pH control method for UpA cell

Patent metadata

Field	Value
Publication number	US-10974976-B2
Application number	US-201515538721-A
Country	US
Kind code	B2
Filing date	Dec 22, 2015
Priority date	Dec 26, 2014
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

The present invention relates to a device and method for controlling the pH of a UpA cell. The device comprises a receiving unit for receiving a preset parameter including a desired pH value; a computing module configured to calculate an UpA cell parameter based on the preset parameter; and a control module configured to control the UpA cell based on the calculated UpA cell parameter.

First claim

The invention claimed is:

1. A device for controlling the pH of an unidirectional pH adjustment cell, the device comprising:
a receiving unit configured to receive a water related preset parameter characterizing water subject to an unidirectional pH adjustment by the unidirectional pH adjustment cell, wherein the water related preset parameter includes a desired pH value of the water;
a computing module configured to calculate an unidirectional pH adjustment cell parameter associated with the pH of the unidirectional pH adjustment cell based on an equational relationship between the unidirectional pH adjustment cell parameter and the water related preset parameter including the desired pH value of the water as received by the receiving unit; and
a control module configured to control the unidirectional pH adjustment of the water by the unidirectional pH adjustment cell based on the unidirectional pH adjustment cell parameter as calculated by the computing module.

2. Device according to claim 1 , wherein the preset parameter comprises at least a thickness of reaction layer, electrochemical reaction rate, diffusion index, a thickness of diffusion layer, a water volume, and a diffusion cross area.

3. Device according to claim 2 , wherein the computing module is further configured to calculate the unidirectional pH adjustment cell parameter based on equations (4) to (7):
d *( dC s /dt )= r−D *( C s −C b )/ L   (4),

r=I/F   (5),

V *( dC b /dt )= D*A *( C s −C b )/ L   (6),

wherein d is thickness of reaction layer, C s is concentration of OH − in the reaction layer, t is time, I is current, F is Faraday constant, D is diffusion index, C b is concentration of OH − in the bulk water, L is thickness of diffusion layer (L), V is water volume, A is diffusion cross area; and
C s0 =C b0 =10 pH0-14 *1000  (7),

wherein C s0 is initial concentration of OH − in the reaction layer, C b0 is initial concentration of OH − in water, and pH0 is the initial pH value of water.

4. The device according to claim 1 ,
wherein the unidirectional pH adjustment cell has a power source;
wherein the computing module is configured to calculate the unidirectional pH adjustment cell parameter including a power source parameter associated with the power source; and
wherein the control module is configured to control the unidirectional pH adjustment of the water by the unidirectional pH adjustment cell by controlling the power source based on the power source parameter.

5. The device according to claim 1 , further comprising:
a flowmeter for controlling flow of the water being feed to the unidirectional pH adjustment cell, wherein the control module is further configured to control the flowmeter based on the unidirectional pH adjustment cell parameter calculated by the computing module.

6. The device according to claim 1 , wherein the control module being configured to control the unidirectional pH adjustment of the water by the unidirectional pH adjustment cell includes an adjustment to a hydroxide ion concentration of the water within the unidirectional pH adjustment cell.

7. The device according to claim 1 ,
wherein the receiving unit is configured to receive a cell related preset parameter characterizing the unidirectional pH adjustment cell; and
wherein the computing module is configured to calculate the unidirectional pH adjustment cell parameter based on an equational relationship between the unidirectional PH adjustment cell parameter, the water related preset parameter including the desired pH value of the water as received by the receiving unit and the cell related preset parameter as received by the receiving unit.

8. The device according to claim 7 , wherein the control module being configured to control the unidirectional pH adjustment of the water by the unidirectional pH adjustment cell includes an adjustment to a hydroxide ion concentration of the water within the unidirectional pH adjustment cell.

9. The device according to claim 1 ,
wherein the computing module is configured to calculate the unidirectional pH adjustment cell parameter including an operating time parameter associated with the unidirectional pH adjustment cell; and
wherein the control module is configured to control the unidirectional pH adjustment of the water by the unidirectional pH adjustment cell by controlling the operating time of the unidirectional pH adjustment cell based on the operating time parameter.

10. A method for controlling the pH of an unidirectional pH adjustment cell, the method comprising:
providing a device including a receiving unit, a computing module and a control module;
receiving, by the receiving unit, a water related preset parameter characterizing water subject to an unidirectional pH adjustment by the unidirectional pH adjustment cell, wherein the water related preset parameter includes a desired pH value of the water;
calculating, by the computing module, an unidirectional pH adjustment cell parameter associated with the pH of the unidirectional pH adjustment cell based on an equational relationship between the unidirectional pH adjustment cell parameter and the water related preset parameter including the desired pH value of the water received by the receiving unit; and
controlling, by the control module, the unidirectional pH adjustment of the water by the unidirectional pH adjustment cell based on the unidirectional pH adjustment cell parameter calculated by the computing module.

11. Method according to claim 10 , wherein the preset parameter comprises at least a thickness of reaction layer, electrochemical reaction rate, diffusion index, a thickness of diffusion layer, a water volume, and a diffusion cross area.

12. Method according to claim 11 , wherein calculating the unidirectional pH adjustment cell parameter is based on equations (4) to (7):
d *( dC s /dt )= r−D *( C s −C b )/ L   (4),

r=I/F   (5),

V *( dC b /dt )= D*A *( C s −C b )/ L   (6),

wherein d is thickness of reaction layer, C s is concentration of OH − in the reaction layer, t is time, I is current, F is the Faraday constant, D is diffusion index, C b is concentration of OH − in the bulk water, L is thickness of diffusion layer (L), V is water volume, A is diffusion cross area; and
C s0 =C b0 =10 pH0-14 *1000  (7),

wherein C s0 is initial concentration of OH − in the reaction layer, C b0 is initial concentration of OH − in water, and pH0 is the initial pH value of water.

13. The method according to claim 10 , further comprising:
controlling, by the control module, a flow of the water into the unidirectional pH adjustment cell based on the unidirectional pH adjustment cell parameter calculated by the computing module.

14. The method according claim 10 , wherein the controlling, by the control module, the unidirectional pH adjustment of the water by the unidirectional pH adjustment cell includes adjusting the hydroxide ion concentration of the water within the unidirectional pH adjustment cell.

15. The method according claim 10 , further comprising:
receiving, by the receiving unit, a cell related preset parameter characterizing the unidirectional pH adjustment cell; and
calculating, by the computing module, the unidirectional pH adjustment cell parameter based on an equational relationship between the unidirectional PH adjustment cell parameter, the water related preset parameter including the desired pH value of the water received by the receiving unit and the cell related preset parameter received by the receiving unit.

Assignees

• Koninklijke Philips Nv

Inventors

• Li Qing
• Wang Guangwei

Classifications

• C02F1/4696

  electrophoresis · CPC title

• C02F2209/005

  Processes using a programmable logic controller [PLC] · CPC title

• C02F2209/006

  comprising a software program or a logic diagram · CPC title

• C02F2209/06

  pH · CPC title

• C02F2209/40

  Liquid flow rate · CPC title