Method for the manufacture of a urea-based particulate material containing elemental sulphur

Patent metadata

Field	Value
Publication number	US-10974998-B2
Application number	US-201916673069-A
Country	US
Kind code	B2
Filing date	Nov 4, 2019
Priority date	Jul 7, 2015
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

This invention relates to a method for the manufacture of a homogeneous, solid, particulate, urea-based material comprising elemental sulphur. The invention further relates to a homogeneous, solid, particulate urea-based material comprising small elemental sulphur phases in a urea-based base material and formed by an accretion process. The product is in particular suitable as a fertilizer.

First claim

The invention claimed is:

1. A method for the manufacture of a homogeneous, solid, particulate, urea-based material comprising elemental sulphur, the method comprising the steps of:
(i) providing a melt of molten urea-based base material and molten elemental sulphur; and
(ii) spraying the melt in a urea fluidized bed granulator using spraying means, wherein the spraying means comprise at least one atomization nozzle, operated at less than 2 bar, such that the melt is solidified into homogeneous, solid, particulate urea-based material comprising solid elemental sulphur phases therein;
wherein the solid elemental sulphur phases have a size, determined by laser diffraction analysis and expressed as d90, of smaller than about 20 μm, or expressed as d50, of smaller than about 10 μm, or expressed as d10, of smaller than about 5 μm;
wherein the solidification of the particulate urea-based material is done in the fluidized bed granulator substantially by the action of accretion.

2. The method according to claim 1 , wherein step (i) comprises:
(a) providing a first liquid flow comprising a urea-based base material at a first temperature at least at or above the melting temperature of the urea-based base material;
(b) providing a second liquid flow comprising elemental sulphur at a second temperature at least at or above the melting temperature of the elemental sulphur; and
(c) continuously joining the first flow with the second flow to form a third flow at a third temperature at which both flows are liquid, such that elemental sulphur in the resulting melt of molten urea-based base material and molten elemental sulphur is in liquid form.

3. The method according to claim 1 , wherein the melt of molten urea-based base material and molten elemental sulphur is sprayed in the absence of an additive that improves the homogeneity of the melt of molten urea-based base material and molten elemental sulphur, and/or decreases the average particle size of the elemental sulphur phases therein.

4. The method according to claim 1 , wherein the melt of molten urea-based base material and molten elemental sulphur is inhomogeneous, wherein the DEVSQ of the S content is more than 1 (determined on at least 5 samples of about 2 gram).

5. The method according to claim 2 , wherein the first temperature is in the range of about 120° C. to 145° C., and/or wherein the second temperature is in the range of about 120° C. to 150° C., and/or wherein the third temperature is in the range of about 120° C. to 150° C.

6. The method according to claim 1 , wherein the step of spraying the resulting melt in a urea fluidized bed granulator using spraying means such that the melt is solidified into a homogeneous, solid, particulate urea-based material is performed at a temperature of 95° C. to 120° C.

7. The method according to claim 2 , wherein the ratio of second flow to first flow ranges between 0.1:100 and 25:100 by weight.

8. The method according to claim 2 , wherein the residence time of the third flow between the steps of joining (c) and spraying (ii) is in the order of about 10 to 100 seconds.

9. The method according to claim 1 , wherein about 90% of the elemental sulphur phases have a size, determined by wind sieve mill analysis, of smaller than 32 μm.

10. The method according to claim 1 , wherein the urea-based base material is selected from the group consisting of urea, urea-ammonium sulphate, and urea-ammonium phosphate fertilizer.

11. The method according to claim 1 , wherein the homogeneity, determined as the DEVSQ for the S content of said material is less than 1 (determined on at least 5 samples of about 2 gram).

12. The method according to claim 1 , wherein the spraying means comprise at least one atomization nozzle, operated at less than 1 bar.

13. A homogeneous, solid, particulate urea-based material, comprising finely divided elemental sulphur phases in a urea-based base material and formed by an accretion process wherein said elemental sulphur phases have a size, determined by laser diffraction analysis and expressed as d90, of smaller than about 20 μm or expressed as d50, of smaller than about 10 μm or expressed as d10, of smaller than about 5 μm; and wherein the homogeneous, solid, particulate urea-based material does not comprise a surfactant.

14. A homogeneous, solid, particulate urea-based material according to claim 13 , wherein about 90% of the elemental sulphur phases have a size, determined by wind sieve mill analysis, of smaller than 32 μm.

15. The homogeneous, solid, particulate urea-based material according to claim 13 , wherein the homogeneity, determined as the DEVSQ for the S content of said material is less than 1 (determined on at least 5 samples of about 2 gram).

16. A fertilizer, for supporting the growth of agricultural products on a sulphur-deficient soil, or an animal feed, comprising the homogeneous, solid, particulate urea-based material as claimed in claim 13 .

Assignees

• Yara Int Asa

Inventors

• Ledoux Francois
• Colpaert Filip

Classifications

• C05C9/005 Primary

  Post-treatment · CPC title

• B01J2/16

  by suspending the powder material in a gas, e.g. in fluidised beds or as a falling curtain · CPC title

• C05G5/12

  Granules or flakes · CPC title

• C05G3/30

  Anti-agglomerating additives; Anti-solidifying additives · CPC title

• C05C9/00 Primary

  Fertilisers containing urea or urea compounds · CPC title