measured in decalin at 135° C.

3. The resin composition according to claim 1 , wherein the non-conjugated polyene (a3) comprises 5-vinyl-2-norbornene (VNB).

4. The resin composition according to claim 1 , comprising
(C) 10 to 300 parts by mass of carbon black, and
(D) 0.5 to 5 parts by mass of antioxidant,
with respect to 100 parts by mass of the ethylene/α-olefin/non-conjugated polyene copolymer (A).

5. The resin composition according to claim 1 , comprising
(E) a softening agent in an amount of less than 20 parts by mass,
with respect to 100 parts by mass of the ethylene/α-olefin/non-conjugated polyene copolymer (A).

6. The resin composition according to claim 1 , comprising
(F) a crosslinking aid in an amount of 0 to 4 parts by mass,
with respect to 100 parts by mass of the ethylene/α-olefin/non-conjugated polyene copolymer (A).

7. A crosslinked shaped article obtained by crosslinking the resin composition according to claim 1 .

8. A process for producing a crosslinked shaped article comprising a step of crosslinking the resin composition according to claim 1 .

9. A hose comprising a layer formed by crosslinking the resin composition according to claim 1 .

10. An automobile, a motorbike, industrial machinery, construction machinery, or agricultural machinery comprising the hose according to claim 9 .

11. A turbocharger hose for an automobile comprising the hose according to claim 9 .

12. A process for producing a hose, comprising a step of shaping and crosslinking the resin composition according to claim 1 to form a layer of a crosslinked shaped article.

13. The resin composition according to claim 1 , comprising
(G) 10 to 250 parts by mass of a white filler, except for silica,
with respect to 100 parts by mass of the ethylene/α-olefin/non-conjugated polyene copolymer (A).

14. The resin composition according to claim 13 , comprising
(E) 0 to 40 parts by mass of a softening agent,
with respect to 100 parts by mass of the ethylene/α-olefin/non-conjugated polyene copolymer (A).

15. The resin composition according to claim 13 , comprising
(D) 0 to 5 parts by mass of an antioxidant, and
(F) 0 to 4 parts by mass of a crosslinking aid,
with respect to 100 parts by mass of the ethylene/α-olefin/non-conjugated polyene copolymer (A).

16. A crosslinked shaped article obtained by crosslinking the resin composition according to claim 13 .

17. A process for producing a crosslinked shaped article, comprising a step of crosslinking the resin composition according to claim 13 .

18. A sealing material comprising the crosslinked shaped article according to claim 16 .

19. An automobile, a motorbike, industrial machinery, construction machinery, or agricultural machinery comprising the sealing material according to claim 18 .

20. A lamp seal packing or a packing for a meter comprising the sealing material according to claim 18 .

21. The resin composition according to claim 1 , comprising:
(C) 10 to 300 parts by mass of carbon black;
(E) 5 to 50 parts by mass of a softening agent; and
(F) 0.1 to 4 parts by mass of a crosslinking aid,
with respect to 100 parts by mass of the ethylene/α-olefin/non-conjugated polyene copolymer (A).

22. The resin composition according to claim 21 , comprising:
(D) 0 to 5 parts by mass of an antioxidant,
with respect to 100 parts by mass of the ethylene/α-olefin/non-conjugated polyene copolymer (A).

23. A crosslinked shaped article obtained by crosslinking the resin composition according to claim 21 .

24. A process for producing a crosslinked shaped article, comprising a step of crosslinking the resin composition according to claim 21 .

25. A sliding member comprising the crosslinked shaped article according to claim 23 .

26. An automobile, a motorbike, industrial machinery, construction machinery, or agricultural machinery comprising the sliding member according to claim 25 .

27. A wiper blade comprising the crosslinked shaped article according to claim 23 .

28. The resin composition according to claim 1 , which comprises
(H) 0.1 to 10 parts by mass of magnesium oxide, with respect to 100 parts by mass of the ethylene/α-olefin/non-conjugated polyene copolymer (A),
wherein the resin composition is substantially free from zinc oxide (I).

29. The resin composition according to claim 28 , comprising an antioxidant (D) in an amount of 5 parts by mass or less, with respect to 100 parts by mass of the ethylene/α-olefin/nonconjugated polyene copolymer (A).

30. The resin composition according to claim 28 , comprising a softening agent (E) in an amount of 80 parts by mass or less with respect to 100 parts by mass of the ethylene/α-olefin/non-conjugated polyene copolymer (A).

31. The resin composition according to claim 28 , comprising a crosslinking aid (F) in an amount of 4 parts by mass or less with respect to

Assignees

• Mitsui Chemicals Inc

Inventors

• Ichino Kotaro
• Kikuchi Yoshiharu
• Arino Mitsunao
• Hosoya Mikio
• Shishido Keisuke

Classifications

• C08K5/14 Primary

  Peroxides · CPC title

• C08F236/20

  unconjugated · CPC title

• C08F210/18

  with non-conjugated dienes, e.g. EPT rubbers · CPC title

• C08F210/06

  Propene · CPC title

• C09K3/1006

  characterised by the chemical nature of one of its constituents · CPC title