Alkali-doped and alkali-free boroaluminosilicate glass
US-2015051060-A1 · Feb 19, 2015 · US
US10974987B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10974987-B2 |
| Application number | US-201916351007-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 12, 2019 |
| Priority date | Sep 13, 2016 |
| Publication date | Apr 13, 2021 |
| Grant date | Apr 13, 2021 |
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The present invention relates to a glass substrate for a high-frequency device, which includes SiO2 as a main component, the glass substrate having a total content of alkali metal oxides in the range of 0.001-5% in terms of mole percent on the basis of oxides, the alkali metal oxides having a molar ratio represented by Na2O/(Na2O+K2O) in the range of 0.01-0.99, and the glass substrate having a total content of Al2O3 and B2O3 in the range of 1-40% in terms of mole percent on the basis of oxides and having a molar ratio represented by Al2O3/(Al2O3+B2O3) in the range of 0-0.45, in which at least one main surface of the glass substrate has a surface roughness of 1.5 nm or less in terms of arithmetic average roughness Ra, and the glass substrate has a dielectric dissipation factor at 35 GHz of 0.007 or less.
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The invention claimed is: 1. A glass substrate, which comprises SiO 2 as a main component, the glass substrate having a total content of alkali metal oxides in the range of 0.001-5% in terms of mole percent on the basis of oxides, the alkali metal oxides having a molar ratio represented by Na 2 O/(Na 2 O+K 2 O) in the range of 0.01-0.99, and the glass substrate having a total content of Al 2 O 3 and B 2 O 3 in the range of 16-40% in terms of mole percent on the basis of oxides and having a molar ratio represented by Al 2 O 3 /(Al 2 O 3 +B 2 O 3 ) in the range of 0-0.45, wherein the glass substrate comprises, in terms of mole percent on the basis of oxides: SiO 2 40-75%; Al 2 O 0-15%; B 2 O 3 16-30%; MgO 0-13%; CaO 0-13%; SrO 3-13%; BaO 0-10%, wherein at least one main surface of the glass substrate has a surface roughness of 1.5 nm or less in terms of arithmetic average roughness Ra, and the glass substrate has a dielectric dissipation factor at 35 GHz of 0.007 or less. 2. The glass substrate according to claim 1 , which has a content of Al 2 O 3 in the range of 0-10%, in terms of mole percent on the basis of oxides. 3. The glass substrate according to claim 1 , which has a content of Fe, in terms of Fe 2 O 3 , of 0.012% or less in terms of mole percent on the basis of oxides. 4. The glass substrate according to claim 1 , which has a β-OH value in the range of 0.05-0.6 mm −1 . 5. The glass substrate according to claim 1 , which has a relative permittivity at 35 GHz of 10 or less. 6. The glass substrate according to claim 1 , which has an average thermal expansion coefficient over the range of from 50° C. to 350° C. in the range of 3-15 ppm/° C. 7. The glass substrate according to claim 1 , which has a Young's modulus of 40 GPa or higher. 8. The glass substrate according to claim 1 , which has a porosity of 0.1% or less. 9. The glass substrate according to claim 1 , which has a transmittance at 350-nm wavelength of 50% or higher. 10. The glass substrate according to claim 1 , which has a thickness in the range of 0.05-1 mm and a substrate area in the range of 225-10,000 cm 2 . 11. The glass substrate according to claim 1 , which is amorphous. 12. A circuit board for a high-frequency device, comprising: the glass substrate according to claim 1 ; and a wiring layer formed on the main surface of the glass substrate, wherein the circuit board has a transmission loss at 35 GHz of 1 dB/cm or less. 13. The glass substrate according to claim 1 , which has a content of B 2 O 3 in the range of 16-24%, in terms of mole percent on the basis of oxides. 14. The glass substrate according to claim 1 , which has a content of B 2 O 3 in the range of 16-23%, in terms of mole percent on the basis of oxides. 15. The glass substrate according to claim 1 , which has a content of CaO in the range of 0-5%, in terms of mole percent on the basis of oxides.
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