Process for quenching a gaseous reaction mixture obtained in the gas phase phosgenation of diamines

Patent metadata

Field	Value
Publication number	US-10975020-B2
Application number	US-201816641697-A
Country	US
Kind code	B2
Filing date	Sep 7, 2018
Priority date	Sep 11, 2017
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

A process for quenching, in a quenching zone, a gaseous reaction mixture that includes a diisocyanate, phosgene and hydrogen chloride that is obtained in a reaction zone upstream of the quenching zone by phosgenation of a diamine in the gas phase. The process includes injecting a deposit preventing liquid in a deposit preventing zone located between the reaction zone and the quenching zone by passing the deposit preventing liquid through spray nozzles for the deposit preventing liquid at the entrance to the deposit preventing zone. Each spray nozzle for the deposit preventing liquid sprays the deposit preventing liquid (i) onto a wall segment of the deposit preventing zone that is adjacent to said spray nozzle for the deposit preventing liquid to produce a film of the deposit preventing liquid flowing along the wall, and/or (ii) to areas in a cross-sectional plane of the deposit preventing zone before the entrance to the quenching zone.

First claim

The invention claimed is:

1. A process for quenching, in a quenching zone, a gaseous reaction mixture comprising a diisocyanate, phosgene and hydrogen chloride that is obtained in a reaction zone upstream of the quenching zone by phosgenation of a diamine in the gas phase, the process comprising:
(a) injecting a quenching liquid in the quenching zone by passing the quenching liquid through spray nozzles for the quenching liquid arranged at the entrance to the quenching zone, thereby partially condensing the gaseous reaction mixture; and
(b) injecting a deposit preventing liquid in a deposit preventing zone located between the reaction zone and the quenching zone by passing the deposit preventing liquid through spray nozzles for the deposit preventing liquid arranged at the entrance to the deposit preventing zone above the spray nozzles for the quenching liquid, wherein each spray nozzle for the deposit preventing liquid sprays the deposit preventing liquid ( 1 ) onto a wall segment of the deposit preventing zone that is adjacent to said spray nozzle for the deposit preventing liquid to produce a film of the deposit preventing liquid flowing along the wall, and/or (ii) to areas in a cross-sectional plane of the deposit preventing zone before the entrance to the quenching zone.

2. The process according to claim 1 , wherein the deposit preventing zone has a height in the range of 1.5 centimeters to 5 meters.

3. The process according to claim 1 , wherein the spray nozzles through which the deposit preventing liquid is passed are arranged at equal distances along the circumference of the entrance of the deposit preventing zone.

4. The process according to claim 1 , wherein the spray nozzles through which the quenching liquid is passed are arranged at equal distances along the circumference of the entrance of the quenching zone.

5. The process according to claim 1 , wherein the process comprises injecting a deposit preventing liquid in a deposit preventing zone located between the reaction zone and the quenching zone by passing the deposit preventing liquid through spray nozzles for the deposit preventing liquid at the entrance to the deposit preventing zone, wherein each spray nozzle for the deposit preventing liquid sprays the deposit preventing liquid (i) onto a wall segment of the deposit preventing zone that is adjacent to said spray nozzle for the deposit preventing liquid to produce a film of the deposit preventing liquid flowing along the wall, and (ii) to areas in a cross-sectional plane of the deposit preventing zone before the entrance to the quenching zone.

6. The process according to claim 1 , wherein the process comprises injecting a deposit preventing liquid in a deposit preventing zone located between the reaction zone and the quenching zone by passing the deposit preventing liquid through spray nozzles for the deposit preventing liquid at the entrance to the deposit preventing zone, wherein each spray nozzle for the deposit preventing liquid sprays the deposit preventing liquid (i) onto a wall segment of the deposit preventing zone that is adjacent to said spray nozzle for the deposit preventing liquid to produce a film of the deposit preventing liquid flowing along the wall, but not (ii) to areas in a cross-sectional plane of the deposit preventing zone before the entrance to the quenching zone.

7. The process according to claim 1 , wherein the process comprises injecting a deposit preventing liquid in a deposit preventing zone located between the reaction zone and the quenching zone by passing the deposit preventing liquid through spray nozzles for the deposit preventing liquid at the entrance to the deposit preventing zone, wherein each spray nozzle for the deposit preventing liquid sprays the deposit preventing liquid (ii) to areas in a cross-sectional plane of the deposit preventing zone before the entrance to the quenching zone, but not (i) onto a wall segment of the deposit preventing zone that is adjacent to said spray nozzle for the deposit preventing liquid to produce a film of the deposit preventing liquid flowing along the wall.

8. The process according to claim 1 , wherein the deposit preventing liquid is a solvent or a mixture of different solvents comprising toluene, chlorobenzene, chlorotoluene, dichlorobenzene, xylene or chloronaphthalene.

9. The process according to claim 1 , wherein the deposit preventing liquid is a solution of the product diisocyanate dissolved in a solvent or a mixture of different solvents comprising toluene, chlorobenzene, chlorotoluene, dichlorobenzene, xylene or chloronaphthalene, wherein the solvent or mixture of solvents represents 40% to 99% by mass, based on the total mass of the solution.

10. The process according to claim 1 , wherein the temperature of the deposit preventing liquid is −20° C. to 200° C.

11. The process according to claim 1 , wherein the quenching liquid is a solvent or a mixture of different solvents comprising toluene, chlorobenzene, chlorotoluene, dichlorobenzene, xylene or chloronaphthalene.

12. The process according to claim 1 , wherein the quenching liquid is a solution of the product diisocyanate dissolved in a solvent or a mixture of different solvents comprising toluene, chlorobenzene, chlorotoluene, dichlorobenzene, xylene or chloronaphthalene, wherein the solvent or mixture of different solvents represents 10% to 99% by mass, based on the total mass of the solution.

13. The process according to claim 1 , wherein the temperature of the quenching liquid is −20° C. to 200° C.

14. The process according to claim 1 , wherein the process for quenching the gaseous reaction mixture is part of a process for preparing a diisocyanate by phosgenation of a diamine comprising:
providing a gaseous stream comprising the diamine and a gaseous stream comprising phosgene, and
mixing the gaseous stream comprising the diamine and the gaseous stream comprising phosgene, and guiding the mixed gaseous streams through the reaction zone, thereby forming the gaseous reaction mixture comprising a diisocyanate, phosgene and hydrogen chloride.

15. The process according to claim 14 , wherein the diisocyanate is isolated from the condensed reaction mixture leaving the quenching zone by distillation.

Assignees

• Covestro Deutschland Ag

Inventors

• Gai Yuguo
• Ming Zhangyong
• Wei Qiang
• Zechlin Joachim
• Bludowsky Thomas
• Taube Wolfgang
• Michele Volker

Classifications

• C07C263/10 Primary

  by reaction of amines with carbonyl halides, e.g. with phosgene · CPC title

• C07C265/14

  containing at least two isocyanate groups bound to the same carbon skeleton · CPC title

• C07C263/20

  Separation; Purification · CPC title