N-heptane production method

Patent metadata

Field	Value
Publication number	US-10975003-B2
Application number	US-202016850158-A
Country	US
Kind code	B2
Filing date	Apr 16, 2020
Priority date	May 13, 2019
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

Provided is an n-heptane production method including: a step of distilling a feed containing C6−, C7, and C8+ hydrocarbon components, removing the C8+ and C6− hydrocarbon components, and separating the C7 hydrocarbon component; a step of adding the separated C7 hydrocarbon component to a hydrogenation apparatus and hydrogenating the separated C7 hydrocarbon component; a step of adding the hydrogenated C7 hydrocarbon component to a simulated moving bed (SMB) apparatus and separating the hydrogenated C7 hydrocarbon component into an extract containing n-heptane and a raffinate containing other components; and a step of distilling the extract and separating the n-heptane in an extract column, wherein a purity of the produced n-heptane is 98 wt % or higher.

First claim

What is claimed is:

1. An n-heptane production method comprising:
a step of distilling a feed containing C6−, C7, and C8+ hydrocarbon components, removing the C8+ and C6− hydrocarbon components, and separating the C7 hydrocarbon component;
a step of adding the separated C7 hydrocarbon component to a hydrogenation apparatus and hydrogenating the separated C7 hydrocarbon component;
a step of adding the hydrogenated C7 hydrocarbon component to a simulated moving bed (SMB) apparatus and separating the hydrogenated C7 hydrocarbon component into an extract containing n-heptane and a raffinate containing other components;
a step of distilling the extract and separating the n-heptane in an extract column to obtain a produced n-heptane; and
a step of recirculating a portion of the n-heptane separated in the extract column between a rear end of the hydrogenation apparatus and a front end of the SMB apparatus,
wherein, in the recirculation step, a recirculation rate is 30% to 60% by weight of the n-heptane separated;
wherein a purity of the produced n-heptane is 99.8 wt % or higher.

2. The n-heptane production method of claim 1 , wherein the step of distilling the feed containing C6−, C7, and C8+ hydrocarbon components, removing the C8+ and C6− hydrocarbon components, and separating the C7 hydrocarbon component includes:
a step of performing distillation and removing the C8+ hydrocarbon component in a first distillation column; and
a step of performing distillation and removing the C6− hydrocarbon component in a second distillation column.

3. The n-heptane production method of claim 1 , wherein the step of distilling the feed containing C6−, C7, and C8+ hydrocarbon components, removing the C8+ and C6− hydrocarbon components, and separating the C7 hydrocarbon component includes:
a step of performing distillation and removing the C6− hydrocarbon component in a first distillation column; and
a step of performing distillation and removing the C8+ hydrocarbon component in a second distillation column.

4. The n-heptane production method of claim 1 , wherein the feed containing C6−, C7, and C8+ hydrocarbon components is desulfurized naphtha.

5. The n-heptane production method of claim 1 , wherein the feed containing C6−, C7, and C8+ hydrocarbon components contains, with respect to a total weight of 100 wt % thereof, 3 wt % to 10 wt % of C6− n-paraffin, 5 wt % to 15 wt % of C7 n-paraffin, 5 wt % to 20 wt % of C8+ n-paraffin, and a balance containing naphthene, isoparaffin, and an aromatic component.

Assignees

• Sk Innovation Co Ltd
• Sk Global Chemical Co Ltd

Inventors

• Jeon Kyung Jin
• Kang Soo Kil

Classifications

• C10G69/00

  Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process (C10G67/00 takes precedence) · CPC title

• C07C7/04

  by distillation · CPC title

• C10G7/00

  Distillation of hydrocarbon oils · CPC title

• C07C9/15

  Straight-chain hydrocarbons · CPC title

• C10G69/02

  plural serial stages only · CPC title