Additive fabrication process with a structural material comprising an IR absorber

Patent metadata

Field	Value
Publication number	US-10974498-B2
Application number	US-201716474152-A
Country	US
Kind code	B2
Filing date	Dec 22, 2017
Priority date	Dec 28, 2016
Publication date	Apr 13, 2021
Grant date	Apr 13, 2021

Abstract

A process for manufacturing an article, comprising the step of manufacturing the article via an additive fabrication process from a structural material, is notable in that the structural material comprises a polymer selected from the following group: (co)polycarbonates, polyesters, polyestercarbonates, polyformals, polyamides, polyethers, polyvinyl chloride, polymethyl (meth)acrylate, polystyrene or a combination of at least two thereof and an additive absorbing infrared radiation. The additive absorbing infrared radiation is selected for its chemical structure and its concentration in the structural material such that it reduces transmission by the structural material of light in the wavelength range between 600 nm and 1700 nm, determined on a sample 100 μm thick, by ≥2.5 percentage points relative to a structural material sample with a thickness of 100 μm that does not contain the additive absorbing infrared radiation. During the additive fabrication process the structural material is exposed at least temporarily to infrared radiation in the wavelength range between 600 nm and 1700 nm. An article obtainable by a process as described above is notable for its production from a structural material which comprises a polymer selected from the following group: (co)polycarbonates, polyesters, polyestercarbonates, polyformals, polyamides, polyethers, polyvinyl chloride, polymethyl (meth)acrylate, polystyrene or a combination of at least two thereof and an additive absorbing infrared radiation, where the article, in the direction of its construction in the additive manufacturing process used to make it, has a tensile strength (ISO 527) which is >30% to . . . 100% of the tensile strength (ISO 527) of a specimen injection-moulded from the same structural material.

First claim

The invention claimed is:

1. A process for producing an article, comprising:
producing the article by means of an additive manufacturing method from a construction material, comprising applying a filament of an at least partly molten construction material to a carrier, such that a layer of the construction material is obtained, corresponding to a first selected cross section of the article;
optionally applying the filament of the at least partly molten construction material to a previously applied layer of the construction material, such that a further layer of the construction material is obtained, which corresponds to a further selected cross section of the article and which is bonded to the layer applied beforehand; and
optionally repeating the step of applying the filament of the at least partly molten construction material to a previously applied layer of the construction material until the article has been formed,
wherein the construction material comprises a polymer comprising (co)polycarbonates, polyesters, polyestercarbonates, polyformals, polyamides, polyethers, polyvinylchloride, polymethyl(meth)acrylate, polystyrene, or a combination of at least two of these
and an additive that absorbs infrared radiation, wherein the additive that absorbs infrared radiation is present at a surface of the construction material, and
wherein the additive that absorbs infrared radiation is selected to reduce transmittance of the construction material for light in a wavelength range between 600 nm and 1700 nm, determined on a 100 μm-thick sample, by >2.5 percentage points compared to a sample of the construction material having a thickness of 100 μm that does not contain the additive that absorbs infrared radiation,
and wherein, during the additive manufacturing method, the construction material is at least temporarily exposed to infrared radiation in the wavelength range between 600 nm and 1700 nm.

2. The process as claimed in claim 1 , wherein the additive that absorbs infrared radiation is distributed within the construction material.

3. The process as claimed in claim 1 , wherein the additive that absorbs infrared radiation comprises borides, tungstates, mixtures of at least one boride and at least one tungstate, carbon black, organic IR absorbers, or a combination of at least two of these.

4. The process as claimed in claim 1 , wherein the additive that absorbs infrared radiation is present in the construction material in an amount of 0.0005% by weight to 3% by weight, based on a total weight of the construction material.

5. The process as claimed in claim 1 , wherein, during the production of the article, an infrared radiation source irradiates the construction material with infrared radiation.

6. The process as claimed in claim 1 , wherein the construction material includes a polycarbonate having a weight-average molecular weight of ≥25 000 g/mol to ≤40 000 g/mol.

7. The process as claimed in claim 1 , wherein the process is conducted within a construction space and a temperature of the construction space is 10° C. lower than a glass transition temperature T g of the construction material (determined by DSC to DIN EN ISO 11357 at heating rate 10° C./min).

8. The process as claimed in claim 1 , wherein a surface temperature of a layer of the construction material applied last in the additive manufacturing method is not less than a temperature which, in a dynamic-mechanical analysis of the construction material (according to ISO 6721-10 at an angular frequency of 1/s), corresponds to a point of intersection of a theoretical straight line in the section of the curve of the storage modulus E′ corresponding to a vitreous state of the construction material and a theoretical straight line in the section of the curve of the storage modulus E′ in which the storage modulus E′ declines and indicates a glass transition.

Assignees

• Covestro Deutschland Ag

Inventors

• Achten Dirk
• Büsgen Thomas
• Wehrmann Rolf
• Heuer Helmut Werner

Classifications

• B33Y70/10

  Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials · CPC title

• B29C64/118 Primary

  using filamentary material being melted, e.g. fused deposition modelling [FDM] · CPC title

• B33Y80/00 Primary

  Products made by additive manufacturing · CPC title

• B29C64/153 Primary

  using layers of powder being selectively joined, e.g. by selective laser sintering or melting · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title