Catalysts for control of long chain branching
US-10538604-B2 · Jan 21, 2020 · US
US10975174B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10975174-B2 |
| Application number | US-201916526673-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 30, 2019 |
| Priority date | Apr 17, 2015 |
| Publication date | Apr 13, 2021 |
| Grant date | Apr 13, 2021 |
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Catalyst systems and methods for making and using the same are disclosed. A catalyst composition is provided that includes a catalyst compound supported to form a supported catalyst system, the catalyst compound including: where each of R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 and X are as discussed herein.
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What is claimed is: 1. A catalyst composition comprising a catalyst compound supported to form a supported catalyst system, wherein the catalyst compound comprises: wherein Each X is independently a leaving group selected from a halogen, a labile hydrocarbyl, a substituted hydrocarbyl, or a heteroatom group. 2. The catalyst composition of claim 1 , comprising an activator comprising an acid derived from a coordinating anion. 3. The catalyst composition of claim 1 , comprising an activator of an aluminoxane compound, an organoboron compound, an organoaluminum compound or combinations thereof. 4. The catalyst composition of claim 3 , wherein the activator comprises methyl aluminoxane or modified methylauminoxane. 5. The catalyst composition of claim 1 , comprising a support comprising a mineral, a clay, a metal oxide, a metalloid oxide, a mixed metal oxide, a mixed metalloid oxide, a mixed metal-metalloid oxide, a polymer, or any combinations thereof. 6. The catalyst composition of claim 5 , wherein the support is a polyolefin. 7. The catalyst composition of claim 5 , wherein the support has been thermally treated and/or chemically treated with an acid, an organoaluminum compound, or a fluoriding agent, or any combinations thereof. 8. The catalyst composition of claim 5 , wherein the support has been thermally treated. 9. The catalyst composition of claim 5 , wherein the support comprises silica, alumina, aluminosilicate, titanated silica, or titanated alumina, or any combinations thereof. 10. The catalyst composition of claim 1 , comprising a silica support and a methyl aluminoxane activator.
Manufacture of films or sheets · CPC title
Monomers containing five or more carbon atoms · CPC title
Cyclic compounds, e.g. cyclopentadienyls · CPC title
Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title
Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title
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