Process and plant for producing ethylene and acetic acid

Patent metadata

Field	Value
Publication number	US-10975015-B2
Application number	US-201716472473-A
Country	US
Kind code	B2
Filing date	Dec 22, 2017
Priority date	Dec 22, 2016
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

A process for producing ethylene and acetic acid is proposed in which an ethane- and oxygen-containing reaction input stream is formed and a portion of the ethane and of the oxygen in the reaction input stream is converted into the ethylene and the acetic acid by oxidative dehydrogenation to obtain a process gas, wherein the process gas contains the unconverted portion of the ethane and of the oxygen, the ethylene and the acetic acid and also water. It is provided that the process comprises adjusting in the process gas a water partial pressure according to a specified product ratio of the acetic acid to the ethylene to a value in a range between 0.7 and 5 bar (abs.). A corresponding plant ( 100 ) likewise forms part of the subject matter of the present invention.

First claim

The invention claimed is:

1. Process for producing ethylene and acetic acid in which an ethane- and oxygen-containing reaction input stream is formed and a portion of the ethane and of the oxygen in the reaction input stream is converted into the ethylene and the acetic acid by oxidative dehydrogenation using a catalyst containing at least the elements molybdenum, vanadium, niobium and optionally tellurium to obtain a process gas, wherein the process gas contains the unconverted portion of the ethane and of the oxygen, the ethylene and the acetic acid and also water, wherein the process comprises adjusting a water partial pressure of the process gas according to a specified product ratio of the acetic acid to the ethylene to a value in a range between 0.5 and 5 bar (abs.), wherein one or more reactors are used for the oxidative dehydrogenation and the water partial pressure of the process gas is measured at a reactor outlet of the reactor(s) and wherein at least one of an addition of water to the reaction input stream and an adjustment of a reactor temperature is performed on the basis of said measuring the water partial pressure of the process gas at said reactor outlet of the reactor(s).

2. Process according to claim 1 in which the water partial pressure in the process gas is adjusted in a range between 0.7 and 3 bar (abs.).

3. Process according to claim 1 in which the ethane conversion in the oxidative dehydrogenation is greater than 15%.

4. Process according to claim 1 in which the reactor(s) comprise at least one catalyst bed, wherein the oxidative dehydrogenation is performed at a temperature range from 240° C. to 500° C. in the reactor bed(s) of the reactor(s).

5. Process according to claim 1 in which the reactor(s) comprise at least one catalyst bed, wherein a space velocity in the catalyst bed(s) of the reactor(s) is in a range between 0.1 and 10 kg of ethane/(h×kg of catalyst).

6. Process according to claim 1 in which a total pressure at a reactor inlet of the reactor(s) is between 1 and 10 bar (abs.).

7. Process according to claim 1 in which one or more diluents that pass into the process gas are further added to the reaction input stream.

8. Process according to claim 7 in which the diluent(s) is or are selected from the group consisting of water, methane, nitrogen, carbon dioxide, at least one inert gas, and mixtures thereof.

9. Process according to claim 1 in which ethylene is further added to the reaction input stream.

10. Process according to claim 1 in which an input mixture containing ethylene and ethane is added to the reaction input stream.

Assignees

• Linde Ag

Inventors

• Zellhuber Mathieu
• Winkler Florian
• Schubert Martin
• Meiswinkel Andreas

Classifications

• C07C53/08

  Acetic acid (pyroligneous acid C10C; preparation of vinegar C12J) · CPC title

• C07C5/48 Primary

  with oxygen as an acceptor · CPC title

• C07C51/215 Primary

  of saturated hydrocarbyl groups · CPC title

• C07C11/04

  Ethene · CPC title